Sulfonylacetate activator-stabilizer precursor

Claim 2

In a heat developable and heat stabilizable photographic element comprising a support having thereon, in reactive association, (a) a photographic silver salt, (b) a photographic silver salt developing agent, (c) a binder, and (d) a stabilizing concentration of an activator-stabilizer precursor having a base portion and an acid portion the improvement wherein said acid portion is an alpha-sulfonylacetate.

Claim 3

A heat developable and heat stabilizable photographic element comprising a support having thereon in reactive association (a) a photographic silver salt, (b) a photographic silver salt developing agent, (c) a binder, and (d) a stabilizing concentration of an activator-stabilizer precursor represented by the formula: Q.sub.m A.sub.w wherein Q is a protonated basic nitrogen containing moiety; A is an alpha-sulfonylacetate; m is 1 to 4 and w is 1 to 2.

Claim 4

A heat developable and heat stabilizable photographic element comprising a support having thereon in reactive association (a) a photographic silver salt, (b) a photographic silver salt developing agent, (c) a binder, and (d) a stabilizing concentration of an activator-stabilizer precursor represented by the formula: Q.sub.m A.sub.w wherein Q is a protonated basic nitrogen containing moiety; A is an alpha-sulfonylacetate; m is 1 to 4 and w is 1 to 2.

Claim 5

The element of claim 2 wherein A is an alphasulfonylacetate represented by the formula: ##STR17## wherein w is 1 or 2; R 1 is alkyl containing 1 to 6 carbon atoms, aryl containing 5 to 10 carbon atoms or carboxymethyl when w is 1, and alkylene containing 1 to 6 carbon atoms, alkylidene, or arylene containing 6 to 10 carbon atoms when w is 2; R 2 and R 3 individually are hydrogen, alkyl containing 1 to 6 carbon atoms or aryl containing 6 to 10 carbon atoms.

Claim 6

The element of claim 2 wherein Q is selected from the group consisting of the following formulas: ##STR18## wherein Y is alkylene containing 2 or 3 chain carbon atoms, X is SR 7 or NHR 8 , wherein R 7 is aminoalkyl containing 2 to 6 carbon atoms, and R 8 is hydrogen, alkyl containing 1 to 20 carbon atoms, phenyl, or aminoalkyl containing 2 to 6 carbon atoms; p is 1 or 2; when p is 1, Z is ##STR19## when p is 2, Z is a divalent linking group selected from the group consisting of ##STR20## R 6 is alkylene containing 2 to 12 carbon atoms, or phenylene; R 5 and R 4 are individually selected from the group consisting of hydrogen, alkyl containing 1 to 6 carbon atoms, or R 5 and R 4 taken together represent alkylene containing 2 or 3 carbon atoms; y is 1 to 8.

Claim 7

The element of claim 1 wherein the activator-stabilizer precursor has the properties of releasing a byproduct by decarboxylation upon heating and undergoes less than 10% weight loss in a thermogravimetric scan between about 30° C and about 180° C where the scan rate is about 40° C per minute.

Claim 8

The element of claim 1 wherein said acid portion is selected from the group consisting of ethylenebis(sulfonylacetate), methylenebis(sulfonylacetate) and phenylsulfonylacetate.

Claim 9

The element of claim 1 wherein the activator-stabilizer precursor consists essentially of bis(2-amino-2-thiazoline) methylene(sulfonylacetate).

Claim 10

The element of claim 1 wherein the activator-stabilizer precursor consists essentially of N-(2-thiazoline)-N'-(imidazoline)ethylenediamine ethylenebis(sulfonylacetate).

Claim 11

The element of claim 1 wherein the activator-stabilizer precursor consists essentially of 1,3-bis[2S-(N,N'-ethyleneisothiourea)ethyl]urea ethylenebis(sulfonylacetate.

Claim 12

The element of claim 1 wherein the photographic silver salt is photographic silver halide.

Claim 13

The element of claim 1 wherein the stabilizing concentration of the activator-stabilizer precursor is 0.2 to 4 moles of the activator-stabilizer precursor per mole of the photographic silver salt.

