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US4053680A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for bonding polymers

Assignee: United States Department of the Navy
•
Filing: 1975-12-04
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Granted: 1977-10-11
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Expires: 1995-12-04
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Abstract

Abstract A material which has two reactive groups, one of which is reactive with theirst of two dissimilar polymeric materials but not the second and the other of which is reactive with the second but not the first, is utilized to bind layers of the two polymeric materials together. The groups that are reactive with the first polymeric material are reacted with it as a layer of that material cures. Then a layer of the uncured second polymeric material is placed on the first and the groups that are reactive with it are reacted with it as it cures.

Inventors

  • 👤 Bernard Wasserman
  • 👤 Martin H. Kaufman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 13:32
CPC Classifications
B; B32; B32B; B32B25/00; B32B25/04; B32B25/08; B32B25/042; B32B25/16; B32B25/20; C; C08; C08J; C08J5/00; C08J5/12; B32B38/00; B32B2038/0052; B32B2038/0076; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31536; Y10T428/31551; Y10T428/31598; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 65 words
An article of manufacture comprising at least two layers, one of which is a silicone rubber layer and the second of which is a layer containing isocyanate cured hydroxy terminated polybutadiene, the layers being chemically tied together by chemical strings, the strings being chemically knotted in the silicone rubber layer by ##STR3## groups and in the isocyanate cured hydroxy terminated polybutadiene layer by ##STR4## groups.
Claim 2
Dependent Claim 65 words
An article of manufacture comprising at least two layers, one of which is a silicone rubber layer and the second of which is a layer containing isocyanate cured hydroxy terminated polybutadiene, the layers being chemically tied together by chemical strings, the strings being chemically knotted in the silicone rubber layer by ##STR3## groups and in the isocyanate cured hydroxy terminated polybutadiene layer by ##STR4## groups.
Claim 3
Independent Claim 167 words
A method for chemically tieing a layer of silicone rubber to a layer of material containing isocyanate groups, said method comprising the steps of: 1. forming a mixture by mixing uncured silicone rubber prepolymer which contains silane groups with a material containing vinyl groups which are compatible with and reactive with the silane groups and hydroxy groups which are incompatible with the prepolymer and forming said mixture into a layer; 2. curing the prepolymer to form silicone rubber whereby the vinyl groups react with the silane groups and the hydroxy groups migrate to the surface of the layer; 3. applying a layer of the material which contains isocyanate groups to the surface of the silicone rubber; and 4. allowing isocyanate groups to react with the hydroxy groups whereby the layers become chemically tied together by chemical strings, the strings being chemically knotted in the silicone rubber layer by CH 3 -- CH 2 -- Si.tbd. groups and in the layer which contained isocyanate groups by ##STR5## groups.
Claim 4
Independent Claim 167 words
A method for chemically tieing a layer of silicone rubber to a layer of material containing isocyanate groups, said method comprising the steps of: 1. forming a mixture by mixing uncured silicone rubber prepolymer which contains silane groups with a material containing vinyl groups which are compatible with and reactive with the silane groups and hydroxy groups which are incompatible with the prepolymer and forming said mixture into a layer; 2. curing the prepolymer to form silicone rubber whereby the vinyl groups react with the silane groups and the hydroxy groups migrate to the surface of the layer; 3. applying a layer of the material which contains isocyanate groups to the surface of the silicone rubber; and 4. allowing isocyanate groups to react with the hydroxy groups whereby the layers become chemically tied together by chemical strings, the strings being chemically knotted in the silicone rubber layer by CH 3 -- CH 2 -- Si.tbd. groups and in the layer which contained isocyanate groups by ##STR5## groups.

References Cited (Backward Citations)

US2751314A Cited
US3053712A Cited
US3198692A Cited
US3313773A Cited
US3477869A Cited
US3433158A Cited
US3716604A Cited
US3507114A Cited
US3725174A Cited
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US3686355A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-10-10 1981-04-11 1981-10-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-10-10 1985-04-11 1985-10-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-10-10 1989-04-11 1989-10-11 $7700.00 Window Closed / Lapsed

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