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Hydrocarbon upgrading process

Assignee: Texaco Inc
•
Filing: 1973-12-26
•
Granted: 1977-08-16
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Expires: 1993-12-26
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Abstract

Abstract A process for converting mixtures of C 6 to C 30 n-paraffin and n-paraffin by-products to substantially pure n-paraffin which comprises catalytically hydrogenating the mixture at a temperature of from about 600° to 750° F. in the presence of a Group VIII metal on alumina catalyst where the catalyst contains from about 0.05 to 2.0 weight percent of an alkali metal oxide or alkaline earth metal oxide or thallous oxide. The catalyst can additionally contain a Group VIB or VIIB metal.

Inventors

  • 👤 Robert M. Suggitt
  • 👤 Walter C. Gates, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 22:22
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/02; C10G45/04; B; B01; B01J; B01J23/00; B01J23/38; B01J23/54; B01J23/56; B01J23/58; B01J23/70; B01J23/76; B01J23/78; B01J23/84; C07; C07C; C07C7/00; C07C7/148; C07C7/163

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 128 words
In a process for selectively converting a mixture of n-paraffin and oxygenated n-paraffin by-products, said n-paraffin and by-products having from 6 to 30 carbon atoms, to a substantially pure n-paraffin recycle feedstock by catalytically hydrogenating said mixture and converting said oxygenated n-paraffin by-products to the corresponding n-paraffin, the improvement which comprises catalytically hydrogenating said mixture in the absence of substantial isomerization and hydrocracking at a temperature of from about 600° to 750° F. in the presence of a catalyst composed of alumina, from about 0.1 to 5.0 weight percent of a Group VIII metal and from about 0.05 to 2.0 weight percent of an alkali metal oxide or alkaline earth metal oxide or thallous oxide or mixtures thereof impregnated on said alumina to convert said by-products to n-paraffins.
Claim 2
Dependent Claim 128 words
In a process for selectively converting a mixture of n-paraffin and oxygenated n-paraffin by-products, said n-paraffin and by-products having from 6 to 30 carbon atoms, to a substantially pure n-paraffin recycle feedstock by catalytically hydrogenating said mixture and converting said oxygenated n-paraffin by-products to the corresponding n-paraffin, the improvement which comprises catalytically hydrogenating said mixture in the absence of substantial isomerization and hydrocracking at a temperature of from about 600° to 750° F. in the presence of a catalyst composed of alumina, from about 0.1 to 5.0 weight percent of a Group VIII metal and from about 0.05 to 2.0 weight percent of an alkali metal oxide or alkaline earth metal oxide or thallous oxide or mixtures thereof impregnated on said alumina to convert said by-products to n-paraffins.
Claim 3
Dependent Claim 19 words
A process according to claim 1 wherein said Group VIII metal is platinum, palladium, rhodium, ruthenium, nickel or cobalt.
Claim 4
Dependent Claim 23 words
A process according to claim 1 wherein said alkali metal oxide is lithium oxide, sodium oxide, potassium oxide, rubidium oxide or cesium oxide.
Claim 5
Dependent Claim 20 words
A process according to claim 1 wherein said alkaline earth metal oxide is calcium oxide, strontium oxide or barium oxide.
Claim 6
Dependent Claim 12 words
A process according to claim 1 wherein said catalyst contains thallous oxide.
Claim 7
Dependent Claim 16 words
A process according to claim 1 wherein said catalyst additionally contains a Group VIB metal oxide.
Claim 8
Dependent Claim 15 words
A process according to claim 6 wherein said Group VIB metal oxide is molybdenum oxide.
Claim 9
Dependent Claim 15 words
A process according to claim 6 wherein said Group VIB metal oxide is tungsten oxide.
Claim 10
Dependent Claim 15 words
A process according to claim 1 wherein said catalyst additionally contains a Group VIIB metal.
Claim 11
Dependent Claim 13 words
A process according to claim 9 wherein said Group VIIB metal is rhenium.
Claim 12
Dependent Claim 13 words
A process according to claim 1 wherein said Group VIII metal is platinum.
Claim 13
Dependent Claim 13 words
A process according to claim 1 wherein said Group VIII metal is rhodium.
Claim 14
Dependent Claim 15 words
A process according to claim 1 wherein said catalyst comprises platinum, lithium oxide and alumina.
Claim 15
Dependent Claim 15 words
A process according to claim 1 wherein said catalyst comprises platinum, thallous oxide and alumina.
Claim 16
Dependent Claim 15 words
A process according to claim 1 wherein said catalyst comprises platinum, potassium oxide and alumina.
Claim 17
Dependent Claim 18 words
A process according to claim 1 wherein said catalyst comprises nickel oxide, molybdenum oxide, barium oxide and alumina.
Claim 18
Dependent Claim 18 words
A process according to claim 1 wherein said catalyst comprises nickel oxide, molybdenum oxide, lithium oxide and alumina.
Claim 19
Dependent Claim 15 words
A process according to claim 1 wherein said temperature is from 610° to 700° F.
Claim 20
Dependent Claim 20 words
A process according to claim 1 wherein said mixture is initially catalytically hydrogenated at from about 350° to 500° F.
Claim 21
Dependent Claim 20 words
A process according to claim 19 wherein said mixture is initially catalytically hydrogenated at from about 400° to 450° F.
Claim 22
Dependent Claim 22 words
A process according to claim 1 wherein said mixture is additionally and subsequently catalytically hydrogenated at from about 450° to 650° F.

References Cited (Backward Citations)

US2779711A Cited
US3524891A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-15 1981-02-14 1981-08-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-15 1985-02-14 1985-08-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-15 1989-02-14 1989-08-16 $7700.00 Window Closed / Lapsed

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