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US4042447A Expired / Lapsed US ⏱️ 0.0 years remaining

Crystallizing a layer of silicon on a sodium thallium type crystalline alloy substrate

Assignee: Sotec Corp
•
Filing: 1976-11-01
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Granted: 1977-08-16
•
Expires: 1996-11-01
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Abstract

Abstract Relates to a method for producing a product comprising crystalline silicon on a sodium thallium type substrate by application of silicon atoms gradually to that substrate whereby oriented overgrowth occurs and also to the product produced by said method. The product is useful in semiconductor and solar cell applications.

Inventors

  • 👤 Norman E. Reitz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 01:15
CPC Classifications
C; C30; C30B; C30B29/00; C30B29/02; C30B29/06; C30B25/00; C30B25/02; C30B25/18; H; H10; H10F; H10F71/00; H10F71/121; H10P; H10P14/00; H10P14/20; H10P14/29; H10P14/2901; H10P14/2923; H10P14/34; H10P14/3402; H10P14/3404; H10P14/3411; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/547; Y02P; Y02P70/00; Y02P70/50; Y10; Y10S; Y10S148/00; Y10S148/025; Y10S148/12; Y10S148/122; Y10S148/15; Y10S148/152; Y10S148/169

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 75 words
A method for producing solar cell quality crystalline silicon comprising: providing a sodium thallium type crystalline alloy substrate selected from the group consisting of LiZn, LiAl, LiGa, LiCd, LiIn and NaTl gradually applying silicon atoms thereto from the vapor state at a rate which allows said silicon atoms to arrange themselves for oriented crystal overgrowth on said substrate; and recovering a product comprising solar cell quality crystalline silicon upon a sodium thallium type crystalline substrate.
Claim 2
Independent Claim 75 words
A method for producing solar cell quality crystalline silicon comprising: providing a sodium thallium type crystalline alloy substrate selected from the group consisting of LiZn, LiAl, LiGa, LiCd, LiIn and NaTl gradually applying silicon atoms thereto from the vapor state at a rate which allows said silicon atoms to arrange themselves for oriented crystal overgrowth on said substrate; and recovering a product comprising solar cell quality crystalline silicon upon a sodium thallium type crystalline substrate.
Claim 3
Dependent Claim 18 words
A method as in claim 1, further comprising: providing thermal energy to said sodium thallium type crystalline substrate.
Claim 4
Dependent Claim 22 words
A method as in claim 1, wherein the step of applying atoms of silicon to said substrate is accomplished by gas epitaxy.
Claim 5
Dependent Claim 21 words
A method as in claim 1, wherein the step of applying atoms of silicon to said substrate is accomplished by sputtering.
Claim 6
Dependent Claim 22 words
A method as in claim 1, wherein the step of applying atoms of silicon to said substrate is accomplished by vacuum deposition.
Claim 7
Dependent Claim 21 words
A method as in claim 1, wherein the step of applying atoms of silicon to said substrate is accomplished by evaporation.
Claim 8
Dependent Claim 31 words
A method as in claim 1, wherein a tetrahedral center-apex distance of said sodium thallium type crystalline substrate is within about 30% of a tetrahedral center-apex distance of said crystalline silicon.
Claim 9
Dependent Claim 31 words
A method as in claim 1, wherein a tetrahedral center-apex distance of said sodium thallium type crystalline substrate is within about 15% of a tetrahedral center-apex distance of said crystalline silicon.
Claim 10
Dependent Claim 24 words
A method as in claim 1, wherein said sodium thallium type substrate is selected from the group consisting of LiZn, LiAl, LiGa, and LiCd.
Claim 11
Dependent Claim 33 words
A method as in claim 1, further comprising: providing thermal energy to said sodium thallium type crystalline substrate to assist said silicon atoms in arranging themselves for oriented crystal overgrowth on said substrate.
Claim 12
Dependent Claim 11 words
A method as in claim 1, wherein said substrate comprises LiZn.
Claim 13
Dependent Claim 11 words
A method as in claim 1, wherein said substrate comprises LiAl.
Claim 14
Dependent Claim 11 words
A method as in claim 1, wherein said substrate comprises LiGa.
Claim 15
Dependent Claim 11 words
A method as in claim 1, wherein said substrate comprises LiCd.
Claim 16
Dependent Claim 11 words
A method as in claim 1, wherein said substrate comprises LiIn.
Claim 17
Dependent Claim 11 words
A method as in Claim 1, wherein said substrate comprises NaTl.

References Cited (Backward Citations)

US3325392A Cited
US3382099A Cited
US3370980A Cited
US3515576A Cited
US3658586A Cited
US3990914A Cited
US3993533A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-15 1981-02-14 1981-08-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-15 1985-02-14 1985-08-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-15 1989-02-14 1989-08-16 $7700.00 Window Closed / Lapsed

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