Patent US4053534A successfully refreshed from Google Patents.
US4053534A
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Organic compound conversion
Assignee: Mobil Oil AS
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Filing: 1976-12-27
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Granted: 1977-10-11
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Expires: 1996-12-27
Abstract
Abstract Organic compound conversion in the presence of a new class of heterogeneous catalyst is provided. Said new class of heterogeneous catalyst comprises a substrate having a minimum surface area of about 10 m 2 /g and having pores with a minimum pore diameter of about 5 Angstrom Units, said substrate being modified by at least one amine functional member coordinated to a metal function, said amine functional member acting as a bridging member between said substrate and said metal function.
Inventors
- 👤 Thomas Owen Mitchell
- 👤 Darrell Duayne Whitehurst
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 09:16
CPC Classifications
C; C07; C07C; C07C45/00; C07C45/49; C07C45/50; B; B01; B01J; B01J31/00; B01J31/16; B01J31/1616; B01J31/1625; B01J31/1633; B01J31/18; B01J31/1805; B01J31/1845; B01J31/1865; B01J31/187; B01J37/00; B01J37/02; B01J37/0215; B01J37/0219; C07C2/00; C07C2/02; C07C2/04; C07C2/06; C07C2/08; C07C2/26; C07C2/32; B01J2531/00; B01J2531/80; B01J2531/82; B01J2531/821; B01J2531/822; B01J35/00; B01J35/60; C07C2521/00; C07C2521/02; C07C2521/04; C07C2521/06; C07C2521/08; C07C2529/00; C07C2529/04; C07C2531/00; C07C2531/02; C07C2531/12; C07C2531/14; C07C2531/16; C07C2531/22
Claims Analysis
Total Claims: 30
Claim 1
Independent Claim
118 words
A method for olefin dimerization which comprises contacting said olefin under conditions effective for dimerization with a catalyst comprised of a substrate of a porous refractory oxide, said substrate having surface hydroxyl groups, a minimum surface area of about 10 m 2 /g and pores with a minimum pore diameter of about 5 Angstrom Units, said substrate being modified by at least one amine functional member, containing the element silicon, coordinated to a metal function of a transistion metal selected from the group consisting of Group VIII metals of the Periodic Table of Elements, said amine functional member acting as a bridging member between said substrate and said metal function, as a ligand covalently bonded to said substrate.
Claim 2
Independent Claim
118 words
A method for olefin dimerization which comprises contacting said olefin under conditions effective for dimerization with a catalyst comprised of a substrate of a porous refractory oxide, said substrate having surface hydroxyl groups, a minimum surface area of about 10 m 2 /g and pores with a minimum pore diameter of about 5 Angstrom Units, said substrate being modified by at least one amine functional member, containing the element silicon, coordinated to a metal function of a transistion metal selected from the group consisting of Group VIII metals of the Periodic Table of Elements, said amine functional member acting as a bridging member between said substrate and said metal function, as a ligand covalently bonded to said substrate.
Claim 3
Dependent Claim
32 words
The method of claim 1 wherein the substrate of said catalyst has a minimum surface area of about 200 m 2 /g and has a minimum pore diameter of 100 Angstrom Units.
Claim 4
Dependent Claim
19 words
The method of claim 1 wherein the substrate of said catalyst has a major component of silica or alumina.
Claim 5
Dependent Claim
49 words
The method of claim 1 wherein the substrate of said catalyst is selected from the group consisting of alumina, silica, silica combined with an oxide of a metal of Groups IIA, IIIA, IVA, IIIB, IVB, or VB of the Periodic Table of Elements, open lattice clays and crystalline aluminosilicates.
Claim 6
Dependent Claim
37 words
The method of claim 4 wherein the substrate of said catalyst is silica or silica combined with an oxide of a metal of Groups IIA, IIIA, IVA, IIIB, IVB, or VB or the Periodic Table of Elements.
Claim 7
Dependent Claim
15 words
The method of claim 4 wherein the substrate of said catalyst is a crystalline aluminosilicate.
Claim 8
Dependent Claim
13 words
The method of claim 6 wherein said crystalline aluminosilicate is a synthetic zeolite.
Claim 9
Dependent Claim
13 words
The method of claim 6 wherein said crystalline aluminosilicate is a natural zeolite.
