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US4043934A
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Catalyst and method for oxidizing reducing gases
Assignee: University of California, San Diego
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Filing: 1975-03-31
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Granted: 1977-08-23
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Expires: 1995-03-31
Abstract
Abstract A reducing gas, such as, carbon monoxide (CO) or unsaturated hydrocarbons, is oxidized by contacting a mixture of the gas and oxygen with a catalyst or reagent which includes palladium sulfate and ammonium molybdate adsorbed on silica gel. The reducing gas is oxidized by the reagent and simultaneously reduces the reagent from a first oxidation state to a second, with an accompanying color change, which indicates the presence of the reducing gas. If the reducing gas is an unsaturated hydrocarbon it can be converted to an oxygenated hydrocarbon. A salt of a transition metal (such as, copper, iron, or nickel) is included in the reagent so it is oxidized back to the first state (regenerated) by atmospheric oxygen. The catalyst also promotes the synthesis of oxygenated hydrocarbons from the reaction of unsaturated hydrocarbons with other hydrocarbons.
Inventors
- 👤 Kurt E. Shuler
- 👤 Gerhard N. Schrauzer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 22:07
CPC Classifications
G; G01; G01N; G01N31/00; G01N31/22; G01N31/223; G01N31/224; B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/62; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; C; C07; C07C; C07C45/00; C07C45/27; C07C45/32; C07C45/33; C07C45/34; C07C45/35; G01N31/005; Y; Y02; Y02A; Y02A50/00; Y02A50/20; Y02P; Y02P20/00; Y02P20/50; Y02P20/582; Y10; Y10S; Y10S55/00; Y10S55/30; Y10T; Y10T436/00; Y10T436/18; Y10T436/182; Y10T436/184; Y10T436/20; Y10T436/204998; Y10T436/205831; Y10T436/21; Y10T436/214; Y10T436/216
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
121 words
A reagent which is self-regenerating in air, and which, on contact with a reducing gas, oxidizes the gas and is reduced from an oxidized state to a reduced state, the reagent comprising a mixture of a palladium salt, a compound which includes a complex ion of a metal selected from the group consisting of molybdenum, tungsten and vanadium, and a salt of a metal selected from the group consisting of copper, nickel and iron, said salt being present in an amount sufficient to cause the reagent to oxidize from the reduced state caused by contact with the reducing gas to the oxidized state in the presence of air and absence of the reducing gas, and a hydrophilic carrier for the mixture.
Claim 2
Dependent Claim
121 words
A reagent which is self-regenerating in air, and which, on contact with a reducing gas, oxidizes the gas and is reduced from an oxidized state to a reduced state, the reagent comprising a mixture of a palladium salt, a compound which includes a complex ion of a metal selected from the group consisting of molybdenum, tungsten and vanadium, and a salt of a metal selected from the group consisting of copper, nickel and iron, said salt being present in an amount sufficient to cause the reagent to oxidize from the reduced state caused by contact with the reducing gas to the oxidized state in the presence of air and absence of the reducing gas, and a hydrophilic carrier for the mixture.
Claim 3
Dependent Claim
18 words
A reagent according to claim 1 in which the mixture is deposited on a carrier containing OH groups.
Claim 4
Dependent Claim
31 words
A reagent according to claim 1 in which the mixture is deposited on a carrier selected from the group consisting of polymeric alcohols, polyglycols, cellulose, silica, alumina, glass wool, and sponge.
Claim 5
Dependent Claim
24 words
A reagent according to claim 1 in which the mixture is a solid powder having a particle size which passes through about 50 mesh.
Claim 6
Dependent Claim
37 words
A reagent for oxidizing a reducing gas comprising a silica gel coated with a mixture of a palladium salt, a molybdate complex, and a salt of a meta selected from the group consisting of copper and nickel.
Claim 7
Dependent Claim
37 words
A reagent for oxidizing a reducing gas comprising a silica gel coated with a mixture of a palladium salt, a molybdate complex, and a salt of a meta selected from the group consisting of copper and nickel.
Claim 8
Dependent Claim
36 words
A reagent according to claim 5 in which the palladium salt is selected from the group consisting of PdSO 4 , Pd 2 Cl, Pd(NO 3 ) 2 , palladium acetate, palladium trifluoroacetate and palladium acetylacetonate.
Claim 9
Dependent Claim
14 words
A reagent according to claim 5 in which the molybdate complex is a silicomolybdate.
Claim 10
Dependent Claim
57 words
A reagent according to claim 7 in which the silicomolybdate complex is a product of the reaction between silica gel and a material selected from the group consisting of a heteropolyacid of molybdenum, a water-soluble salt of a molybdic acid, a water-soluble salt of a heteropolyacid of molybdenum, a molybdic acid phosphate, and a molybdic acid borate.
Claim 11
Dependent Claim
56 words
A reagent according to claim 7 in which the silicomolybdate complex is a product of the reaction between silica gel in a mildly acid aqueous suspension and MoCl 5 , KMoCl 6 , Li 2 MoO 4 , Na 2 MoO 4 , K 2 MoO 4 , and (NH 4 ) 2 MoO 4 .
Claim 12
Dependent Claim
49 words
A reagent according to claim 5 which includes a salt selected from the group consisting of CuF 2 , CuCl 2 , CuI 2 , CuBr 2 , CuSO 4 , Cu(NO 3 ) 2 , copper formate, copper acetate, copper trifluoroacetate , copper acetylacetonate, and NiCl 2 .
Claim 13
Dependent Claim
47 words
A reagent according to claim 5 which includes a silicomolybdate complex, which is oxidized by atmospheric oxygen to one oxidation state at which it exhibits a characteristic color, and which is reduced by a reducing gas to a lower oxidation state where it has a different color.
References Cited (Backward Citations)
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1980-08-22 | 1981-02-21 | 1981-08-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-22 | 1985-02-21 | 1985-08-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-22 | 1989-02-21 | 1989-08-23 | $7700.00 | Window Closed / Lapsed |