Patent US4043969A successfully refreshed from Google Patents.
US4043969A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Casting compound for semiconductor devices
Assignee: National Semiconductor Corp
•
Filing: 1975-04-14
•
Granted: 1977-08-23
•
Expires: 1995-04-14
Abstract
Abstract Casting composition for semiconductor devices composed of an aliphatic, preferably cycloaliphatic polyepoxide, a dicarboxylic acid anhydride, a catalyst and a finely ground fused silica which has been surface treated, e.g., with a silazane, to replace the hydrogens of silanol groups with hydrophobic groups.
Inventors
- 👤 Christian R. Sporck
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 20:33
CPC Classifications
H; H10; H10W; H10W74/00; H10W74/40; H10W74/47; C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/42; C08G59/68; C08K; C08K9/00; C08K9/04; C08K9/06; C08L; C08L63/00; C08L63/04; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/40; H10W76/00; H10W76/40; H10W76/42; H10W76/43
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
257 words
A curable composition which is liquid at room temperature or at a slightly elevated temperature and which comprises a. a major proportion of a polyepoxide A--(X).sub.a --B wherein A and B are selected from the class of (1) cycloaliphatic groups, (2) open chain aliphatic groups and (3) segments of a cycloaliphatic single ring or fused ring systems, A and B each containing an epoxide group, X is a linking entity selected from the class of a valence bond and an atom or group of atoms and a is unity except where A and B belong to group (3) in which case a is zero; b. a cross-linking agent in the form of an anhydride of a polycarboxylic acid ##STR25## wherein R is a cycloaliphatic group, an open chain aliphatic group or an aromatic group c. a catalyst capable of promoting polymerizing and cross-linking of (a) and (b); and d. a filler in the form of a finely divided fused silica the surface of which has been treated with a substance to convert silanol groups to groups ##STR26## wherein the R 3 's are the same or different hydrocarbon groups said components (a) and (b) being present in amounts and proportions to enable the composition to cure at temperatures not greater than about 175° C, to a hard product; said components (a), (b) and (d) being selected and their proportions being such that the composition is a pourable liquid at temperatures not greater than about 40° C and is free of significant quantities of chloride and sodium ions.
Claim 2
Dependent Claim
257 words
A curable composition which is liquid at room temperature or at a slightly elevated temperature and which comprises a. a major proportion of a polyepoxide A--(X).sub.a --B wherein A and B are selected from the class of (1) cycloaliphatic groups, (2) open chain aliphatic groups and (3) segments of a cycloaliphatic single ring or fused ring systems, A and B each containing an epoxide group, X is a linking entity selected from the class of a valence bond and an atom or group of atoms and a is unity except where A and B belong to group (3) in which case a is zero; b. a cross-linking agent in the form of an anhydride of a polycarboxylic acid ##STR25## wherein R is a cycloaliphatic group, an open chain aliphatic group or an aromatic group c. a catalyst capable of promoting polymerizing and cross-linking of (a) and (b); and d. a filler in the form of a finely divided fused silica the surface of which has been treated with a substance to convert silanol groups to groups ##STR26## wherein the R 3 's are the same or different hydrocarbon groups said components (a) and (b) being present in amounts and proportions to enable the composition to cure at temperatures not greater than about 175° C, to a hard product; said components (a), (b) and (d) being selected and their proportions being such that the composition is a pourable liquid at temperatures not greater than about 40° C and is free of significant quantities of chloride and sodium ions.
Claim 3
Dependent Claim
24 words
The composition of claim 1 wherein (a) is a cycloaliphatic polyepoxide in which at least one of A and B is a cycloaliphatic group.
Claim 4
Dependent Claim
19 words
The composition of claim 2 wherein A and B are cycloaliphatic groups and (b) is a cycloaliphatic dicarboxylic anhydride.
Claim 5
Dependent Claim
80 words
A composition as in claim 1 wherein both A and B are epoxidized cyclohexyl groups, (b) is hexahydrophthalic anhydride, (c) is selected from the class of (1) salts of a fatty acid and a divalent metal ion which constitutes a Lewis acid and (2) Lewis bases; and the filler (d) has a fineness and is present in a quantity such that the composition will adhere as a layer of substantial thickness when poured onto a solid surface at room temperature.
Claim 6
Dependent Claim
12 words
The composition of claim 1 wherein the R 3 's are methyl.
Claim 7
Dependent Claim
196 words
A casting composition suitable for use at a temperature not exceeding about 40° C to pour onto a flat semiconductor surface and to adhere to such surface at such temperature in substantial thickness, said composition having a fast hot plate cure at 170° C, being free of significant amounts of halide and alkali metal ions and when cured having a glass transition temperature substantially above 100° C and a coefficient of thermal expansion at temperatures below its glass transition temperature substantially less than 30, said composition comprising: a. a curable mixture of a cycloaliphatic polyepoxide and an anhydride of a cycloaliphatic polycarboxylic acid in proportion such that on curing they copolymerize to a thermoset resin, b. a catalyst capable of catalyzing such copolymerization, said catalyst being free of alkali metal and halogen, and c. a silica filler constituting not less than about 70% of the weight of the composition, said silica filler being a finely ground fused silica surface treated with a silazane to eliminate free silanol groups on the surface of the silica and to replace such groups with groups ---- Si(R.sub.3).sub.3 wherein the R 3 's are the same or different lower alkyl groups.
Claim 8
Dependent Claim
196 words
A casting composition suitable for use at a temperature not exceeding about 40° C to pour onto a flat semiconductor surface and to adhere to such surface at such temperature in substantial thickness, said composition having a fast hot plate cure at 170° C, being free of significant amounts of halide and alkali metal ions and when cured having a glass transition temperature substantially above 100° C and a coefficient of thermal expansion at temperatures below its glass transition temperature substantially less than 30, said composition comprising: a. a curable mixture of a cycloaliphatic polyepoxide and an anhydride of a cycloaliphatic polycarboxylic acid in proportion such that on curing they copolymerize to a thermoset resin, b. a catalyst capable of catalyzing such copolymerization, said catalyst being free of alkali metal and halogen, and c. a silica filler constituting not less than about 70% of the weight of the composition, said silica filler being a finely ground fused silica surface treated with a silazane to eliminate free silanol groups on the surface of the silica and to replace such groups with groups ---- Si(R.sub.3).sub.3 wherein the R 3 's are the same or different lower alkyl groups.
Claim 9
Dependent Claim
33 words
The composition of claim 6 wherein: 1. the cycloaliphatic polyepoxide has the structure ##STR27## wherein X is a linking group and the six membered cycloaliphatic rings may be substituted by lower alkyl; and
Claim 10
Dependent Claim
18 words
the anhydride is hexahydrophthalic anhydride in which the six membered cycloaliphatic ring may be substituted by lower alkyl.
Claim 11
Dependent Claim
18 words
the anhydride is hexahydrophthalic anhydride in which the six membered cycloaliphatic ring may be substituted by lower alkyl.
References Cited (Backward Citations)
US2890196A
Cited
US2965610A
Cited
US3194784A
Cited
US3290165A
Cited
US3635743A
Cited
US3627724A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-22 | 1981-02-21 | 1981-08-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-22 | 1985-02-21 | 1985-08-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-22 | 1989-02-21 | 1989-08-23 | $7700.00 | Window Closed / Lapsed |