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US4041060A
Expired / Lapsed
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Process for synthesizing organo-tin compounds
Assignee: Individual
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Filing: 1976-04-07
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Granted: 1977-08-09
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Expires: 1996-04-07
Abstract
Abstract This invention relates to a process for synthesizing organo-tin halides by reacting an organic halide of the formula RX wherein R represents an organic, preferably alkyl or aryl radical whereas X represents halogen, with a finely divided solid alloy, consisting of tin and a catalyst of the class consisting of copper, gold and silver, so as to form a compound of the formula R n Sn X 4 -n wherein R and X have the meanings indicated here-above and n represents an integer equal to 1, 2 or 3 wherein any contact of alloy particles with one another is avoided by separating said particles in a fluidized bed by means of a fluid comprising said organic halide, by admixing refractory particles to the alloy particles and by stirring thoroughly the fluidized bed. The products made according to the invention are particularly useful for stabilizing chlorinated organic materials.
Inventors
- 👤 Andre Paul de Haan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 17:14
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/56; C08K5/57; C07; C07F; C07F7/00; C07F7/22; C07F7/2208; C03; C03C; C03C2217/00; C03C2217/20; C03C2217/21; C03C2217/211; C03C2218/00; C03C2218/10; C03C2218/17
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
161 words
A process for synthesizing organo-tin halides of the formula R n Sn X 4 -n , wherein R represents an alkyl or aryl radical, X represents a halogen atom and n represents an integer equal to 1, 2 or 3, by reacting an organic halide of the formula RX, wherein R and X have the meanings indicated above, in the gaseous phase at a temperature between 300° and 400° C., with finely divided solid alloy particles consisting of tin and a catalyst of the group consisting of copper, gold and silver, characterized in that contact of the solid alloy particles, having a particle size between about 50 and 250 microns, with one another is avoided by separating said particles in a fluidized bed by means of a fluid, comprising said organic halide mixed with an inert gas, at a flow rate of 5 to 40 l/hour-cm2, by admixing refractory particles with said alloy particles and by thoroughly stirring the fluidized bed.
Claim 2
Dependent Claim
161 words
A process for synthesizing organo-tin halides of the formula R n Sn X 4 -n , wherein R represents an alkyl or aryl radical, X represents a halogen atom and n represents an integer equal to 1, 2 or 3, by reacting an organic halide of the formula RX, wherein R and X have the meanings indicated above, in the gaseous phase at a temperature between 300° and 400° C., with finely divided solid alloy particles consisting of tin and a catalyst of the group consisting of copper, gold and silver, characterized in that contact of the solid alloy particles, having a particle size between about 50 and 250 microns, with one another is avoided by separating said particles in a fluidized bed by means of a fluid, comprising said organic halide mixed with an inert gas, at a flow rate of 5 to 40 l/hour-cm2, by admixing refractory particles with said alloy particles and by thoroughly stirring the fluidized bed.
Claim 3
Dependent Claim
13 words
The process as claimed in claim 1, wherein said inert gas is nitrogen.
Claim 4
Dependent Claim
29 words
The process as claimed in claim 1, wherein said organic halide is methylchloride CH 3 Cl and said organo-tin halide is dimethyldichlorostannane (CH 3 ) 2 SnCl 2 .
Claim 5
Dependent Claim
30 words
The process as claimed in claim 1, wherein the alloy of tin is an alloy of copper and tin having a tin content of more than about 40% by weight.
Claim 6
Dependent Claim
23 words
The process as claimed in claim 1, wherein the tin content of the alloy is between about 40% and about 60% by weight.
Claim 7
Dependent Claim
19 words
The process as claimed in claim 1, wherein the reaction is performed at a temperature of about 350° C.
Claim 8
Dependent Claim
26 words
The process as claimed in claim 1, wherein the refractory particles are constituted of sand, silica or alumina having a particle size of about 0.1 mm.
Claim 9
Dependent Claim
20 words
The process as claimed in claim 1, wherein the particle size of said solid alloy particles is about 50 microns.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-08-08 | 1981-02-07 | 1981-08-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-08-08 | 1985-02-07 | 1985-08-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-08-08 | 1989-02-07 | 1989-08-09 | $7700.00 | Window Closed / Lapsed |