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US4059505A Expired / Lapsed US ⏱️ 0.0 years remaining

Separating hydrocarbons

Assignee: BP PLC
•
Filing: 1976-03-22
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Granted: 1977-11-22
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Expires: 1996-03-22
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Abstract

Abstract Molecular sieve pressure swing separating process is modified by stopping the feed before the end of the adsorption stage and passing a mixture richer in n-paraffins than the feed through the sieve bed. Suitable mixtures include purge effluent and desorpting effluent. This enhances the purity of the product.

Inventors

  • 👤 Colin William Cartwright
  • 👤 Donald Lamb

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 05:48
CPC Classifications
C; C10; C10G; C10G25/00; C10G25/12; C10G25/02; C10G25/03

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 128 words
A cyclic vapour phase process for separating n-paraffins boiling in the gasoline, kerosine or gas oil ranges from a feed mixture thereof with non-straight chain hydrocarbons by means of a bed of a 5A molecular sieve comprising: i. an adsorption stage in which the feed mixture is passed into the bed under conditions of increasing pressure and an effluent produced from which the n-paraffins have been at least partly removed, and ii. a desorption stage in which the n-paraffins are desorbed from the bed by pressure reduction wherein the feed is stopped to the adsorption stage when at least 50% of the breakthrough volume has been passed and then a mixture richer in n-paraffins than the feed is passed through the bed, while the pressure is still rising.
Claim 2
Dependent Claim 128 words
A cyclic vapour phase process for separating n-paraffins boiling in the gasoline, kerosine or gas oil ranges from a feed mixture thereof with non-straight chain hydrocarbons by means of a bed of a 5A molecular sieve comprising: i. an adsorption stage in which the feed mixture is passed into the bed under conditions of increasing pressure and an effluent produced from which the n-paraffins have been at least partly removed, and ii. a desorption stage in which the n-paraffins are desorbed from the bed by pressure reduction wherein the feed is stopped to the adsorption stage when at least 50% of the breakthrough volume has been passed and then a mixture richer in n-paraffins than the feed is passed through the bed, while the pressure is still rising.
Claim 3
Dependent Claim 22 words
A process according to claim 1 wherein a purge stage effected by pressure reduction is interposed between the adsorption and desorption stages.
Claim 4
Dependent Claim 25 words
A process according to claim 1 wherein the mixture richer in n-paraffins than the feedstock is n-paraffin product obtained as effluent from the desorption stage.
Claim 5
Dependent Claim 22 words
A process according to claim 2 wherein the mixture richer in n-paraffins than the feedstock is effluent obtained from the purge stage.
Claim 6
Dependent Claim 34 words
A process according to claim 1 wherein 50-150% of the breakthrough volume of feed is passed through the bed in the adsorption stage before introduction of the mixture richer in n-paraffins than the feed.
Claim 7
Dependent Claim 34 words
A process according to claim 5 wherein 90-110% of the breakthrough volume of feed is passed through the bed in the adsorption stage before introduction of the mixture richer in n-paraffins than the feed.
Claim 8
Dependent Claim 32 words
A process according to claim 1 wherein the mixture richer in n-paraffins than the feed is passed into the bed until 20-100% of the adsorber volume has been passed into the bed.
Claim 9
Dependent Claim 20 words
A process according to claim 7 wherein the mixture is passed until 40-80% of the adsorber volume has been passed.

References Cited (Backward Citations)

US2901519A Cited
US2912473A Cited
US3422003A Cited
US3244619A Cited
US3373103A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-11-21 1981-05-23 1981-11-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-11-21 1985-05-23 1985-11-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-11-21 1989-05-23 1989-11-22 $7700.00 Window Closed / Lapsed

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