Claim 14

A heat developable and heat stabilizable photographic element comprising a support having thereon a layer comprising in reactive association (a) photographic silver halide, (b) a 3-pyrazolidone silver halide developing agent, (c) a polymeric binder, and (d) a stabilizing concentration of an activator-stabilizer precursor comprising bis(2-amino-2-thiazoline) methylene(sulfonylacetate).

Claim 15

A heat developable and heat stabilizable photographic element comprising a support having thereon a layer comprising in reactive association (a) photographic silver halide, (b) a 3-pyrazolidone silver halide developing agent, (c) a polymeric binder, and (d) a stabilizing concentration of an activator-stabilizer precursor comprising bis(2-amino-2-thiazoline) methylene(sulfonylacetate).

Claim 16

A heat developable and heat stabilizable photographic element comprising a support having thereon a layer comprising in reactive association (a) photographic silver halide, (b) a 3-pyrazolidone silver halide developing agent, (c) a polymeric binder and (d) a stabilizing concentration of an activator-stabilizer precursor comprising N-(2-thiazolino)-N'-(imidazolino)ethylenediamine ethylenebis(sulfonylacetate).

Claim 17

A heat developable and heat stabilizable photographic element comprising a support having thereon a layer comprising in reactive association (a) photographic silver halide, (b) a 3-pyrazolidone silver halide developing agent, (c) a polymeric binder and (d) a stabilizing concentration of an activator-stabilizer precursor comprising N-(2-thiazolino)-N'-(imidazolino)ethylenediamine ethylenebis(sulfonylacetate).

Claim 18

In a heat developable and heat stabilizable photographic composition comprising (a) a photographic silver salt, (b) a photographic silver salt developing agent and (c) a stabilizing concentration of an activator-stabilizer precursor having an acid portion and a base portion the improvement wherein said acid portion is an alpha-sulfonylacetate.

Claim 19

In a heat developable and heat stabilizable photographic composition comprising (a) a photographic silver salt, (b) a photographic silver salt developing agent and (c) a stabilizing concentration of an activator-stabilizer precursor having an acid portion and a base portion the improvement wherein said acid portion is an alpha-sulfonylacetate.

Claim 20

A heat developable and heat stabilizable photographic composition comprising (a) a photographic silver salt, (b) a photographic silver salt developing agent, and (c) a stabilizing concentration of an activator-stabilizer precursor represented by the formula: Q.sub.m A.sub.w wherein Q is a protonated basic nitrogen containing moiety; A is an alpha-solfonylacetate; m is an integer from 1 to 4 and w is an integer 1 to 2.

Claim 21

A heat developable and heat stabilizable photographic composition comprising (a) a photographic silver salt, (b) a photographic silver salt developing agent, and (c) a stabilizing concentration of an activator-stabilizer precursor represented by the formula: Q.sub.m A.sub.w wherein Q is a protonated basic nitrogen containing moiety; A is an alpha-solfonylacetate; m is an integer from 1 to 4 and w is an integer 1 to 2.

Claim 22

The composition of claim 15 wherein A is an alpha-sulfonylacetate represented by the formula: ##STR21## wherein w is 1 or 2; R 1 is alkyl containing 1 to 6 carbon atoms, aryl containing 5 to 10 carbon atoms or carboxymethyl when w is 1, and alkylene containing 1 to 6 carbon atoms, alkylidene, or arylene containing 6 to 10 carbon atoms when w is 2; R 2 and R 3 individually are hydrogen, alkyl containing 1 to 6 carbon atoms or aryl containing 6 to 10 carbon atoms.

Claim 23

The composition of claim 15 wherein Q is selected from the group consisting of the following formulas: ##STR22## wherein Y is alkylene containing 2 or 3 chain carbon atoms, X is SR 7 or NHR 8 , wherein R 7 is aminoalkyl containing 2 to 6 carbon atoms, and R 8 is hydrogen, alkyl containing 1 to 20 carbon atoms, phenyl, or aminoalkyl containing 2 to 6 carbon atoms; p is 1 or 2; when p is 1, Z is ##STR23## when p is 2, Z is a divalent linking group selected from the group consisting of ##STR24## R 6 is alkylene containing 2 to 12 carbon atoms, or phenylene; R 5 and R 4 are individually selected from the group consisting of hydrogen, alkyl containing 1 to 6 carbon atoms, or R 5 and R 4 taken together represent alkylene containing 2 or 3 carbon atoms; y is 1 to 8.

