Claims Analysis
Total Claims: 36
Claim 1
Independent Claim
226 words
Process for producing thermosetting coating compositions from saturated polyesters containing hydroxy groups and aminoplast resins, characterized in that A. n mols of one or more compounds having two free or latent hydroxy groups are reacted with B. n +1 mols of a dicarboxylic acid which will not form an anhydride, to form a polyester AB carrying terminal carboxy groups, C. thereafter each mol of polyester AB is reacted with an amine alcohol of the general formula HO -- (CX.sub.2).sub.n -- NH.sub.2 n being 2 or 3 and X is equal or different and stands for hydrogen, or an alkyl, aryl or hydroxy alkyl radical, the amount of AB to amine being equal to (e s - e p ) M A wherein M A is the molecular weight of the amine alcohol; e s equals the number of carboxy equivalents in the polyester; and e p equals the number of hydroxy equivalents in the polyester, and not exceeding 2 mols amine alcohol per mol polyester AB, to provide a polyester containing terminal oxazoline groups, D. reacting ABC with an aldehyde in an amount sufficient to introduce sufficient hydroxyl groups at the carbon atoms alpha to the oxazoline group of ABC in order that ABC will undergo reaction with an aminoplast resin, and E. combining ABCD with 10 - 60 percent by weight of an aminoplast resin.
Claim 2
Dependent Claim
226 words
Process for producing thermosetting coating compositions from saturated polyesters containing hydroxy groups and aminoplast resins, characterized in that A. n mols of one or more compounds having two free or latent hydroxy groups are reacted with B. n +1 mols of a dicarboxylic acid which will not form an anhydride, to form a polyester AB carrying terminal carboxy groups, C. thereafter each mol of polyester AB is reacted with an amine alcohol of the general formula HO -- (CX.sub.2).sub.n -- NH.sub.2 n being 2 or 3 and X is equal or different and stands for hydrogen, or an alkyl, aryl or hydroxy alkyl radical, the amount of AB to amine being equal to (e s - e p ) M A wherein M A is the molecular weight of the amine alcohol; e s equals the number of carboxy equivalents in the polyester; and e p equals the number of hydroxy equivalents in the polyester, and not exceeding 2 mols amine alcohol per mol polyester AB, to provide a polyester containing terminal oxazoline groups, D. reacting ABC with an aldehyde in an amount sufficient to introduce sufficient hydroxyl groups at the carbon atoms alpha to the oxazoline group of ABC in order that ABC will undergo reaction with an aminoplast resin, and E. combining ABCD with 10 - 60 percent by weight of an aminoplast resin.
Claim 3
Dependent Claim
12 words
Process according to claim 1 characterized in that the aldehyde is formaldehyde.
Claim 4
Dependent Claim
22 words
Process according to claim 1 characterized in that the average molecular weight of the linear polyester AB ranges between 500 and 10,000.
Claim 5
Dependent Claim
21 words
Process according to claim 3 characterized in that the average molecular weight of the polyester AB ranges between 1,000 and 3,000.
Claim 6
Dependent Claim
52 words
Process according to claim 1 characterized in that the polyester of AB prior to reaction with C is pre-condensed either in situ or subsequently with hydroxyl compounds carrying more than two free hydroxy groups, said pre-condensate having an intrinsic viscosity of a maximum of 20 ml./g. measured in chloroform at 20° C.
Claim 7
Dependent Claim
20 words
Process according to claim 5 characterized in that the polyester is pre-condensed with polyols having three or more hydroxy groups.
Claim 8
Dependent Claim
32 words
Process according to claim 5 characterized in that the polyester is pre-condensed with reaction products of polyols and polycarboxylic acids, the reaction products having an average hydroxy functionality of more than 2.
Claim 9
Dependent Claim
26 words
Process according to claim 1 characterized in that in the general formula for the amine alcohol C, n is 2 and X is a hydroxymethyl radical.
Claim 10
Dependent Claim
42 words
Process according to claim 1 characterized in that in the general formula at least one substituent X is a hydroxyalkyl radical and the reaction product of ABC is reacted with a maximum of 2 moles of aldehyde per mol of amine alcohol.
Claim 11
Dependent Claim
12 words
Process according to claim 9 characterized in that the aldehyde is formaldehyde.
Claim 12
Dependent Claim
22 words
Process according to claim 1 characterized in that the reaction with the amine alcohol is carried out at 150° - 200° C.
Claim 13
Dependent Claim
21 words
Process according to claim 1 characterized in that the acid value of the reaction product of ABC is below 1 mg.KOH/g.
Claim 14
Dependent Claim
21 words
Process according to claim 1 characterized in that the reaction with the aldehyde is carried out at 100° - 150° C.
Claim 15
Dependent Claim
31 words
Process according to claim 1 characterized in that the combination of the reaction product of ABCD with the aminoplast resin is carried out in the presence of solvents at reflux temperature.
Claim 16
Dependent Claim
30 words
Process according to claim 1 characterized in that the combination of the reaction product of ABCD with the aminoplast resin is carried out in the presence of an acid catalyst.
