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US4050576A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymeric sterilant assembly

Assignee: Becton Dickinson and Co
•
Filing: 1976-08-17
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Granted: 1977-09-27
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Expires: 1996-08-17
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Abstract

Abstract Sterilant package including a polyacetal, which contains oxymethylene groups and stabilizing groups therefor, such as oxyethylene groups, which has been irradiated to effect chain cleavage, without depolymerization, whereby upon subsequent heating, the polyacetal is depolymerized with increased release of formaldehyde sterilizing gas.

Inventors

  • 👤 Joel L. Williams
  • 👤 Jerry J. Tulis
  • 👤 Larry A. Taylor

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 18:46
CPC Classifications
A; A61; A61L; A61L2/00; A61L2/16; A61L2/20; A61L2/204

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 78 words
An article of manufacture, comprising: a sterilant package, said sterilant package including in the interior of such package a polyacetal containing oxymethylene groups and stabilizing groups linked to the oxymethylene groups to prevent chain cleavage, said polyacetal having been subjected to high energy irradiation, prior to subjecting said package to heat sterilization, in a dose of from 0.01 to 400 megarads sufficient to effect chain cleavage without depolymerization to increase formaldehyde release upon subsequent heating of the package.
Claim 2
Dependent Claim 78 words
An article of manufacture, comprising: a sterilant package, said sterilant package including in the interior of such package a polyacetal containing oxymethylene groups and stabilizing groups linked to the oxymethylene groups to prevent chain cleavage, said polyacetal having been subjected to high energy irradiation, prior to subjecting said package to heat sterilization, in a dose of from 0.01 to 400 megarads sufficient to effect chain cleavage without depolymerization to increase formaldehyde release upon subsequent heating of the package.
Claim 3
Dependent Claim 19 words
The article of claim 1 wherein at least an interior portion of the package is formed from the polyacetal.
Claim 4
Dependent Claim 17 words
The article of claim 1 wherein the polyacetal is included as a separate piece in the package.
Claim 5
Dependent Claim 19 words
The article of claim 1 wherein the package is formed of a polymer film having the polyacetal dispersed therein.
Claim 6
Dependent Claim 14 words
The article of claim 1 wherein the package includes an article to be sterilized.
Claim 7
Dependent Claim 15 words
The article of claim 1 wherein the irradiation dose was from 0.1 to 40 megarads.
Claim 8
Dependent Claim 39 words
The article of claim 1 wherein the stabilizing group is --OR-- wherein R is a divalent radical including at least two carbon atoms directly linked to each other and included within the polyacetal polymer chain between the two valances.
Claim 9
Dependent Claim 9 words
The article of claim 7 wherein --OR-- is oxyethylene.
Claim 10
Dependent Claim 85 words
In a process for producing a sterilant package including an article to be sterilized, the improvement comprising: including in the interior of the sterilant package a polyacetal containing oxymethylene groups and stabilizing groups linked to the oxymethylene groups to prevent chain cleavage, said polyacetal having been subjected to high energy irradiation, prior to subjecting said package to heat sterilization, in a dose of from 0.01 to 400 megarads sufficient to effect chain cleavage without depolymerization to increase formaldehyde release upon subsequent heating of the package.
Claim 11
Dependent Claim 85 words
In a process for producing a sterilant package including an article to be sterilized, the improvement comprising: including in the interior of the sterilant package a polyacetal containing oxymethylene groups and stabilizing groups linked to the oxymethylene groups to prevent chain cleavage, said polyacetal having been subjected to high energy irradiation, prior to subjecting said package to heat sterilization, in a dose of from 0.01 to 400 megarads sufficient to effect chain cleavage without depolymerization to increase formaldehyde release upon subsequent heating of the package.
Claim 12
Dependent Claim 17 words
The process of claim 9 wherein the polyacetal is included as a separate piece in the package.
Claim 13
Dependent Claim 21 words
The process of claim 9 wherein said polyacetal is included by forming an interior portion of the package from said polyacetal.
Claim 14
Dependent Claim 39 words
The process of claim 9 wherein the stabilizing group is --OR-- wherein R is a divalent radical including at least two carbon atoms directly linked to each other and included with the polyacetal polymer chain between the two valences.
Claim 15
Dependent Claim 9 words
The process of claim 12 wherein --OR-- is oxyethylene.

References Cited (Backward Citations)

US3494726A Cited
US3630348A Cited
US3939971A Cited
US3923154A Cited
US3942634A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-09-26 1981-03-28 1981-09-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-09-26 1985-03-28 1985-09-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-09-26 1989-03-28 1989-09-27 $7700.00 Window Closed / Lapsed

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