Claim 10
Dependent Claim
13 words
The method of claim 4 wherein the substrate of said catalyst is alumina.
Claim 11
Dependent Claim
24 words
The method of claim 4 wherein the substrate of said catalyst is silica and the metal function of said catalyst is rhodium or ruthenium.
Claim 12
Dependent Claim
28 words
The method of claim 1 wherein the amine functional member of said catalyst is made from a compound selected from the group consisting of N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane and N-(β-aminoethyl) -γ-aminopropyltriethoxysilane.
Claim 13
Dependent Claim
13 words
The method of claim 1 wherein said amine functional member is a phosphinoamine.
Claim 14
Dependent Claim
13 words
The method of claim 2 wherein said amine functional member is a phosphinoamine.
Claim 15
Dependent Claim
13 words
The method of claim 3 wherein said amine functional member is a phosphionamine.
Claim 16
Dependent Claim
13 words
The method of claim 4 wherein said amine functional member is a phosphinoamine.
Claim 17
Dependent Claim
48 words
The method of claim 1 wherein the conditions effective for said dimerization include a temperature of from about -80° C. to about 50° C., a pressure of from about 0.1 atmosphere to about 100 atmospheres and a contact time of from about 0.1 second to about 10 seconds.
Claim 18
Dependent Claim
48 words
The method of claim 2 wherein the conditions effective for said dimerization include a temperature of from about -80° C. to about 50° C., a pressure of from about 0.1 atmosphere to about 100 atmospheres and a contact time of from about 0.1 second to about 10 seconds.
Claim 19
Dependent Claim
48 words
The method of claim 3 wherein the conditions effective for said dimerization include a temperature of from about -80° C. to about 50° C., a pressure of from about 0.1 atmosphere to about 100 atmospheres and a contact time of from about 0.1 second to about 10 seconds.
Claim 20
Dependent Claim
48 words
The method of claim 4 wherein the conditions effective for said dimerization include a temperature of from about -80° C. to about 50° C., a pressure of from about 0.1 atmosphere to about 100 atmospheres and a contact time of from about 0.1 second to about 10 seconds.
Claim 21
Dependent Claim
10 words
The method of claim 16 wherein said olefin is propylene.
Claim 22
Dependent Claim
10 words
The method of claim 17 wherein said olefin is propylene.
Claim 23
Dependent Claim
10 words
The method of claim 18 wherein said olefin is propylene.
Claim 24
Dependent Claim
10 words
The method of claim 19 wherein said olefin is propylene.
Claim 25
Dependent Claim
53 words
The method of claim 12 wherein the conditions effective for said dimerization include a temperature of from about -80° C. to about 50° C., a pressure of from about 0.1 atmosphere to about 100 atmospheres and a contact time of from about 0.1 second to about 10 seconds and said olefin is propylene.
Claim 26
Dependent Claim
53 words
The method of claim 13 wherein the conditions effective for said dimerization include a temperaure of from about -80° C. to about 50° C., a pressure of from about 0.1 atmosphere to about 100 atmospheres and a contact time of from about 0.1 second to about 10 seconds and said olefin is propylene.
Claim 27
Dependent Claim
53 words
The method of claim 14 wherein the conditions effective for said dimerization include a temperature of from about -80° C. to about 50° C., a pressure of from about 0.1 atmosphere to about 100 atmospheres and a contact time of from about 0.1 second to about 10 seconds and said olefin is propylene.
Claim 28
Dependent Claim
53 words
The method of claim 15 wherein the conditions effective for said dimerization include a temperature of from about -80° C. to about 50° C., a pressure of from about 0.1 atmosphere to about 100 atmospheres and a contact time of from about 0.1 second to about 10 seconds and said olefin is propylene.
Claim 29
Dependent Claim
21 words
The method of claim 1 wherein said olefin is contacted with said catalyst in the presence of an aluminum alkyl chloride.
Claim 30
Dependent Claim
13 words
The method of claim 28 wherein said aluminum alkyl chloride is aluminum sesquichloride.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-10-10 | 1981-04-11 | 1981-10-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-10-10 | 1985-04-11 | 1985-10-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-10-10 | 1989-04-11 | 1989-10-11 | $7700.00 | Window Closed / Lapsed |