Rapid curing two part adhesive

Claim 2

A two part adhesive composition consisting essentially of an adhesive base and an activator therefor wherein the adhesive base comprises an acrylic monomer and a saccharin component selected from the group consisting of saccharin, the copper salt of saccharin and mixtures thereof, said saccharin component being present in an amount of 0.01 to 10% by weight of the monomer; and the activator comprises the copper salt of p-toluenesulfonic acid when only saccharin is used in the adhesive base and is a salt of p-toluenesulfinic acid when the copper salt of saccharin is present in the adhesive base.

Claim 3

The adhesive composition of claim 1 wherein the acrylic monomer of the adhesive base is a member of the group consisting of compounds of the formula: ##STR10## wherein R is selected from the group consisting of hydrogen, phenyl, methyl, ethyl or C 1 -C 18 alkoxymethyl and R' is hydrogen or methyl; ii. monofunctional acrylate and methacrylate esters and the amide, cyano, chloro and silane substituted derivatives thereof; ##STR11## wherein R is selected from the group consisting of hydrogen, methyl, ethyl, ##STR12## R' is selected from the group consisting of hydrogen, chlorine, methyl and ethyl; R" is selected from the group consisting of hydrogen, hydroxy, and ##STR13## m is an integer equal to at least 1; n is an integer equal to at least 1; l and p is 0 or 1; ##STR14## wherein R is hydrogen, chlorine, methyl or ethyl, R' is alkylene with 2-6 carbon atoms, R" is selected from the group consisting of (CH 2 ) m in which m is an integer of from 0 to 8, ##STR15## n is an integer of from 1 to 4; ##STR16## wherein X is selected from the group consisting of '0--and ##STR17## R is selected from the group consisting of hydrogen and lower alkyl of 1 to 7 carbon atoms; A is the organic residue of an active hydrogen containing acrylic ester wherein the active hydrogen has been removed, the ester being hydroxy or amino substituted on the alkyl portion thereof, and the methyl, ethyl and chlorine homologs thereof; n is an integer from 1 to 6 inclusive; and B is mono- or polyvalent organic radical selected from the group consisting of alkyl, alkylene, alkenylene, cycloalkyl, cycloalkylene, aryl, aralkyl, alkaryl, poly(carboalkoxyalkylene), and heterocyclic radicals both substituted and unsubstituted; ##STR18## where R 1 is selected from the group consisting of methyl, ethyl, carboxyl or hydrogen; R 2 is selected from the group consisting of hydrogen, methyl or ethyl; R 3 is selected from the group consisting of hydrogen, methyl or hydroxyl; R 4 is selected from the group consisting of hydrogen, chlorine, methyl or ethyl; and n is an integer having a value of 0 to 8.

Claim 4

The composition of claim 1 wherein the acrylic monomer is polymerizable hydroxyethyl acrylate or polymerizable hydroxyethyl methacrylate.

Claim 5

The composition of claim 1 wherein there is present in the adhesive base up to 60% by weight of at least one nonacrylic polymerizable comonomer.

Claim 6

The composition of claim 1 wherein the activator is employed in an amount equal to 0.001 to 1.0 percent by weight of the acrylic monomer.

Claim 7

A process for bonding surfaces comprising the steps of: 1. applying to at least one of such surfaces an adhesive bse consisting essentially of an acrylic monomer and a saccharin component selected from the group consisting of saccharin, the copper salt of saccharin and mixture thereof, said saccharin component being present in an amount of 0.01 to 10% by weight of the monomer;

Claim 8

A process for bonding surfaces comprising the steps of: 1. applying to at least one of such surfaces an adhesive bse consisting essentially of an acrylic monomer and a saccharin component selected from the group consisting of saccharin, the copper salt of saccharin and mixture thereof, said saccharin component being present in an amount of 0.01 to 10% by weight of the monomer;

Claim 9

applying to at least one of such surfaces an activator comprising the copper salt of p-toluenesulfinic acid when only saccharin is used in the adhesive base and a salt of p-toluenesulfonic acid when the copper salt of saccharin is present in the adhesive base; and 3. placing the surfaces so treated in abutting relation until the adhesive composition polymerizes and bonds the surfaces together.

Claim 10

applying to at least one of such surfaces an activator comprising the copper salt of p-toluenesulfinic acid when only saccharin is used in the adhesive base and a salt of p-toluenesulfonic acid when the copper salt of saccharin is present in the adhesive base; and 3. placing the surfaces so treated in abutting relation until the adhesive composition polymerizes and bonds the surfaces together.

Claim 11

The process of claim 6 wherein the acrylic monomer of the adhesive base is a member of the group consisting of compounds of the formula: ##STR19## wherein R is selected from the group consisting of hydrogen, phenyl, methyl, ethyl or C 1 - C 18 alkoxymethyl and R' is hydrogen or methyl; ii. monofunctional acrylate and methacrylate esters and the amide, cyano, chloro and silane substituted derivatives thereof; ##STR20## wherein R is selected from the group consisting of hydrogen, methyl, ethyl, ##STR21## R' is selected from the group consisting of hydrogen, chlorine, methyl and ethyl; R" is selected from the group consisting of hydrogen hydroxy, and ##STR22## m is an integer equal to at least 1; n is an integer equal to at least 1; and p is 0 or 1; ##STR23## wherein R is hydrogen, chlorine, methyl or ethyl, R' is alkylene with 2-6 carbon atoms, R" is selected from the group consisting of (CH 2 ) m in which m is an integer of from 0 to 8, ##STR24## n is an integer of from 1 to 4; ##STR25## wherein X is selected from the group consisting of --0-- and ##STR26## R is selected from the group consisting of hydrogen and lower alkyl of 1 to 7 carbon atoms; A is the organic residue of an active hydrogen containing acrylic ester wherein the active hydrogen has been removed, the ester being hydrogen or amino substituted on the alkyl portion thereof, and the methyl, ethyl and chlorine homologs thereof; n is an integer from 1 to 6 inclusive; and B is a mono- or polyvalent organic radical selected from the group consisting of alkyl, alkylene, alkenylene, cycloalkyl, cycloalkylene, aryl, aralkyl, alkaryl, poly(carboalkoxyalkylene), and heterocyclic radicals both substituted and unsubstituteed; ##STR27## where R 1 is selected from the group consisting of methyl, ethyl, carboxyl or hydrogen; R 2 is selected from the group consisting of hydrogen, methyl, or ethyl; R 3 is selected from the group consisting of hydrogen, methyl or hydroxyl; R 4 is selected from the group consisting of hydrogen, chlorine, methyl or ethyl; and n is an integer having a value of 0 to 8.

Claim 12

The process of claim 6 wherein the acrylic monomer is polymerizable hydroxyethyl acrylate or polymerizable hydroxyethyl methacrylate.

Claim 13

The process of claim 6 wherein there is present in the adhesive base up to 60% by weight of at least one non-acrylic polymerizable comonomer.

Claim 14

The process of claim 6 wherein the activator is employed in an amount equal to 0.001 to 1.0 percent by weight of the acrylic monomer.