Hydroesterification process

Claim 2

A process for producing esters which comprises: A. reacting olefin having from about 3 to about 40 carbon atoms per molecule, CO and alcohol having from about 1 to about 20 carbon atoms per molecule in the presence of cobalt carbonyl catalyst to produce ester in admixture with residual catalyst and residual reactants, B. recovering at least a portion of the ester product from said reaction thereby producing a cobalt-containing catalyst residue, C. heating the catalyst residue at a temperature of from about 1000° F. to about 4000° F. under oxidizing conditions wherein the cobalt of the catalyst residue is converted to cobalt oxide, D. reacting the cobalt oxide with carbon monoxide and hydrogen to form a cobalt carbonyl complex, and E. recycling the cobalt carbonyl complex to the olefin-CO-alcohol reaction step to provide at least a portion of the catalyst therein.

Claim 3

A process in accordance with claim 1 wherein the alcohol is an alkanol.

Claim 4

A process in accordance with claim 1 wherein the alcohol is methanol.

Claim 5

A process in accordance with claim 1 wherein the cobalt carbonyl catalyst is of the formula HCo(CO) 4 .pyridine.

Claim 6

A process in accordance with claim 1 wherein the temperature at the heating step is from about 1500° F. to about 2500° F.

Claim 7

A process in accordance with claim 1 wherein the temperature at the heating step is from about 1900° F. to about 2000° F.

Claim 8

A process for producing esters which comprises: A. reacting olefin having from about 3 to about 40 carbon atoms per molecule, CO and alcohol having from 1 to about 20 carbon atoms per molecule in the presence of cobalt carbonyl-pyridinium catalyst to produce ester in admixture with residual catalyst. B. combining the reaction mass from the preceding step with olefin of the type reacted at A and separating the resulting mixture into two phases, a first phase consisting essentially of alcohol, a pyridine and cobalt catalyst complex and a second phase consisting essentially of olefin and ester and minor proportions each of catalyst, alcohol and a pyridine, C. recycling the first phase to the reacting step, D. purifying the second phase to recover olefin, product ester, alcohol and a pyridine, producing a residue containing the catalyst, E. heating the residue at a temperature of from about 1000° F. to about 4000° F. under oxidizing conditions wherein the cobalt of the catalyst residue is converted to cobalt oxide, F. recovering the cobalt oxide, G. reacting the recovered cobalt oxide with CO, hydrogen and a pyridine to form cobalt carbonyl-pyridinium catalyst, H. and recycling the cobalt carbonyl-pyridinium catalyst formed in step G to the reaction at step A.

Claim 9

A process for producing esters which comprises: A. reacting olefin having from about 3 to about 40 carbon atoms per molecule, CO and alcohol having from 1 to about 20 carbon atoms per molecule in the presence of cobalt carbonyl-pyridinium catalyst to produce ester in admixture with residual catalyst. B. combining the reaction mass from the preceding step with olefin of the type reacted at A and separating the resulting mixture into two phases, a first phase consisting essentially of alcohol, a pyridine and cobalt catalyst complex and a second phase consisting essentially of olefin and ester and minor proportions each of catalyst, alcohol and a pyridine, C. recycling the first phase to the reacting step, D. purifying the second phase to recover olefin, product ester, alcohol and a pyridine, producing a residue containing the catalyst, E. heating the residue at a temperature of from about 1000° F. to about 4000° F. under oxidizing conditions wherein the cobalt of the catalyst residue is converted to cobalt oxide, F. recovering the cobalt oxide, G. reacting the recovered cobalt oxide with CO, hydrogen and a pyridine to form cobalt carbonyl-pyridinium catalyst, H. and recycling the cobalt carbonyl-pyridinium catalyst formed in step G to the reaction at step A.