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US4046705A Expired / Lapsed US ⏱️ 0.0 years remaining

Stable bleaching detergent composition

Assignee: Kao Corp
•
Filing: 1976-05-21
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Granted: 1977-09-06
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Expires: 1996-05-21
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Abstract

Abstract A stable bleaching detergent composition comprising an inorganic peroxide and a compound having the formula: ##STR1## wherein R 1 is hydrogen or alkyl having 1 to 3 carbon atoms, ##STR2## is a radical of an unsaturated 5 member or 6 member heterocyclic ring system containing only nitrogen and carbon atoms in the ring, which can be fused to a benzene ring or another heterocyclic ring to give a polycyclic radical, R 2 is hydrogen or substituted or unsubstituted alkyl having 1 to 10 carbon atoms, substituted or unsubstituted phenyl, pyridyl or pyrrolidone group, R 3 is hydrogen, substituted or unsubstituted alkyl, phenyl, alkoxy, phenoxy, amino, acyloxy, carbamoyl or acyl group or halogen, or R 3 may form together with R 4 a benzo radical, and R 4 is hydrogen or a monovalent group --R 5 Y in which R 5 is alkylene or alkylidene having 1 to 6 carbon atoms or a phenylene group and Y is a group corresponding to the residue of the above general formula from which R 4 has been removed, or R 4 may form a benzo group together with R 3 .

Inventors

  • 👤 Kouichi Yagi
  • 👤 Makoto Yamanaka
  • 👤 Takashi Fujino

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 22:31
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/39; C11D3/3902; C11D3/3937; C11D3/394; C11D3/16; C11D3/26; C11D3/28; C11D3/3945

