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Cosmetic emulsions containing N-vinylpyrrolidone-alkyl acrylate copolymers

Assignee: Henkel AG and Co KGaA
•
Filing: 1976-03-25
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Granted: 1977-11-08
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Expires: 1996-03-25
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Abstract

Abstract Water-in-oil emulsions wherein the emulsifier consists essentially of a copolymer or terpolymer of N-vinylpyrrolidone with a C6-24 alkyl or cycloalkyl acrylate or methacrylate, and vinyl acetate if desired, and the continuous phase is a cosmetically acceptable oily material which can be prepared easily, safely and inexpensively. The emulsions are substantially odorless and are cosmetically acceptable for the care of the skin.

Inventors

  • 👤 Brigitte Hase
  • 👤 Joachim Galinke
  • 👤 Bernd Wegemund

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 14:13
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/02; A61K8/04; A61K8/06; A61K8/064; A61K8/18; A61K8/72; A61K8/81; A61K8/817; A61K8/8182; A61Q; A61Q19/00; Y; Y10; Y10S; Y10S424/00; Y10S424/02

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 126 words
A cosmetic emulsion of the water-in-oil type consisting essentially of (1) from 2% to 20% by weight of a polymeric emulsifier capable of forming water-in-oil creams consisting essentially of a copolymer of (a) N-vinylpyrrolidone and (b) acrylates of the formula: ##STR3## wherein R is a member having from 6 to 24 carbon atoms selected from the group consisting of alkyl, alkenyl, cycloalkyl and alkylcycloalkyl, and R' is a member selected from the group consisting of hydrogen and methyl, and (c) vinyl acetate wherein the molar ratios of [(a)+(c)]:(b) are from 1:1 to 1:20 and the molar ratios of (c):(a) are 0:1 to 3:1, (2) from 20% to 75% by weight of water and (3) the remainder to 100% by weight of a cosmetically acceptable oily material.
Claim 2
Dependent Claim 126 words
A cosmetic emulsion of the water-in-oil type consisting essentially of (1) from 2% to 20% by weight of a polymeric emulsifier capable of forming water-in-oil creams consisting essentially of a copolymer of (a) N-vinylpyrrolidone and (b) acrylates of the formula: ##STR3## wherein R is a member having from 6 to 24 carbon atoms selected from the group consisting of alkyl, alkenyl, cycloalkyl and alkylcycloalkyl, and R' is a member selected from the group consisting of hydrogen and methyl, and (c) vinyl acetate wherein the molar ratios of [(a)+(c)]:(b) are from 1:1 to 1:20 and the molar ratios of (c):(a) are 0:1 to 3:1, (2) from 20% to 75% by weight of water and (3) the remainder to 100% by weight of a cosmetically acceptable oily material.
Claim 3
Dependent Claim 40 words
The cosmetic emulsion of claim 1 wherein said cosmetically acceptable oily material has a melting point above 30° C and is selected from the group consisting of vegetable fat, animal fat, wax, higher fatty alcohols, mineral oil and silicone oil.
Claim 4
Dependent Claim 37 words
The cosmetic emulsion of claim 1 wherein said polymeric emulsifier is present in an amount of from 5% to 10% by weight and said water is present in an amount of from 45% to 65% by weight.
Claim 5
Dependent Claim 17 words
The cosmetic emulsion of claim 1 wherein R is alkyl having from 8 to 14 carbon atoms.
Claim 6
Dependent Claim 16 words
An emulsion of claim 1 wherein the molar ratio of (a)+(c):(b) is from 1:1.5 to 1:10.
Claim 7
Dependent Claim 19 words
An emulsion of claim 1 wherein said polymeric emulsifier has an average molecular weight of from 2,000 to 100,000.
Claim 8
Dependent Claim 15 words
An emulsion of claim 1 wherein said average molecular weight is from 3,000 to 20,000.
Claim 9
Dependent Claim 17 words
An emulsion according to claim 1 wherein the emulsifier is a 1:2.5 molar ratio N-vinylpyrrolidone/lauryl acrylate copolymer.
Claim 10
Dependent Claim 169 words
In the method for the production of a cosmetic emulsion of the water-in-oil type comprising mixing an emulsifier capable of forming water-in-oil creams with a cosmetically acceptable oily material in the liquid phase at elevated temperatures, mixing therewith from 20% to 75% by weight of water, cooling under agitation and recovering said cosmetic emulsion of the water-in-oil type, the improvement consisting of adding from 2% to 20% by weight of a copolymer of (a) N-vinylpyrrolidone, (b) acrylates of the formula ##STR4## wherein R is a member having from 6 to 24 carbon atoms selected from the group consisting of alkyl, alkenyl, cycloalkyl and alkylcycloalkyl, and R' is a member selected from the group consisting of hydrogen and methyl, and (c) vinyl acetate wherein the molar ratios of [(a)+(c)]:(b) are from 1:1 to 1:20 and the molar ratios of (c):(a) are 0:1 to 3:1, (2) from 20% to 75% by weight of water and (3) the remainder to 100% by weight of a cosmetically acceptable oily material, as said emulsifier.
Claim 11
Dependent Claim 169 words
In the method for the production of a cosmetic emulsion of the water-in-oil type comprising mixing an emulsifier capable of forming water-in-oil creams with a cosmetically acceptable oily material in the liquid phase at elevated temperatures, mixing therewith from 20% to 75% by weight of water, cooling under agitation and recovering said cosmetic emulsion of the water-in-oil type, the improvement consisting of adding from 2% to 20% by weight of a copolymer of (a) N-vinylpyrrolidone, (b) acrylates of the formula ##STR4## wherein R is a member having from 6 to 24 carbon atoms selected from the group consisting of alkyl, alkenyl, cycloalkyl and alkylcycloalkyl, and R' is a member selected from the group consisting of hydrogen and methyl, and (c) vinyl acetate wherein the molar ratios of [(a)+(c)]:(b) are from 1:1 to 1:20 and the molar ratios of (c):(a) are 0:1 to 3:1, (2) from 20% to 75% by weight of water and (3) the remainder to 100% by weight of a cosmetically acceptable oily material, as said emulsifier.

References Cited (Backward Citations)

DE1931080A1 Cited
US3954960A Cited
US3914403A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-11-07 1981-05-09 1981-11-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-11-07 1985-05-09 1985-11-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-11-07 1989-05-09 1989-11-08 $7700.00 Window Closed / Lapsed

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