Anaerobic adhesive and sealant compositions employing as a catalyst α-

Claim 1

An anaerobic curing composition stable when exposed to air consisting essentially of a mixture of a polymerizable acrylic or substituted acrylic monomer selected from the group consisting of ##STR14## wherein R is selected from the group consisting of hydrogen, methyl, ethyl, ##STR15## R' is selected from the group consisting of hydrogen chlorine, methyl and ethyl; R" is selected from the group consisting of hydrogen, hydroxy, ##STR16## m is an integer from 1 to 8; and n is an integer from 1 to 20; and p is 0 or 1; ##STR17## wherein R represents hydrogen, chlorine, methyl or ethyl, R' represents alkylene with 2-6 carbon atoms, R" represents (CH 2 ) m in which m is an integer of from 0 to 8, ##STR18## n represents an integer of from 1 to 4; ##STR19## wherein X is selected from the group consisting of --0-- and ##STR20## and R is a member selected from the group consisting of hydrogen and lower alkyl of 1 to 7 carbon atoms, A represents the organic residue of an active hydrogen containing acrylic ester wherein the active hydrogen has been removed, said ester being hydroxy or amino substituted on the alkyl protion thereof, and the methyl, ethyl and chlorine homologs thereof, n is an integer from 1 to 6, and B is a mono- or polyvalent organic radical selected from the group consisting of alkyl, alkylene, alkenyl, cycloalkyl, cycloalkylene, aryl, aralkyl, alkaryl, poly(oxyalkylene) poly(carboalkoxyalkylene), and heterocyclic radicals both substituted and unsubstituted ##STR21## wherein R 1 is selected from the group consisting of methyl, ethyl, carboxyl and hydrogen, R 2 is selected from the group consisting of hydrogen, methyl and ethyl; R 3 is selected from the group consisting of hydrogen, methyl and hydroxyl; R 4 is selected from the group consisting of hydrogen, chlorine, methyl and ethyl and n represents an integer of from 0 to 8; and e. monofunctional acrylate and methacrylate esters and the hydroxy, amide, cyano, chloro, and silane substituted derivatives thereof; and from 0.05 to 5.0%, by weight of monomer, of an alpha-amino sulfone corresponding to the formula ##STR22## where R is hydrogen or methyl; R 1 , R 2 and R 3 are independently chosen from the group consisting of hydrogen; hydroxy; C 1 -C 20 alkyl; C 1 -C 20 alkyl substituted with chlorine, bromine, fluorine, dialkyl(C 1 -C 6 )amino, carboalkoxy (C 1 -C 4 ) or alkoxy (C 1 -C 4 ); C 6 -C 10 aryl; C 6 -C 10 aryl substituted with alkyl (C 1 -C 8 ), chlorine, bromine, fluorine, dialkyl(C 1 -C 6 )amino, carboalkoxy (C 1 -C 4 ) or alkoxy (C 1 -C 4 ); dialkyl(C 1 -C 6 )amino, or either R 2 or R 3 may be ##STR23## and wherein the alpha-amino sulfone is present in amount sufficient to initiate polymerization of said acrylic monomer at room temperature in the absence of air or oxygen.