Claim 24

The composition of claim 15 wherein the activator-stabilizer precursor has the properties of releasing a byproduct by decarboxylation upon heating and undergoes less than 10% weight loss in a thermogravimetric scan between about 30° and about 180° C where the scan rate is about 40° C per minute.

Claim 25

The composition of claim 15 wherein said acid portion is selected from the group consisting of ethylenebis(sulfonylacetate), methylenebis(sulfonylacetate) and phenylsulfonylacetate.

Claim 26

The composition of claim 15 wherein the activator-stabilizer precursor consists essentially of bis(2-amino-2-thiazoline) methylene(sulfonylacetate).

Claim 27

The composition of claim 15 wherein the activator-stabilizer precursor consists essentially of N-(2-thiazolino-N'-(imidazolino)ethylenediamine ethylene-bis(sulfonylacetate.

Claim 28

The composition of claim 15 wherein the activator-stabilizer precursor consists essentially of 1,3-bis[2S-(N,N'-ethyleneisothiourea)ethyl]urea ethylenebis(sulfonylacetic acid).

Claim 29

The composition of claim 15 wherein the stabilizing concentration of the activator-stabilizer precursor is 0.2 to 4 moles of the activator-stabilizer precursor per mole of the photographic silver salt.

Claim 30

A heat activatable photographic silver salt processing composition comprising a silver salt developing agent and an activator-stabilizer precursor wherein said stabilizer precursor has the formula: Q.sub.m A.sub.w wherein Q is a protonated basic nitrogen containing moiety; A is an alpha-sulfonylacetate; m is an integer from 1 to 4 and w is an integer 1 to 2 and wherein said precursor is present in the composition in a concentration sufficient to stabilize a silver halide image when said composition is heated.

Claim 31

A heat activatable photographic silver salt processing composition comprising a silver salt developing agent and an activator-stabilizer precursor wherein said stabilizer precursor has the formula: Q.sub.m A.sub.w wherein Q is a protonated basic nitrogen containing moiety; A is an alpha-sulfonylacetate; m is an integer from 1 to 4 and w is an integer 1 to 2 and wherein said precursor is present in the composition in a concentration sufficient to stabilize a silver halide image when said composition is heated.

Claim 32

The processing composition of claim 24 wherein said developing agent comprises a phenolic silver halide developing agent and a 3-pyrazolidone silver halide developing agent and wherein said activator-stabilizer precursor is a compound selected from the group consisting of bis(2-amino-2-thiazoline) methylene(sulfonylacetate), N-(2-thiazolino)-N'-(imidazolino)ethylenediamine ethylenebis(sulfonylacetate), 1,3-bis[2S-(N,N'-ethyleneisothiourea)ethyl]urea ethylenebis(sulfonylacetic acid) and combinations thereof.

Claim 33

A heat activatable photographic silver salt processing composition comprising (a) a hydroquinone silver halide developing agent, (b) a 4-methyl-4-hydroxymethyl-1-phenyl-3-pyrazolidone silver halide developing agent and (c) N-(2-thiazolino)-N'-(imidazolino)ethylenediamine ethylenebis(sulfonylacetate).

Claim 34

A heat activatable photographic silver salt processing composition comprising (a) a hydroquinone silver halide developing agent, (b) a 4-methyl-4-hydroxymethyl-1-phenyl-3-pyrazolidone silver halide developing agent and (c) N-(2-thiazolino)-N'-(imidazolino)ethylenediamine ethylenebis(sulfonylacetate).

Claim 35

A method of developing and stabilizing an image in an exposed photographic element as defined in claim 1, after image wise exposure comprising heating said element to a temperature within the range of about 90° to about 200° C until an image is developed and stabilized.

Claim 36

The method of claim 27 wherein the element is heated for about 1 to 60 seconds.