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US4054704A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for decorating coatings produced by heat-stable polymer compositions

Assignee: EIDP Inc
•
Filing: 1975-08-22
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Granted: 1977-10-18
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Expires: 1995-08-22
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Abstract

Abstract The appearance of a heat-stable polymer coating is enhanced by a process which produces a decorative pattern within a coating produced by a heat-stable polymer coating composition. The process consists of applying a heat-stable polymer composition as a subsequent coat over or directly under an antioxidant composition which diffuses into the heat-stable polymer coating composition and renders the pattern visible, upon baking, within the baked coat produced by the coating composition.

Inventors

  • 👤 Eustathios Vassiliou

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 19:37
CPC Classifications
B; B05; B05D; B05D5/00; B05D5/06; C; C09; C09D; C09D5/00; C09D5/28; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24835; Y10T428/24851; Y10T428/24868; Y10T428/24876; Y10T428/24893; Y10T428/24901; Y10T428/24917; Y10T428/31504; Y10T428/31533; Y10T428/31536; Y10T428/3154; Y10T428/31544; Y10T428/31551; Y10T428/31623; Y10T428/31678; Y10T428/31681; Y10T428/31721; Y10T428/31725; Y10T428/3175; Y10T428/31757

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 136 words
A process for preparing a decorative coating on a substrate, comprising the following steps, with (a) and (b) performed in any order: a. applying to a substrate a composition comprising 1. a heat-stable polymer; 2. a colorant; 3. optionally, an antioxidant; and 4. a liquid carrier; and b. applying to a substrate, in a decorative pattern, a composition comprising 1. an antioxidant; 2. a liquid carrier; and 3. optionally, one or more of a heat-unstable organic compound which decomposes to produce a colorant; and then heating the resulting coating to the heat-stable polymer fusion temperature wherein the heat stable polymer composition is stable at temperatures above 300° C and the heat-stable polymer is a silicone, polysulfide, polymerized p-hydroxy-benzoic acid, a polysulfone, a polyimide, a polyamide, a polysulfonate, a polysulfonamide, a fluorocarbon polymer, or a mixture thereof.
Claim 2
Dependent Claim 136 words
A process for preparing a decorative coating on a substrate, comprising the following steps, with (a) and (b) performed in any order: a. applying to a substrate a composition comprising 1. a heat-stable polymer; 2. a colorant; 3. optionally, an antioxidant; and 4. a liquid carrier; and b. applying to a substrate, in a decorative pattern, a composition comprising 1. an antioxidant; 2. a liquid carrier; and 3. optionally, one or more of a heat-unstable organic compound which decomposes to produce a colorant; and then heating the resulting coating to the heat-stable polymer fusion temperature wherein the heat stable polymer composition is stable at temperatures above 300° C and the heat-stable polymer is a silicone, polysulfide, polymerized p-hydroxy-benzoic acid, a polysulfone, a polyimide, a polyamide, a polysulfonate, a polysulfonamide, a fluorocarbon polymer, or a mixture thereof.
Claim 3
Dependent Claim 31 words
The process of claim 1 wherein the heat-stable polymer in (a) (1) is of polymerized hydrocarbon monomers completely substituted with fluorine atoms or a combination of fluorine atoms and chlorine atoms.
Claim 4
Dependent Claim 21 words
The process of claim 2 wherein the heat-stable polymer in (a) (1) is polytetrafluoroethylene or a copolymer of tetrafluoroethylene and hexafluoropropylene.
Claim 5
Dependent Claim 18 words
The process of claim 1 wherein the antioxidant in (b) (1) is a phosphorus, sulfur or boron compound.
Claim 6
Dependent Claim 27 words
The process of claim 4 wherein the antioxidant in (b) (1) is an acid, salt or ester containing phosphorus, boron or sulfur, or an organic derivative thereof.
Claim 7
Dependent Claim 29 words
The process of claim 5 wherein the antioxidant in (b) (1) is phosphoric acid or a decomposable salt thereof, 2-ethylhexyldiphenyl phosphate, or a glycerophosphate of magnesium, calcium or iron.
Claim 8
Dependent Claim 34 words
The process of claim 1 where the colorant in (a) (2) is carbon black, a carbonaceous residue a substance which leaves a carbonaceous residue after the fusion step has been performed, or mixtures thereof.
Claim 9
Dependent Claim 49 words
The process of claim 1 wherein the heat-stable polymer in (a) (1) is PTFE, the colorant in (a) (2) is carbon black, a substance which leaves a carbonaceous residue after the fusion step has been performed, or a mixture thereof, and the antioxidant in (b) (2) is phosphoric acid.
Claim 10
Dependent Claim 14 words
An article bearing a decorative coating, prepared according to the process of Claim 16.
Claim 11
Dependent Claim 14 words
An article bearing a decorative coating, prepared according to the process of claim 2.
Claim 12
Dependent Claim 14 words
An article bearing a decorative coating, prepared according to the process of claim 3.
Claim 13
Dependent Claim 14 words
An article bearing a decorative coating, prepared according to the process of claim 4.
Claim 14
Dependent Claim 14 words
An article bearing a decorative coating, prepared according to the process of claim 5.
Claim 15
Dependent Claim 14 words
An article bearing a decorative coating, prepared according to the process of claim 6.
Claim 16
Dependent Claim 14 words
An article bearing a decorative coating, prepared according to the process of claim 7.
Claim 17
Dependent Claim 14 words
An article bearing a decorative coating, prepared according to the process of claim 8.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-10-17 1981-04-18 1981-10-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-10-17 1985-04-18 1985-10-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-10-17 1989-04-18 1989-10-18 $7700.00 Window Closed / Lapsed

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