Claim 17
Dependent Claim
15 words
Process according to claim 16 characterzied in that the acid catalyst is p-toluol sulfonic acid.
Claim 18
Dependent Claim
28 words
Process according to claim 1 characterized in that the products are rendered water soluble through reaction with inorganic or organic acids, in the presence of water tolerant solvents.
Claim 19
Dependent Claim
15 words
Process according to claim 17 characterized in that the acid is a hydroxy carboxylic acid.
Claim 20
Dependent Claim
15 words
Process according to claim 18 characterized in that the hydroxy carboxylic acid is lactic acid.
Claim 21
Dependent Claim
13 words
Process according to claim 17 characterized in that the acid is phosphoric acid.
Claim 22
Dependent Claim
11 words
The thermosetting coating composition made by the process of claim 1.
Claim 23
Dependent Claim
213 words
Thermosetting coating composition comprising the reaction product of A. a polyester which is the reaction product of a. n mols of one or more compounds having two free or latent hydroxy groups, and b. n + 1 mols of a dicarboxylic acid which will not form an anhydride, to form a polyester A carrying terminal carboxy groups, B. an amine alcohol of the general formula HO -- (CX.sub.2).sub.n -- NH.sub.2 n being 2 or 3 and X is equal or different and stands for hydrogen, or an alkyl, aryl or hydroxy alkyl radical, the amount of AB to amine being equal to (e s - e p ) M A wherein M A is the molecular weight of the amine alcohol; e s equals the number of carboxy equivalents in the polyester; and e p equals the number of hydroxy equivalents in the polyester, and not exceeding 2 mols amine alcohol per mol polyester AB, to provide a polyester containing terminal oxazoline groups, C. ab is reacted with an aldehyde in an amount sufficient to introduce sufficient hydroxyl groups at the carbon atom alpha to the oxazoline group of ABC in order that ABC will undergo reaction with an aminoplast resin, and D. 10 - 60 percent by weight of an aminoplast resin.
Claim 24
Dependent Claim
213 words
Thermosetting coating composition comprising the reaction product of A. a polyester which is the reaction product of a. n mols of one or more compounds having two free or latent hydroxy groups, and b. n + 1 mols of a dicarboxylic acid which will not form an anhydride, to form a polyester A carrying terminal carboxy groups, B. an amine alcohol of the general formula HO -- (CX.sub.2).sub.n -- NH.sub.2 n being 2 or 3 and X is equal or different and stands for hydrogen, or an alkyl, aryl or hydroxy alkyl radical, the amount of AB to amine being equal to (e s - e p ) M A wherein M A is the molecular weight of the amine alcohol; e s equals the number of carboxy equivalents in the polyester; and e p equals the number of hydroxy equivalents in the polyester, and not exceeding 2 mols amine alcohol per mol polyester AB, to provide a polyester containing terminal oxazoline groups, C. ab is reacted with an aldehyde in an amount sufficient to introduce sufficient hydroxyl groups at the carbon atom alpha to the oxazoline group of ABC in order that ABC will undergo reaction with an aminoplast resin, and D. 10 - 60 percent by weight of an aminoplast resin.
Claim 25
Dependent Claim
10 words
Coating composition of claim 22 wherein the aldehyde is formaldehyde.
Claim 26
Dependent Claim
19 words
Coating composition of claim 22 wherein the average molecular weight of the polyester A ranges between 500 and 10,000.
Claim 27
Dependent Claim
19 words
Coating composition of claim 24 wherein the average molecular weight of the polyester A ranges between 1,000 and 3,000.
Claim 28
Dependent Claim
50 words
Coating composition of claim 22 wherein the polyester of A prior to reaction with B is pre-condensed either in situ or subsequently with hydroxyl compounds carrying more than two free hydroxy groups, said pre-condensate having an intrinsic viscosity of a maximum of 20 ml./g. measured in chloroform at 20° C.
Claim 29
Dependent Claim
25 words
Coating composition of claim 22 wherein in the general formula for the amine alcohol of B, n is 2 and X is a hydroxymethyl radical.
Claim 30
Dependent Claim
42 words
Coating composition of claim 22 wherein in the general formula of B at least one substituent X is a hydroxyalkyl radical and the reaction product of AB is reacted with a maximum of 2 mols of aldehyde per mol or amine alcohol.
Claim 31
Dependent Claim
10 words
Coating composition of claim 28 wherein the aldehyde is formaldehyde.
Claim 32
Dependent Claim
20 words
Coating composition of claim 22 to which sufficient inorganic or orgaic acid is added to render the composition water soluble.
Claim 33
Dependent Claim
13 words
Coating composition of claim 30 wherein the acid is a hydroxy carboxylic acid.
Claim 34
Dependent Claim
11 words
Coating composition of claim 30 wherein the acid is phosphoric acid.
Claim 35
Dependent Claim
13 words
Process according to claim 1 wherein reactions D and E are proceeding simultaneously.
Claim 36
Dependent Claim
14 words
Process according to claim 1 wherein reaction D is complete followed by reaction E.