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US4050951A
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US
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Process for the post-treatment of titanium dioxide pigments
Assignee: Societa Italiana Resine SpA SIR
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Filing: 1975-12-05
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Granted: 1977-09-27
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Expires: 1995-12-05
Abstract
Abstract Titanium dioxide is post-treated by flowing it in a tubular zone as a suspension in a stream of carrier gas, injecting a gaseous stream of halides of Si, Ti and Al in said stream and then steam in the resulting mixture, once the latter is homogenized.
Inventors
- 👤 Luigi Piccolo
- 👤 Benedetto Calcagno
- 👤 Emilio Bossi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 23:43
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/36; C09C1/3607; C09C1/3653; C09C1/3661; C01; C01P; C01P2004/00; C01P2004/80; C01P2004/82; C01P2004/84
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
190 words
A method for the post-treatment of titanium dioxide pigments, which comprises flowing in an elongated tubular reaction zone a suspension of subdivided particlces of titanium dioxide of a size from about 0.1 to 1 micron in a stream of carrier gas in which particle concentration is from 5 to 50 Kg per m 3 of carrier gas at a temperature of from 100° to 250° C, injecting into said stream at one or more points along said tubular reaction zone a gaseous flow of one or more halides selected from the group consisting of the halides of aluminum, silicon and titanium in an overall amount corresponding to from 1 to 20% by weight, calculated as oxides, with respect to the feed in titanium dioxide, and injecting, downstream of each point of injection of said gaseous flow at a distance from the latter sufficient to allow the homogenization of the resulting mixture therein, a flow of steam in said mixture in an amount of from the stoichiometric value required for the transformation into hydroxides of said halides injected at said point to 50% in excess with respect to said stoichiometric value.
Claim 2
Independent Claim
190 words
A method for the post-treatment of titanium dioxide pigments, which comprises flowing in an elongated tubular reaction zone a suspension of subdivided particlces of titanium dioxide of a size from about 0.1 to 1 micron in a stream of carrier gas in which particle concentration is from 5 to 50 Kg per m 3 of carrier gas at a temperature of from 100° to 250° C, injecting into said stream at one or more points along said tubular reaction zone a gaseous flow of one or more halides selected from the group consisting of the halides of aluminum, silicon and titanium in an overall amount corresponding to from 1 to 20% by weight, calculated as oxides, with respect to the feed in titanium dioxide, and injecting, downstream of each point of injection of said gaseous flow at a distance from the latter sufficient to allow the homogenization of the resulting mixture therein, a flow of steam in said mixture in an amount of from the stoichiometric value required for the transformation into hydroxides of said halides injected at said point to 50% in excess with respect to said stoichiometric value.
Claim 3
Independent Claim
165 words
A method for the post-treatment of titanium dioxide pigments, which comprises flowing in an elongated tubular reaction zone a suspension of subdivided particles of titanium dioxide in a stream of carrier gas at a temperature of from 100° to 250° C, injecting into said stream at one or more points along said tubular reaction zone a gaseous flow of one or more halides selected from the group consisting of the halides of aluminum, silicon and titanium in an overall amount corresponding to from 1 to 20% by weight, calculated as oxides, with respect to the feed in titanium dioxide, and injecting, downstream of each point of injection of said gaseous flow at a distance from the latter sufficient to allow the homogenization of the resulting mixture therein, a flow of steam in said mixture in an amount of from the stoichiometric value required for the transformation into hydroxides of said halides injected at said point to 50% in excess with respect to said stoichiometric value.
Claim 4
Independent Claim
165 words
A method for the post-treatment of titanium dioxide pigments, which comprises flowing in an elongated tubular reaction zone a suspension of subdivided particles of titanium dioxide in a stream of carrier gas at a temperature of from 100° to 250° C, injecting into said stream at one or more points along said tubular reaction zone a gaseous flow of one or more halides selected from the group consisting of the halides of aluminum, silicon and titanium in an overall amount corresponding to from 1 to 20% by weight, calculated as oxides, with respect to the feed in titanium dioxide, and injecting, downstream of each point of injection of said gaseous flow at a distance from the latter sufficient to allow the homogenization of the resulting mixture therein, a flow of steam in said mixture in an amount of from the stoichiometric value required for the transformation into hydroxides of said halides injected at said point to 50% in excess with respect to said stoichiometric value.
Claim 5
Dependent Claim
11 words
The method of claim 2, wherein said carrier gas is air.
Claim 6
Dependent Claim
27 words
The method of claim 2, wherein the concentration in titanium dioxide in said suspension is of from 20 to 35 Kg per m 3 of carrier gas.
Claim 7
Dependent Claim
30 words
The method of claim 2, wherein said overall amount of halides corresponds to from 2 to 8% by weight, calculated as oxides, with respect to the feed in titanium dioxide.
Claim 8
Dependent Claim
10 words
The method of claim 2, wherein said halides are chlorides.
Claim 9
Dependent Claim
50 words
The method of claim 6, wherein said chlorides are injected in an overall amount of aluminum trichloride of from 2 to 4%, of silicon tetrachloride of from 1 to 5% and of titanium tetrachloride of from 0.5 to 2%, calculated as oxides, with respect to the feed in titanium dioxide.
Claim 10
Dependent Claim
19 words
The method of claim 2, wherein said suspension is flowed at a speed of from 2 to 10 m/sec.
Claim 11
Dependent Claim
20 words
The method of claim 2, wherein aluminum chloride, silicon chloride and titanium chloride are injected separately at different injections points.
Claim 12
Dependent Claim
13 words
The method of claim 2, wherein said tubular zone has a constant cross-section.
Claim 13
Dependent Claim
39 words
The method of claim 2, wherein the cross-section of said tubular zone is increased in the direction of flow of the suspension in correspondence with one or more of the injection points of said gaseous flow and steam flow.
Claim 14
Dependent Claim
25 words
The method of claim 2, wherein said distance is of from 6 to 30 times the average diameter of the tubular zone along said distance.
Claim 15
Dependent Claim
31 words
The method of claim 2, wherein the post-treated titanium dioxide is degassed by heating at 200°-250° C in a light flow of air for a period of 1 to 2 hours.
Claim 16
Dependent Claim
30 words
The method of claim 13, wherein said degassed titanium dioxide is calcined at a temperature of from 500° to 700° C for a period of from 1 to 5 hours.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-09-26 | 1981-03-28 | 1981-09-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-09-26 | 1985-03-28 | 1985-09-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-09-26 | 1989-03-28 | 1989-09-27 | $7700.00 | Window Closed / Lapsed |