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US4053378A Expired / Lapsed US ⏱️ 0.0 years remaining

Water purification method and apparatus

Assignee: CO-AG TECHNOLOGY Inc
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Filing: 1976-03-04
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Granted: 1977-10-11
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Expires: 1996-03-04
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Abstract

Abstract An improved method and apparatus for continuously agglomerating solids of colloidal size or larger suspended in a liquid is disclosed. The process comprises passing the liquid between spaced electrode plates in the presence of a fluidized bed of conductive particles, and subjecting said liquid suspension to an electric field from alternating current applied across said electrodes through the conductive particles of said bed. The turbulence of the particles in said bed has been found to improve conductivity and current efficiency, minimize electrode erosion, and by a mechanical, scrubbing action of the bed particles, minimize fouling or scaling of the electrodes so that the suspending forces of said solids are rapidly and efficiently broken. The agglomerated solids may then be separated from the liquid by conventional means such as skimming, settling, flotation and the like.

Inventors

  • 👤 Karl Moeglich
  • 👤 Graham L. Hodgetts

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 10:41
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/46; C02F1/461; C02F1/463; C02F2301/00; C02F2301/02; C02F2301/024

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 205 words
A continuous method for agglomerating solids of colloidal size of larger suspended in aqueous media comprising: providing at least a pair of metal electrodes having facing surface areas substantially closely spaced with respect to one another; providing a fluidized bed of conductive, attrition resistant particles between said facing surface areas; causing said media and suspended solids to continuously flow between and past the facing surfaces of said spaced electrodes and through said bed; causing said suspended solids to agglomerate by applying an alternating (AC) voltage at a frequency between about 0.2 Hz and 800 Hz across said electrodes while controlling said AC voltage in relation to the spacing between said electrode surface areas and the conductivity of said media so as to provide an alternating electric current flowing between said electrode surfaces with the value of said alternating current being between about 0.08 to 6.0 amperes per square inch of electrode surface; and providing fluid-induced agitation of said liquid media so as to create turbulence therein as the same flows through said bed and between and past the spaced facing surfaces of said electrodes whereby the suspending forces of said solids will be broken so that said solids will agglomerate for removal from said media.
Claim 2
Dependent Claim 205 words
A continuous method for agglomerating solids of colloidal size of larger suspended in aqueous media comprising: providing at least a pair of metal electrodes having facing surface areas substantially closely spaced with respect to one another; providing a fluidized bed of conductive, attrition resistant particles between said facing surface areas; causing said media and suspended solids to continuously flow between and past the facing surfaces of said spaced electrodes and through said bed; causing said suspended solids to agglomerate by applying an alternating (AC) voltage at a frequency between about 0.2 Hz and 800 Hz across said electrodes while controlling said AC voltage in relation to the spacing between said electrode surface areas and the conductivity of said media so as to provide an alternating electric current flowing between said electrode surfaces with the value of said alternating current being between about 0.08 to 6.0 amperes per square inch of electrode surface; and providing fluid-induced agitation of said liquid media so as to create turbulence therein as the same flows through said bed and between and past the spaced facing surfaces of said electrodes whereby the suspending forces of said solids will be broken so that said solids will agglomerate for removal from said media.
Claim 3
Dependent Claim 6 words
The method of claim 1 comprising:
Claim 4
Dependent Claim 46 words
providing compressed gas causing agitation of said liquid and said bed so as to create turbulence of a Reynolds number of at least about 10,000 in said liquid as the same flows through said bed and between and past the spaced facing surfaces of said electrodes.
Claim 5
Dependent Claim 46 words
providing compressed gas causing agitation of said liquid and said bed so as to create turbulence of a Reynolds number of at least about 10,000 in said liquid as the same flows through said bed and between and past the spaced facing surfaces of said electrodes.
Claim 6
Dependent Claim 31 words
A method as set forth in claim 1 wherein the metal of said electrodes is a member selected from the group consisting of aluminum, an aluminum alloy, iron, magnesium, or steel.
Claim 7
Dependent Claim 32 words
A method as set forth in claim 1 wherein said metal hydroxides are caused to be formed at said electrode surfaces without the presence of alkali-halide salt additives in the said liquid.
Claim 8
Dependent Claim 32 words
A method as set forth in claim 1, wherein said metal hydroxides are caused to be formed at said electrodes without external addition of hydroxides to said liquid passing between said electrodes.
Claim 9
Dependent Claim 39 words
A method as set forth in claim 1 wherein the stated conditions are maintained so that said alternating current passing between said electrodes produces hydrogen peroxide at said electrodes causing said metal hydroxides to be formed at said electrodes.
Claim 10
Dependent Claim 34 words
A method as set forth in claim 1, wherein the facing surfaces of said electrodes are caused to be spaced from each other approximately 1/2 inch at the commencement of operation of such method.
Claim 11
Dependent Claim 30 words
A method as set forth in claim 1, wherein a pH range of between 2 and 9 is maintained during the flow of said liquid past and between said electrodes.
Claim 12
Dependent Claim 19 words
A method as set forth in claim 1, wherein said conductive particles have a specific gravity of about 2.
Claim 13
Dependent Claim 10 words
The method of claim 9 wherein said particles are graphite.
Claim 14
Dependent Claim 12 words
The method of claim 10 wherein said particles are cylindrical in form.

References Cited (Backward Citations)

US741322A Cited
US3457152A Cited
US3523891A Cited
US3692661A Cited
US3716459A Cited
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US3764499A Cited
US3981787A Cited
US3969201A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-10-10 1981-04-11 1981-10-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-10-10 1985-04-11 1985-10-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-10-10 1989-04-11 1989-10-11 $7700.00 Window Closed / Lapsed

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