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Benzotriazole ortho-ester ultraviolet stabilizers

Assignee: Eastman Kodak Co
•
Filing: 1975-10-28
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Granted: 1977-08-09
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Expires: 1995-10-28
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Abstract

Abstract The invention relates to benzotriazole ortho-ester compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the benzotriazole ortho-ester composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.

Inventors

  • 👤 David Martin Pond
  • 👤 Richard Hsu-Shien Wang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 16:45
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 212 words
An organic composition susceptible to ultraviolet degradation stabilized against such degradation with a stabilizing amount of a composition of matter having the following formula: ##STR18## wherein Z is an integer 1, 2 or 3; R 1 , R 2 , R 3 and R 4 are hydrogen, chloro, bromo lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, alkoxy, amino, substituted amino, cyano, carboxy and the substituents R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; R 8 may be halogen, hydroxy, halogen, C 1 -C 12 substituted or unsubstituted alkyl, amino, alkylamino, dialkylamino, arylamino, dirarylamino, alkoxy, aryl, or aryloxy; and I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the carbonyl linking substituent, said I substituents can all be one of the substituents listed above or different listed substituents.
Claim 2
Dependent Claim 212 words
An organic composition susceptible to ultraviolet degradation stabilized against such degradation with a stabilizing amount of a composition of matter having the following formula: ##STR18## wherein Z is an integer 1, 2 or 3; R 1 , R 2 , R 3 and R 4 are hydrogen, chloro, bromo lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, alkoxy, amino, substituted amino, cyano, carboxy and the substituents R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; R 8 may be halogen, hydroxy, halogen, C 1 -C 12 substituted or unsubstituted alkyl, amino, alkylamino, dialkylamino, arylamino, dirarylamino, alkoxy, aryl, or aryloxy; and I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the carbonyl linking substituent, said I substituents can all be one of the substituents listed above or different listed substituents.
Claim 3
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##STR19##
Claim 4
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##STR20##
Claim 5
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##STR21##
Claim 6
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##STR22##
Claim 7
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##STR23##
Claim 8
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##STR24##
Claim 9
Dependent Claim 211 words
An organic composition susceptible to ultraviolet degradation stabilized against such degradation with a stabilizing amount of a composition of matter having the formula: ##STR25## wherein W is an integer between 2 and 6; R 1 , R 2 , R 3 and R 4 are hydrogen, chloro, bromo, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, alkoxy, amino, substituted amino, cyano, carboxy and the substituents R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; R 9 may be hydrogen, halogen, hydroxy, C 1 -C 12 substituted or unsubstituted alkyl, amino, alkylamino, dialkylamino, arylamino, diarylamino, alkoxy, aryl, or aryloxy group; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the carbonyl linking substituent, said I substituents can all be one of the substituents listed above or different listed substituents.
Claim 10
Dependent Claim 211 words
An organic composition susceptible to ultraviolet degradation stabilized against such degradation with a stabilizing amount of a composition of matter having the formula: ##STR25## wherein W is an integer between 2 and 6; R 1 , R 2 , R 3 and R 4 are hydrogen, chloro, bromo, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, alkoxy, amino, substituted amino, cyano, carboxy and the substituents R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; R 9 may be hydrogen, halogen, hydroxy, C 1 -C 12 substituted or unsubstituted alkyl, amino, alkylamino, dialkylamino, arylamino, diarylamino, alkoxy, aryl, or aryloxy group; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the carbonyl linking substituent, said I substituents can all be one of the substituents listed above or different listed substituents.
Claim 11
Dependent Claim 20 words
An organic composition according to claim 8 containing a stabilizing amount of a composition of matter having the formula: ##STR26##
Claim 12
Dependent Claim 20 words
An organic composition according to claim 8 containing a stabilizing amount of a composition of matter having the formula: ##STR27##
Claim 13
Dependent Claim 20 words
An organic composition according to claim 8 containing a stabilizing amount of a composition of matter having the formula: ##STR28##
Claim 14
Dependent Claim 20 words
An organic composition according to claim 8 containing a stabilizing amount of a composition of matter having the formula: ##STR29##
Claim 15
Dependent Claim 20 words
An organic composition according to claim 8 containing a stabilizing amount of a composition of matter having the formula: ##STR30##
Claim 16
Dependent Claim 20 words
An organic composition according to claim 8 containing a stabilizing amount of a composition of matter having the formula: ##STR31##

References Cited (Backward Citations)

US3004896A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-08-08 1981-02-07 1981-08-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-08-08 1985-02-07 1985-08-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-08-08 1989-02-07 1989-08-09 $7700.00 Window Closed / Lapsed

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