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 432 words
A stable bleaching detergent composition, consisting essentially of: A. from about one to about 30 percent by weight of a surfactant selected from the group consisting of water-soluble anionic surfactant, water-soluble nonionic surfactant, water-soluble amphoteric surfactant and mixtures thereof; B. from about one to about 50 percent by weight of an inorganic peroxygen compound capable of releasing oxygen in aqueous solution; C. the balance is a substance selected from the group consisting of water-soluble neutral inorganic builder salts, water-soluble alkaline inorganic builder salts, water-soluble organic builders and mixtures thereof; and D. from 0.001 to 5 parts by weight, per 100 parts by weight of the sum of the weights of A plus B plus C, of a compound or mixture of compounds having the formula ##STR35## wherein R 1 is hydrogen or alkyl having one to 3 carbon atoms; ##STR36## is a monovalent radical of an unsaturated 5 member or 6 member heterocyclic ring containing only nitrogen and carbon atoms in the ring, or said heterocylic ring fused to a benzene ring or another heterocyclic ring to give a polycyclic radical having the characteristic ##STR37## grouping; R 2 is hydrogen, unsubstituted alkyl having one to 10 carbon atoms, alkyl having one to 10 carbon atoms substituted with hydroxy, chloro, amino, alkoxy (C 1 to C 10 ), phenoxy, phenyl, hydroxyphenyl or benzoylamino, unsubstituted phenyl, phenyl substituted with one or two alkyls (C 1 to C 2 ), chloro, hydroxy, alkoxy (C 1 to C 10 ), acyloxy (C 1 to C 4 ) or amino, aroyl having 6 to 8 carbon atoms, pyridyl or oxopyrrolidinyl; R 3 is hydrogen, unsubstituted alkyl having one to 22 carbon atoms, alkyl having one to 22 carbon atom substituted with hydroxy, chloro, alkoxy (C 1 to C 4 ), phenoxy, phenyl or amino, phenyl, phenyl substituted with one or 2 alkyls having one or 2 carbon atoms or alkoxy (C 1 to C 10 ), aroyl having 6 to 8 carbon atoms, alkoxy having one to 10 carbon atoms, phenoxy, halogen, alkylamino (C 1 to C 10 ), aminosulfonamido, alkanoyloxy (C 2 to C 6 ), aroyloxy (C 6 to C 8 ), carbamoyl, alkoxy (C 1 to C 10 ) carbonyl and aryl (C 6 to C 8 ) oxycarbonyl, or R 3 and R 4 together form a benzo group; and R 4 is hydrogen or --R 5 Y, in which R 5 is alkylene having one to 6 carbons, alkylidene having one to 6 carbons or phenylene, and Y is a radical obtained by removing R 4 from a compound of said formula.
Claim 2
Dependent Claim 432 words
A stable bleaching detergent composition, consisting essentially of: A. from about one to about 30 percent by weight of a surfactant selected from the group consisting of water-soluble anionic surfactant, water-soluble nonionic surfactant, water-soluble amphoteric surfactant and mixtures thereof; B. from about one to about 50 percent by weight of an inorganic peroxygen compound capable of releasing oxygen in aqueous solution; C. the balance is a substance selected from the group consisting of water-soluble neutral inorganic builder salts, water-soluble alkaline inorganic builder salts, water-soluble organic builders and mixtures thereof; and D. from 0.001 to 5 parts by weight, per 100 parts by weight of the sum of the weights of A plus B plus C, of a compound or mixture of compounds having the formula ##STR35## wherein R 1 is hydrogen or alkyl having one to 3 carbon atoms; ##STR36## is a monovalent radical of an unsaturated 5 member or 6 member heterocyclic ring containing only nitrogen and carbon atoms in the ring, or said heterocylic ring fused to a benzene ring or another heterocyclic ring to give a polycyclic radical having the characteristic ##STR37## grouping; R 2 is hydrogen, unsubstituted alkyl having one to 10 carbon atoms, alkyl having one to 10 carbon atoms substituted with hydroxy, chloro, amino, alkoxy (C 1 to C 10 ), phenoxy, phenyl, hydroxyphenyl or benzoylamino, unsubstituted phenyl, phenyl substituted with one or two alkyls (C 1 to C 2 ), chloro, hydroxy, alkoxy (C 1 to C 10 ), acyloxy (C 1 to C 4 ) or amino, aroyl having 6 to 8 carbon atoms, pyridyl or oxopyrrolidinyl; R 3 is hydrogen, unsubstituted alkyl having one to 22 carbon atoms, alkyl having one to 22 carbon atom substituted with hydroxy, chloro, alkoxy (C 1 to C 4 ), phenoxy, phenyl or amino, phenyl, phenyl substituted with one or 2 alkyls having one or 2 carbon atoms or alkoxy (C 1 to C 10 ), aroyl having 6 to 8 carbon atoms, alkoxy having one to 10 carbon atoms, phenoxy, halogen, alkylamino (C 1 to C 10 ), aminosulfonamido, alkanoyloxy (C 2 to C 6 ), aroyloxy (C 6 to C 8 ), carbamoyl, alkoxy (C 1 to C 10 ) carbonyl and aryl (C 6 to C 8 ) oxycarbonyl, or R 3 and R 4 together form a benzo group; and R 4 is hydrogen or --R 5 Y, in which R 5 is alkylene having one to 6 carbons, alkylidene having one to 6 carbons or phenylene, and Y is a radical obtained by removing R 4 from a compound of said formula.
Claim 3
Dependent Claim 51 words
A composition as claimed in claim 1 in which the amount of B is from 5 to 30 percent by weight and the amount of D is from 0.01 to 3 parts by weight, per 100 parts by weight of the sum of the weights of A plus B plus C.
Claim 4
Dependent Claim 32 words
A composition as claimed in claim 1 in which said peroxygen compound is selected from the group consisting of peroxides and hydrogen peroxide adducts of water-soluble carbonates, borates, phosphates, sulfates, and silicates.
Claim 5
Dependent Claim 28 words
A composition as claimed in claim 1 in which said peroxygen compound is selected from the group consisting of sodium percarbonate, sodium perborate, sodium peroxypyrophosphate and sodium peroxytripolyphosphate.
Claim 6
Dependent Claim 15 words
A composition as claimed in claim 1 in which said peroxygen compound is sodium percarbonate.
Claim 7
Dependent Claim 42 words
A composition as claimed in claim 1 in which ##STR38## is a radical of a heterocyclic ring selected from the group consisting of triazole, triazine, tetrazole, tetrazine, imidazole, benzoimidazole, indazole, imidazoline, pyrazole, benzopyrazole, 5-pyrazolone, pyrazine, pyridazine, pyrimidine, quinoline, indolenine, pyrazoline, and quinazoline.
Claim 8
Dependent Claim 15 words
A composition as claimed in claim 1 in which ##STR39## is a radical of triazole.

References Cited (Backward Citations)

US3816324A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-09-05 1981-03-07 1981-09-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-09-05 1985-03-07 1985-09-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-09-05 1989-03-07 1989-09-06 $7700.00 Window Closed / Lapsed

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