US4044831A
Expired / Lapsed
US
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Secondary recovery process utilizing water saturated with gas
Assignee: Texaco Inc
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Filing: 1975-04-02
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Granted: 1977-08-30
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Expires: 1995-04-02
Abstract
Abstract Hydrocarbons are recovered from subterranean formations by injecting into a hydrocarbon bearing formation via an injection well a fluid comprising water saturated with a gas such as natural gas, carbon dioxide, etc., forcing the said fluid through the formation and recovering hydrocarbons through a production well.
Inventors
- 👤 Joseph C. Allen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 13:27
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/58; C09K8/584; C09K8/594; E; E21; E21B; E21B43/00; E21B43/16; E21B43/164; E21B43/20; Y; Y10; Y10S; Y10S507/00; Y10S507/935; Y10S507/936
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
201 words
A process for recovering hydrocarbons from a subterranean hydrocarbon-bearing formation penetrated by an injecting well and a production well which comprises: a. injecting into the formation via an injection well a fluid comprising water saturated at the injection pressure with a gas selected from the groups consisting of natural gas, carbon dioxide, ammonia, flue gas, and mixtures thereof, and containing a minor amount of a solubilizing agent selected from the group consisting of compounds of the formula: R(OR').sub.a OH (A) wherein R is selected from the group consisting of: ##STR8## R' is alkylene of from 2 to 5 carbon atoms and a is an integer of from about 5 to about 50, R(OC.sub.3 H.sub.6).sub.b --(OC.sub.2 H.sub.4).sub.c (B) wherein R has the same meaning as previously described, b is an integer of from about 3 to about 20, c is an integer of from about 10 to about 50 and wherein the sum of b plus c is not more than about 60, and ##STR9## wherein R' has the same meaning as previously described and d is an integer of from about 5 to about 50, b. forcing the said fluid through the formation, and c. recovering hydrocarbons through the production well.
Claim 2
Dependent Claim
201 words
A process for recovering hydrocarbons from a subterranean hydrocarbon-bearing formation penetrated by an injecting well and a production well which comprises: a. injecting into the formation via an injection well a fluid comprising water saturated at the injection pressure with a gas selected from the groups consisting of natural gas, carbon dioxide, ammonia, flue gas, and mixtures thereof, and containing a minor amount of a solubilizing agent selected from the group consisting of compounds of the formula: R(OR').sub.a OH (A) wherein R is selected from the group consisting of: ##STR8## R' is alkylene of from 2 to 5 carbon atoms and a is an integer of from about 5 to about 50, R(OC.sub.3 H.sub.6).sub.b --(OC.sub.2 H.sub.4).sub.c (B) wherein R has the same meaning as previously described, b is an integer of from about 3 to about 20, c is an integer of from about 10 to about 50 and wherein the sum of b plus c is not more than about 60, and ##STR9## wherein R' has the same meaning as previously described and d is an integer of from about 5 to about 50, b. forcing the said fluid through the formation, and c. recovering hydrocarbons through the production well.
Claim 3
Dependent Claim
13 words
The process of claim 1 wherein the said gas-saturated water contains a surfactant.
Claim 4
Dependent Claim
16 words
The process of claim 1 wherein the gas employed to saturate the water is natural gas.
Claim 5
Dependent Claim
21 words
The method of claim 1 wherein in step (a) the water-saturated with gas is heated to formation temperature prior to injection.
Claim 6
Dependent Claim
12 words
The process of claim 1 wherein the said gas is carbon dioxide.
Claim 7
Dependent Claim
26 words
The process of claim 1 wherein an alkaline agent selected from the group consisting of sodium hydroxide and sodium hypochlorite is included with the said fluid.
Claim 8
Dependent Claim
20 words
The process of claim 6, wherein the water saturated with gas is made alkaline through the addition of sodium hydroxide.
Claim 9
Dependent Claim
23 words
The process of claim 6 wherein in step (a) the water saturated with gas is made alkaline by the addition of sodium hypochlorite.
Claim 10
Dependent Claim
47 words
The process of claim 1 wherein the said solubilizing agent is a compound of the formula: R(OR').sub.a OH wherein R is selected from the group consisting of: ##STR10## R' is alkylene of from 2 to 5 carbon atoms and a is from about 5 to about 50.
Claim 11
Dependent Claim
40 words
The process of claim 1 wherein the said solubilizing agent is a compound of the formula: ##STR11## wherein R' is alkylene of from 2 to 5 carbon atoms and d is an integer of from about 5 to about 50.
Claim 12
Dependent Claim
64 words
The process of claim 1 wherein the said solubilizing agent is a compound of the formula: R(OC.sub.3 H.sub.6).sub.b (OC.sub.2 H.sub.4).sub.c OH wherein R is selected from the group consisting: ##STR12## b is an integer of from about 3 to about 20, c is an integer of from about 10 to about 50 and the sum of b plus c is not more than 60.
Claim 13
Dependent Claim
150 words
A fluid comprising water-saturated with a gas selected from the group consisting of natural gas, carbon dioxide, ammonia, flue gas and mixtures thereof containing a minor amount of a solubilizing agent selected from the group consisting of compounds of the formula: R(OR').sub.a OH (A) wherein R is selected from the group consisting of: ##STR13## R' is alkylene of from 2 to 5 carbon atoms and a is an integer of from about 5 to about 50, R(OC.sub.3 H.sub.6).sub.b (OC.sub.2 H 4).sub.c (B) wherein R has the same meaning as previously described, b is an integer of from about 3 to about 20, c is an integer of from about 10 to about 50 and wherein the sum of b plus c is not more than about 60, and ##STR14## wherein R' has the same meaning as previously described and d is an integer of from about 5 to about 50.
Claim 14
Dependent Claim
150 words
A fluid comprising water-saturated with a gas selected from the group consisting of natural gas, carbon dioxide, ammonia, flue gas and mixtures thereof containing a minor amount of a solubilizing agent selected from the group consisting of compounds of the formula: R(OR').sub.a OH (A) wherein R is selected from the group consisting of: ##STR13## R' is alkylene of from 2 to 5 carbon atoms and a is an integer of from about 5 to about 50, R(OC.sub.3 H.sub.6).sub.b (OC.sub.2 H 4).sub.c (B) wherein R has the same meaning as previously described, b is an integer of from about 3 to about 20, c is an integer of from about 10 to about 50 and wherein the sum of b plus c is not more than about 60, and ##STR14## wherein R' has the same meaning as previously described and d is an integer of from about 5 to about 50.
Claim 15
Dependent Claim
40 words
The fluid of claim 12 wherein the said solubilizing agent is a compound of the formula: ##STR15## wherein R' is alkylene of from 2 to 5 carbon atoms and d is an integer of from about 5 to about 50.
Claim 16
Dependent Claim
67 words
The fluid of claim 12 wherein the said solubilizing agent is a compound of the formula: R (OC.sub.3 H.sub.6).sub.b (OC.sub.2 H.sub.4).sub.c OH wherein R is selected from the group consisting of: ##STR16## b is an integer of from about 3 to about 20, c is an integer of from about 10 to about 50 and wherein the sum of b plus c is more than about 60.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-29 | 1981-02-28 | 1981-08-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-29 | 1985-02-28 | 1985-08-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-29 | 1989-02-28 | 1989-08-30 | $7700.00 | Window Closed / Lapsed |