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US4057598A Expired / Lapsed US ⏱️ 0.0 years remaining

Multiphase block and graft copolymers comprising a hydrophilic continuous phase and hydrophobic domains

Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1975-02-27
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Granted: 1977-11-08
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Expires: 1995-02-27
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Abstract

Abstract This invention relates to thermoplastic, multiphase copolymers selected from the group consisting of copolymers represented by graft copolymers having the general formula <IMAGE> AND BLOCK COPOLYMERS HAVING THE GENERAL FORMULA XB-[AB]n-yA wherein n is an integer >/=1, m is >1, x and y are 0 or 1, and y is 1 when n is 1, A is a thermoplastic, hydrophobic polymer block having a softening point (i.e., a glass transition or crystalline melting point) of at least 35 DEG C and a molecular weight of at least 2,000, and B is a thermoplastic, hydrophilic polymer block having a softening point of at least about 35 DEG C and a molecular weight of at least about 6,000, which comprises from about 30-97 wt % of said copolymer. The novel polymers of this invention are useful for making water containing gels. Preferably, the thermoplastic multiphase copolymer is a styrene-ethylene oxide copolymer. The novel polymers are made by a process which allows one to prepare a copolymer which is substantially free of homopolymeric impurities. The compositions of the instant invention are melt processable by conventional thermoplastic techniques.

Inventors

  • 👤 Robert D. Lundberg
  • 👤 Neville G. Thame

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 19:35
CPC Classifications
C; C08; C08G; C08G81/00; C08G81/02; C08G81/024; C08G2210/00; C08G2250/00; C08G2310/00

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 164 words
A composition of matter which comprises a thermoplastic having an average molecular weight of at least 10,000 selected from the group consisting of copolymers represented by graft copolymers having the general formula ##STR8## and block copolymers having the general formula xB--[AB] n --ya wherein n is an integer ≧1, m is >1, x and y are 0 or 1, and y is 1 when n is 1, A is a thermoplastic hydrophobic polymer block having a softening point of at least about 35° C. and a molecular weight of at least about 2,00, A being selected from the group consisting of polystyrene, poly(t-butyl styrene), polyvinyl toluene, polymethylmethacrylate, polyamides and copolymers thereof, and B is a thermoplastic hydrophilic polymer block which comprises from about 30-97 weight % of said copolymer, B being selected from the group consisting of poly(ethylene oxide), polyacrylamide, poly- α-hydroxyethyl-methacrylate and copolymers thereof wherein the hydrophilic portion is greater than 50%, and said composition further characterized as being a water swollen gel.
Claim 2
Dependent Claim 164 words
A composition of matter which comprises a thermoplastic having an average molecular weight of at least 10,000 selected from the group consisting of copolymers represented by graft copolymers having the general formula ##STR8## and block copolymers having the general formula xB--[AB] n --ya wherein n is an integer ≧1, m is >1, x and y are 0 or 1, and y is 1 when n is 1, A is a thermoplastic hydrophobic polymer block having a softening point of at least about 35° C. and a molecular weight of at least about 2,00, A being selected from the group consisting of polystyrene, poly(t-butyl styrene), polyvinyl toluene, polymethylmethacrylate, polyamides and copolymers thereof, and B is a thermoplastic hydrophilic polymer block which comprises from about 30-97 weight % of said copolymer, B being selected from the group consisting of poly(ethylene oxide), polyacrylamide, poly- α-hydroxyethyl-methacrylate and copolymers thereof wherein the hydrophilic portion is greater than 50%, and said composition further characterized as being a water swollen gel.
Claim 3
Dependent Claim 18 words
The composition of claim 1 wherein said copolymer has a molecular weight of from about 25,000 to 500,000.
Claim 4
Dependent Claim 22 words
The composition of claim 2 wherein A block and said B block having a softening point of about 35° to 260° C.
Claim 5
Dependent Claim 19 words
The composition of claim 3, wherein said A block is a polyamide and said B block is polyethylene oxide.
Claim 6
Dependent Claim 20 words
The composition of claim 3 wherein said A block is a polystyrene and said B block is a polyethlene oxide.
Claim 7
Dependent Claim 21 words
The composition of claim 3 wherein water comprises from about 30 to about 98 weight % of said water swollen gel.

References Cited (Backward Citations)

US2848434A Cited
US2808388A Cited
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US3157527A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-11-07 1981-05-09 1981-11-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-11-07 1985-05-09 1985-11-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-11-07 1989-05-09 1989-11-08 $7700.00 Window Closed / Lapsed

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