High temperature chemical reaction processes utilizing fluid-wall reactors

Claim 2

A high temperature chemical reaction process which comprises: a. generating an annular envelope of an inert fluid which is substantially transparent to radiation within a shell of a refractory material which reflects radiation, the volume enclosed by the shell constituting a black body cavity, the envelope having substantial axial length and the interior of the envelope defining a reaction chamber; b. passing at least one reactant into the black body cavity and through the reaction chamber along a predetermined path substantially coincident with the longitudinal axis of the envelope, the reactants being confined within the reaction chamber, at least one of the reactants being a carbonaceous material; and c. directing high intensity radiant energy into the reaction chamber to coincide with at least a portion of the predetermined path of the reactants, sufficient radiant energy being absorbed within the reaction chamber to raise the temperature of the reactants to a level required to initiate and sustain the desired chemical reaction.

Claim 3

The process according to claim 1, in which hydrocarbons or hydrocarbonaceous materials are dissociated into hydrogen and carbon black.

Claim 4

The process according to claim 1, in which coal, petroleum fractions, oil shale, tar sands, lignite, or any other carbonaceous or hydrocarbonaceous feedstock is steam-reformed into synthesis gas mixtures containing carbon monoxide and and hydrogen.

Claim 5

The process according to claim 1, in which hydrocarbons or hydrocarbonaceous material is partially dissociated into lower molecular weight compounds.

Claim 6

The process according to claim 1 in which saturated hydrocarbons undergo partial pyrolysis into unsaturated hydrocarbons.

Claim 7

The process according to claim 3, in which organic waste materials are converted into a fuel gas.

Claim 8

The process according to claim 3, in which the process involves carbonaceous or hydrocarbonaceous reactants and a catalyst is added to the reactants to promote the formation of free radicals, carbonium ions or carbanions during the reaction.

Claim 9

The process according to claim 3, in which sulfur-containing hydrocarbonaceous feedstock undergoes complete or partial desulfurization.

Claim 10

The process according to claim 8, in which one or more inorganic carbonates or oxides are added to the reactants to chemically react with the sulfur-containing contaminants such that they may be removed from the resultant synthesis gas mixtures.

Claim 11

The process according to claim 1, in which an inorganic element or compound is partially or completely reacted with a carbonaceous material to form the corresponding inorganic carbide.

Claim 12

The process according to claim 10, in which silicon dioxide is partially reacted with a carbonaceous material to form silicon carbide.

Claim 13

A high temperature chemical reaction process according to claim 1, in which the annular envelope is generated in a direction generally parallel to the envelope axis.

Claim 14

A high temperature chemical reaction process according to claim 1, in which the annular envelope is generated in a direction generally perpendicular to the envelope axis and radially inwardly of the outer circumferential surface of the envelope.

Claim 15

A high temperature chemical reaction process according to claim 2, in which a radiant energy absorptive target is introduced along the path of the reactants prior to the introduction of the reactants into the reactor tube, sufficient radiant energy being absorbed by the target to raise the temperature in the core to the level required to initiate the desired chemical reaction.

Claim 16

A high temperature chemical reaction process according to claim 13 utilizing a high temperature fluid-wall reactor in which substantially all of the heat is supplied by radiation coupling, which reactor comprises: A. a reactor tube having an inlet end and an outlet end, the interior of the tube defining a reactor chamber, the reactor tube being made of a porous refractory material capable of emitting sufficient radiant energy to raise the temperature of reactants within the reactor tube to a level required to initiate and sustain the desired chemical reaction; the pores of the refractory material being of such diameter as to permit a uniform flow of sufficient inert fluid which is substantially transparent to radiant energy through the tube wall to constitute a protective blanket for the radially inward surface of the reactor tube; B. a fluid-tight, tubular pressure vessel enclosing the reactor tube to define an inert fluid plenum between the reactor tube and the pressure vessel, the inlet and outlet ends of the reactor tube being sealed from the plenum; the pressure vessel having an inlet for admitting the inert fluid which is directed under pressure into the plenum and through the porous tube wall into the reactor chamber; C. means for introducing at least one reactant into the reactor chamber through the inlet end of the reactor tube, the reactants being directed in a predetermined path axially of the reactor tube and being confined by the protective blanket substantially centrally within the reactor chamber and out of contact with the inner wall of the reactor tube; D. electrical means disposed within the plenum and spaced radially outwardly of the reactor tube for heating the reactor tube to the temperature level at which it emits sufficient radiant energy to initiate and sustain the desired chemical reaction, the radiant energy being directed centrally therewithin substantially coincident with at least a portion of the path of the reactants; and E. a circumferential heat shield disposed within the pressure vessel and radially outwardly of the heating means, the heat shield reflecting radiant energy toward the reactor tube; wherein the step of generating an annular envelope of an inert fluid includes the steps of: a.1. introducing the inert fluid under pressure through the inlet in the pressure vessel and into the plenum; and a.2. directing the inert fluid through the porous tube wall in a uniform flow to generate an annular envelope constituting a protective blanket for the radially inward surface of the reactor tube.

Claim 17

The process according to claim 5 in which sulfur-containing hydrocarbonaceous feedstock undergoes complete or partial desulfurization.

Claim 18

The process according to claim 16 in which one or more inorganic carbonates or oxides are added to the feedstock to chemically react with sulfur-containing contaminants such that they may be removed from the resultant unsaturated hydrocarbons.

Claim 19

The process according to claim 5 in which a catalyst is added to the reactants to promote the formation of free radicals, carbonium ions, or carbanions during the reaction.

Claim 20

The process according to claim 4 in which sulfur-containing hydrocarbonaceous feedstock undergoes complete or partial desulfurization.

Claim 21

The process according to claim 19 in which one or more inorganic carbonates or oxides are added to the feedstock to chemically react with sulfur-containing contaminants such that they may be removed from the resultant lower molecular weight compounds.

Claim 22

The process according to claim 4 in which a catalyst is added to the reactants to promote the formation of free radicals, carbonium ions, or carbanions during the reaction.