Degradable polymeric composition

Claim 2

A process for degrading a polymeric composition, which process comprises reacting the polymeric material in the presence of a source of free radicals with a non-polymeric organic reagent R-X, wherein R is at least one aliphatic hydrocarbon group containing at least six carbon atoms and X is at least one polymeric material-degradation-sensitizing group, to produce said degradable polymeric composition, and subsequently exposing said composition to at least one natural environmental condition sufficient to degrade said composition.

Claim 3

The process of claim 1 wherein the polymeric material is selected from the group consisting of polypropylene, poly(4-methyl-1-pentene), polystyrene, polyvinylchloride, poly(1-butene), ethylene-propylene copoylymers, ethylene-1-butene copolymers, ethylene-1-hexene copolymers, ethylene-vinyl acetate copolymers, ethylene-ethyl acrylate copolymers, ethylene-acrylic acid copolymers, poly(vinylidene chloride), polyvinyl fluoride, poly(vinylidene fluoride), polyoxymethylene, poly(ethylene oxide), poly(propylene oxide), polyvinyl alcohol, polyvinyl acetate, polyvinyl formal, polyvinyl butyral, poly(methylacrylate), poly(ethyl acrylate), poly(caprolactam), poly(hexamethyleneadipamide), poly(ethylene terephthalate), vinyl chloride-vinyl acetate copolymers, styrene-butadiene copolymers, styrene-isoprene copolymers, cellulose, cellulose acetate, cellulose propionate, cellulose acetate butyrate, ethyl cellulose, methyl cellulose, hydroxyethyl cellulose, and hydroxypropyl cellulose.

Claim 4

The process of claim 1 wherein R is at least one saturated or unsaturated aliphatic group which is linear, branched, or cyclic.

Claim 5

The process of claim 3 wherein X is at least one group selected from the group consisting of acyl, aroyl, aldehyde, ether, acyl halide, arylazo, quinone, sulfide, disulfide, thiol, halogen, phenyl, substituted phenyl, naphthyl, substituted naphthyl, heterocyclics, and substituted heterocyclics.

Claim 6

The process of claim 1 wherein the source of free radicals is selected from the group consisting of an organic peroxide, hydroperoxide, and azo compound.

Claim 7

The process of claim 5 wherein there is reacted a composition containing about 60 to about 98% by weight of the polymeric material, about 1 to about 30% by weight of the reagent R-X, and about 1 to about 20% by weight of the free-radical source.

Claim 8

The process of claim 1 wherein a composition containing about 60 to about 99% by weight of the polymeric material, about 1 to about 30% by weight of the reagent R-X and an effective amount up to 10% by weight of a photosensitizing additive are subjected to actinic radiation.

Claim 9

The process of claim 1 wherein a composition containing about 70 to about 99% by weight of the polymeric material and about 1 to about 30% by weight of the reagent R-X are subjected to ionizing radiation.

Claim 10

The process of claim 1 wherein R-X is a compound selected from the group consisting of ketones, aldehydes, sulfur compounds, nitro compounds, halogenated compounds, ethers, amines and aromatic compounds.

Claim 11

The process of claim 9 wherein said ketones are selected from the group consisting of laurophenone, n-decanophenone, di-n-heptyl ketone, 2-dodecanone, and 2-octadecanone.

Claim 12

The process of claim 9 wherein said aldehydes are selected from the group consisting of lauraldehyde, undecylenic aldehyde, and p-n-octyloxybenzaldehyde.

Claim 13

The process of claim 9 wherein said sulfur compounds are selected from the group consisting of n-decyl mercaptan, lauryl mercaptan, stearyl mercaptan, dilauryl sulfide, dilauryl disulfide, distearyl disulfide, and di-n-octyl disulfide.

Claim 14

The process of claim 9 wherein said nitro compounds are selected from the group consisting of p-nitrophenyl caprylate and p-nitrophenyl laurate.

Claim 15

The process of claim 9 wherein said halogenated compounds are selected from the group consisting of lauryl bromide, lauryl chloride, stearyl bromide, stearyl chloride, oleoyl chloride, lauroyl chloride, stearoyl chloride, and dodecenyl chloride.

Claim 16

The process of claim 9 wherein said ethers are selected from the group consisting of cetyl vinyl ether, n-dodecyl phenyl ether, lauryl vinyl ether, and dilauryl ether.

Claim 17

The process of claim 9 wherein said amines are selected from the group consisting of stearyl diphenylamine, and N-stearylmorpholine.

Claim 18

The process of claim 9 wherein said aromatic compounds are selected from the group consisting of 1-decylnaphthalene, n-dodecylbenzene, n-decylbenzene, and 1octylnaphthalene.

Claim 19

The process of claim 1 wherein said degradable polymeric composition is exposed to at least one natural environmental condition including sunlight, heat, oxygen, moisture or microorganisms.