Abstract The present invention relates to an interfacial process for the production of polycarbonates having terminal, aliphatically bonded hydroxyl groups by reacting predominantly dihydric alcohols with phosgene or chlorocarbonic acid esters of predominantly dihydric alcohols and/or phenols using alkali liquors as HCl-binding agents and in the presence of inert solvents, the process according to the invention being distinguished by the fact that concentrated, aqueous alkali liquors are used as the HCl-binding agents and thiodiglycol, optionally mixed with additional monohydric and polyhydric alcohols, is used as the dihydric alcohol. The present invention further relates to the new polycarbonates produced according to the novel process and to the use of these new polycarbonates for the production of polyurethane plastics.
A polycarbonate containing terminal aliphatic hydroxyl groups, having a molecular weight of from about 400 to 20,000 and containing at least about 25 mol % of structural units corresponding to the formula: ##STR2## prepared by reacting predominantly dihydric alcohols with phosgene or chlorocarbonic acid esters of predominantly dihydric alcohols and/or phenols by a phase interface process using concentrated, aqueous alkali solutions as hydrogen chloride binding agents and in the presence of inert solvents, said process characterized by the fact that thiodiglycol, optionally mixed with additional monohydric and polyhydric alcohols, is used as the dihydric alcohol in amounts of at least 25 mol %, based on the total mols of hydroxyl compounds used.
Claim 2
Dependent Claim
112 words
A polycarbonate containing terminal aliphatic hydroxyl groups, having a molecular weight of from about 400 to 20,000 and containing at least about 25 mol % of structural units corresponding to the formula: ##STR2## prepared by reacting predominantly dihydric alcohols with phosgene or chlorocarbonic acid esters of predominantly dihydric alcohols and/or phenols by a phase interface process using concentrated, aqueous alkali solutions as hydrogen chloride binding agents and in the presence of inert solvents, said process characterized by the fact that thiodiglycol, optionally mixed with additional monohydric and polyhydric alcohols, is used as the dihydric alcohol in amounts of at least 25 mol %, based on the total mols of hydroxyl compounds used.