Patent US4059448A successfully refreshed from Google Patents.
US4059448A
Expired / Lapsed
US
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Dye containing photographic sensitive elements
Assignee: Fujifilm Holdings Corp
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Filing: 1975-09-12
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Granted: 1977-11-22
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Expires: 1995-09-12
Abstract
Abstract A silver halide photographic light-sensitive element containing at least one hydrophilic colloid layer which contains a basic polymer and at least one oxonol dye which contains two pyrazolone nuclei in which the 3-position of the pyrazolone nuclei is substituted with a phenyl group-containing residue and in which the 1-position of the pyrazolone nuclei is substituted with a sulfo group containing aliphatic group.
Inventors
- 👤 Masatoshi Sugiyama
- 👤 Eiichi Kato
- 👤 Yasuharu Nakamura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 07:10
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/825; G03C1/83; G03C1/832
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
160 words
A silver halide photographic light-sensitive element comprising at least one hydrophilic colloid layer which contains poly(2-diethylamino ethylmethacrylate), the poly(2-diethylamino ethymethacrylate) being a water-soluble high molecular weight material which has a basic residue in a main chain thereof or in a branch chain thereof and which is compatible with gelatin, the poly(2-diethylamino ethymethacrylate) being present in an amount of 80 to 800 mg/m 2 which is effective for mordanting, and at least one oxonal dye represented by the following formula (I): ##STR5## wherein R represents a divalent aliphatic group; M represents a cation; L represents a methine group; n represents 0, 1 or 2, and -X represents a residue selected from the group consisting of --X 1 , --CH 2 X 1 , --CONX 1 , NHCOX 1 , NHCONHX 1 or NHCSNHX 1 , wherein X 1 represents a phenyl group, the at least one oxonol dye being present in an amount effective to photographically color the hydrophilic colloid layer.
Claim 2
Dependent Claim
160 words
A silver halide photographic light-sensitive element comprising at least one hydrophilic colloid layer which contains poly(2-diethylamino ethylmethacrylate), the poly(2-diethylamino ethymethacrylate) being a water-soluble high molecular weight material which has a basic residue in a main chain thereof or in a branch chain thereof and which is compatible with gelatin, the poly(2-diethylamino ethymethacrylate) being present in an amount of 80 to 800 mg/m 2 which is effective for mordanting, and at least one oxonal dye represented by the following formula (I): ##STR5## wherein R represents a divalent aliphatic group; M represents a cation; L represents a methine group; n represents 0, 1 or 2, and -X represents a residue selected from the group consisting of --X 1 , --CH 2 X 1 , --CONX 1 , NHCOX 1 , NHCONHX 1 or NHCSNHX 1 , wherein X 1 represents a phenyl group, the at least one oxonol dye being present in an amount effective to photographically color the hydrophilic colloid layer.
Claim 3
Dependent Claim
57 words
The silver halide photographic light-sensitive element of claim 1, wherein said divalent aliphatic group for R has 5 or less carbon atoms and said aliphatic group can contain an unsaturated bond, can be interrupted by a hetero atom and can be substituted with one or more of a hydroxyl group, an alkoxy group or a halogen atom.
Claim 4
Dependent Claim
163 words
The silver halide photographic light-sensitive element of claim 2, wherein said divalent aliphatic group is an alkylene group, an alkenylene group, an alkyleneoxyalkylene group, an alkylenethioalkylene group or an alkylene group substituted with a hydroxy group or an alkoxy group; M is a hydrogen atom, an alkali metal atom, an alkaline earth metal atom or an organic base cation; and said phenyl group for X 1 can be substituted with one or more of a halogen atom, a cyano group, a sulfo group, a carboxy group, an alkoxycarbonyl group, a carbamoyl group, an alkylcarbamoyl group, an acyl group, an alkyl group, a hydroxy group, an alkoxy group, a phenoxy group, an amino group, an alkylamino group, a dialkylamino group, an acylamino group, an alkylsulfonylamino group, or an alkylcarbonyloxy groups; and the methine group forming the methine chain represented by said ═L--(L═L) n -- can be substituted with an alkyl group, a phenyl group, a benzyl group, a phenethyl group or a halogen atom.
Claim 5
Dependent Claim
36 words
The silver halide photographic light-sensitive element of claim 1, wherein said divalent aliphatic group for R is an alkylene group or alkenylene group, and X is a phenyl group, a phenylcarbamoyl group or a phenylureido group.
Claim 6
Dependent Claim
14 words
The silver halide photographic light-sensitive element of claim 1, wherein said dye is ##STR6##
Claim 7
Dependent Claim
20 words
The silver halide photographic light-sensitive element of claim 1, wherein said dye is selected from the group consisting of: ##STR7##
Claim 8
Dependent Claim
29 words
The silver halide photographic element of claim 1, wherein the at least one hydrophilic colloid layer which contains the basic polymer and the oxonol dye is a filter layer.
Claim 9
Dependent Claim
29 words
The silver halide photographic element of claim 1, wherein the at least one hydrophilic colloid layer whicn contains the basic polymer and the oxonal dye is an antihalation layer.
Claim 10
Dependent Claim
39 words
The silver halide photographic element of claim 1, comprising a support having thereon a light-sensitive silver halide photographic emulsion layer and positioned thereabove the at least one hydrophilic colloid layer which contains the basic polymer and the oxonal dye.
Claim 11
Dependent Claim
34 words
The silver halide photographic element of claim 1, comprising a support carrying thereon a plurality of light-sensitive photographic silver halide emulsion layers wherein the at least one hydrophilic colloid layer is between emulsion layers.
Claim 12
Dependent Claim
36 words
The silver halide photographic element of claim 1, comprising a support carrying thereon a light-sensitive silver halide photographic emulsion layer wherein the at least one hydrophilic colloid layer is between the emulsion layer and the support.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-11-21 | 1981-05-23 | 1981-11-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-11-21 | 1985-05-23 | 1985-11-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-11-21 | 1989-05-23 | 1989-11-22 | $7700.00 | Window Closed / Lapsed |