Patent US4048143A successfully refreshed from Google Patents.
US4048143A
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Process for capping polyphenylene oxide
Assignee: General Electric Co
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Filing: 1975-09-15
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Granted: 1977-09-13
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Expires: 1995-09-15
Abstract
Abstract A process is disclosed which provides for the reduction of the occurrence of oxidative and/or thermal degradation of polyphenylene oxides by contacting the oxides with a capping agent in the presence of a water soluble base, a catalytic phase transfer agent, and, optionally, an effective organic phase reducing agent. The resulting capped polyphenylene oxides can be used to prepare improved articles of manufacture using conventional techniques such as molding, vacuum forming, extrusion, etc.
Inventors
- 👤 Allan S. Hay
- 👤 Dwain M. White
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 08:18
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/34; C08G65/48; C08G65/485
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
154 words
A process comprising contacting a polyphenylene oxide with a capping agent selected from the class consisting of monoacyl halides of the formula ##STR6## hydrocarbon monosulfonyl halides of the formula R--SO 2 --X, anhydrides of monocarboxylic acids of the formula ##STR7## alkyl halides of the formula R-X, dialkyl sulfates of the formula R--O--SO 2 --O--R, wherein R is alkyl, cycloalkyl, or mixtures thereof, X is chlorine, bromine, fluorine or iodine, wherein the mole ratio of capping agent to hydroxyl group per polymer unit is within the range of from about 0.5:1 to about 10:1 and wherein said contacting is carried out at a temperature within the range of from about 0° to about 100° C. in the presence of (1) a water soluble base selected from the class consisting of alkali metal and alkaline earth metal hydroxide or carbonate bases, (2) a catalytic phase transfer agent, and optionally, (3) an effective organic phase reducing agent.
Claim 2
Dependent Claim
154 words
A process comprising contacting a polyphenylene oxide with a capping agent selected from the class consisting of monoacyl halides of the formula ##STR6## hydrocarbon monosulfonyl halides of the formula R--SO 2 --X, anhydrides of monocarboxylic acids of the formula ##STR7## alkyl halides of the formula R-X, dialkyl sulfates of the formula R--O--SO 2 --O--R, wherein R is alkyl, cycloalkyl, or mixtures thereof, X is chlorine, bromine, fluorine or iodine, wherein the mole ratio of capping agent to hydroxyl group per polymer unit is within the range of from about 0.5:1 to about 10:1 and wherein said contacting is carried out at a temperature within the range of from about 0° to about 100° C. in the presence of (1) a water soluble base selected from the class consisting of alkali metal and alkaline earth metal hydroxide or carbonate bases, (2) a catalytic phase transfer agent, and optionally, (3) an effective organic phase reducing agent.
Claim 3
Dependent Claim
154 words
A process comprising contacting a polyphenylene oxide with a capping agent selected from the class consisting of monoacyl halides of the formula ##STR8## hydrocarbon monosulfonyl halides of the formula R-SO 2 -X, anhydrides of monocarboxylic acids of the formula ##STR9## alkyl halides of the formula R--X, dialkyl sulfates of the formula R--O--SO 2 --O--R, wherein R is alkyl, cycloalkyl, or mixtures thereof, X is chlorine, bromine, fluorine or iodine, wherein the mole ratio of capping agent to hydroxyl group per polymer unit is within the range of from about 0.5:1 to about 1:1 and wherein said contacting is carried out at a temperature within the range of from about 15° to about 80° C. in the presence of (1) a water soluble base selected from the class consisting of alkali metal and alkaline earth metal hydroxide or carbonate bases, (2) a catalytic phase transfer agent, and optionally, (3) an effective organic phase reducing agent.
Claim 4
Dependent Claim
154 words
A process comprising contacting a polyphenylene oxide with a capping agent selected from the class consisting of monoacyl halides of the formula ##STR8## hydrocarbon monosulfonyl halides of the formula R-SO 2 -X, anhydrides of monocarboxylic acids of the formula ##STR9## alkyl halides of the formula R--X, dialkyl sulfates of the formula R--O--SO 2 --O--R, wherein R is alkyl, cycloalkyl, or mixtures thereof, X is chlorine, bromine, fluorine or iodine, wherein the mole ratio of capping agent to hydroxyl group per polymer unit is within the range of from about 0.5:1 to about 1:1 and wherein said contacting is carried out at a temperature within the range of from about 15° to about 80° C. in the presence of (1) a water soluble base selected from the class consisting of alkali metal and alkaline earth metal hydroxide or carbonate bases, (2) a catalytic phase transfer agent, and optionally, (3) an effective organic phase reducing agent.
Claim 5
Dependent Claim
39 words
The claim 2 process, wherein the process sequence comprises contacting sequentially the polyphenylene oxide reaction mixture with -- first -- an effective organic phase reducing agent and a water soluble base, and -- second -- with a capping agent.
Claim 6
Dependent Claim
38 words
The claim 3 process, wherein the amount of capping agent present is an amount sufficient to react with substantially all of the hydroxyl groups contained by polymer units, any unreacted phenolic compounds and other low molecular weight oligomers.
Claim 7
Dependent Claim
47 words
The claim 4 process, wherein said polyphenylene oxide is 2,6-dimethyl-1,4-polyphenylene oxide, said catalytic phase transfer agent is selected from quaternary ammonium compounds, quaternary phosphonium compounds, tertiary sulfonium compounds, or mixtures thereof, said base is an alkali metal water soluble base, and said capping agent is acetic anhydride.
Claim 8
Dependent Claim
12 words
The claim 4 process, further comprising recovering the resulting capped polyphenylene oxide.
Claim 9
Dependent Claim
23 words
The claim 6 process, wherein said recovering is carried out at temperatures within the range of from about 0° to about 50° C.
Claim 10
Dependent Claim
60 words
A process in accordance with claim 2, wherein the process sequence comprises contacting sequentially: (1) a polyphenylene oxide reaction mixture and an effective organic phase reducing agent which contains cations selected from quaternary ammonium, quaternary phosphonium and tertiary sulfonium ions and an anion selected from dithionite, dithiosulfate and borohydride ions, (2) a water soluble base, and (3) a capping agent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-09-12 | 1981-03-14 | 1981-09-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-09-12 | 1985-03-14 | 1985-09-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-09-12 | 1989-03-14 | 1989-09-13 | $7700.00 | Window Closed / Lapsed |