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High-temperature glass composition

Assignee: General Electric Co
•
Filing: 1976-07-27
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Granted: 1977-11-29
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Expires: 1996-07-27
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Abstract

Abstract Aluminosilicate glasses containing BaO and CaO are provided having combined high softening points along with exceptionally low liquidus temperatures. These glasses are within the following compositional limits in percent by weight: ______________________________________ Percentage Oxides Range ______________________________________ SiO 2 55-68 Al 2 O 3 15-18 CaO 7-13 BaO 6-16 ______________________________________ except for incidental impurities, residual fluxes and refining agents. The weight ratio of Al 2 O 3 to combined weight ratio of CaO and BaO in the present glass composition is maintained in the range 0.6:1 to 1:1. Such glasses provide an improved hermetic seal for high temperature lamp envelopes.

Inventors

  • 👤 George L. Thomas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 21:01
CPC Classifications
H; H01; H01K; H01K1/00; H01K1/38; C; C03; C03C; C03C27/00; C03C27/02; C03C3/00; C03C3/04; C03C3/076; C03C3/083; C03C3/085; C03C3/087; C03C8/00; C03C8/24; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/294

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 131 words
A molybdenum seal glass composition which consists essentially of oxides in approximate percent by weight 55-68 SiO 2 , 15-18 Al 2 O 3 , 7-13 CaO, and 6-16 BaO, along with minor amounts of incidental impurities, residual fluxes, and refining agents, wherein the weight ratio of Al 2 O 3 to combined weight ratio of CaO and BaO is about in the range 0.6:1 to 1:1 so as to reside in the eutectic region of this aluminosilicate system, said glass composition having a liquidus temperature no greater than about 1250° C, a strain point of at least about 725° C, and an average coefficient of linear thermal expansion in the 0-300° C temperature range between about 42 × 10 -7 cm/cm/° C to about 48 × 10 -7 cm/cm/° C.
Claim 2
Dependent Claim 131 words
A molybdenum seal glass composition which consists essentially of oxides in approximate percent by weight 55-68 SiO 2 , 15-18 Al 2 O 3 , 7-13 CaO, and 6-16 BaO, along with minor amounts of incidental impurities, residual fluxes, and refining agents, wherein the weight ratio of Al 2 O 3 to combined weight ratio of CaO and BaO is about in the range 0.6:1 to 1:1 so as to reside in the eutectic region of this aluminosilicate system, said glass composition having a liquidus temperature no greater than about 1250° C, a strain point of at least about 725° C, and an average coefficient of linear thermal expansion in the 0-300° C temperature range between about 42 × 10 -7 cm/cm/° C to about 48 × 10 -7 cm/cm/° C.
Claim 3
Dependent Claim 18 words
A glass composition as in claim 1 which is essentially alkali metal ion free and lead oxide free.
Claim 4
Dependent Claim 19 words
A glass composition as in claim 1 wherein the mole % CaO content exceeds the mole % BaO content.
Claim 5
Dependent Claim 102 words
A molybdenum seal glass composition for a regenerative cycle halogen-containing incandescent lamp which consists essentially of oxides in approximate percent by weight 63 SiO 2 , 16 Al 2 O 3 , 9 CaO, and 12 BaO so as to reside in the eutectic region of this aluminosilicate system, along with minor amounts of incidental impurities, residual fluxes and refining agents, said glass composition having a liquidus temperature of approximately 1200° C, an average coefficient of linear thermal expansion in the 0°-300° C temperature range of about 43.5 × 10 -7 cm/cm/° C, and a strain point of at least 750° C.
Claim 6
Dependent Claim 102 words
A molybdenum seal glass composition for a regenerative cycle halogen-containing incandescent lamp which consists essentially of oxides in approximate percent by weight 63 SiO 2 , 16 Al 2 O 3 , 9 CaO, and 12 BaO so as to reside in the eutectic region of this aluminosilicate system, along with minor amounts of incidental impurities, residual fluxes and refining agents, said glass composition having a liquidus temperature of approximately 1200° C, an average coefficient of linear thermal expansion in the 0°-300° C temperature range of about 43.5 × 10 -7 cm/cm/° C, and a strain point of at least 750° C.

References Cited (Backward Citations)

US2961328A Cited
US3489627A Cited
US3496401A Cited
US3942992A Cited
US3978362A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-11-28 1981-05-30 1981-11-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-11-28 1985-05-30 1985-11-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-11-28 1989-05-30 1989-11-29 $7700.00 Window Closed / Lapsed

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