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Alkylene oxide derivatives based on polytetrahydrofuran copolymers

Assignee: BASF SE
•
Filing: 1975-01-03
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Granted: 1977-07-26
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Expires: 1995-01-03
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Abstract

Abstract Alkylene oxide derivatives based on tetrahydrofuran copolymers and having the formula R-X, wherein X consists essentially of a copolymer of tetrahydrofuran and a C 2 to C 3 alkylene oxide, R being the radical of a C 8 to C 22 alcohol or carboxylic acid or their oxyalkylation products with from 1 to 20 moles of said C 2 to C 3 alkylene oxide, the total amount of the alkylene oxide and tetrahydrofuran units in R-X being from 60 to 95% by weight and the molar ratio of the alkylene oxide units to tetrahydrofuran units being from 1:0.5 to 1:3. The new products R-X are useful as surfactants, textile auxiliaries and, in particular, emulsifiers in the one-bath finishing and pigment dyeing of textiles.

Inventors

  • 👤 Norbert Greif
  • 👤 Heinz Bille
  • 👤 Rolf Fikentscher
  • 👤 Toni Simenc

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 10:56
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/02; C08G65/04; C08G65/06; C08G65/16; C08G65/20; C08G65/08; C08G65/26; C08G65/2603; D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/53; D06P; D06P1/00; D06P1/44; D06P1/60; D06P1/613

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 111 words
A polyalkylene oxide adduct of the formula R -- X wherein R is the radical of a monoalcohol of 8 to 22 carbon atoms, of a monocarboxylic acid of 8 to 22 carbon atoms or of their oxalkylation products with from 1 to 20 moles of an epoxide of 2 to 3 carbon atoms and X is the radical of a copolymer of an epoxide of 2 or 3 carbon atoms and tetrahydrofuran, with the proviso that the total amount of epoxide and tetrahydrofuran units in R--X is from 60 to 95 percent by weight and that the molar ratio of epoxide units to tetrahydrofuran units is from 1:0.5 to 1:3.
Claim 2
Dependent Claim 111 words
A polyalkylene oxide adduct of the formula R -- X wherein R is the radical of a monoalcohol of 8 to 22 carbon atoms, of a monocarboxylic acid of 8 to 22 carbon atoms or of their oxalkylation products with from 1 to 20 moles of an epoxide of 2 to 3 carbon atoms and X is the radical of a copolymer of an epoxide of 2 or 3 carbon atoms and tetrahydrofuran, with the proviso that the total amount of epoxide and tetrahydrofuran units in R--X is from 60 to 95 percent by weight and that the molar ratio of epoxide units to tetrahydrofuran units is from 1:0.5 to 1:3.
Claim 3
Dependent Claim 45 words
A polyalkylene oxide adduct as claimed in claim 1, wherein R is an oleic acid radical and the starting materials oleic acid, ethylene oxide and tetrahydrofuran are incorporated into the end product R -- X in the weight ratio of 1:(1.5 to 2.5):(1.5 to 3).
Claim 4
Dependent Claim 19 words
A polyalkylene oxide adduct as claimed in claim 1 wherein R is the polyethylene oxide adduct of oleic acid.
Claim 5
Dependent Claim 21 words
A polyalkylene oxide adduct as claimed in claim 1 wherein R is the polyethylene oxide adduct of oleic acid hydroxyethyl ester.
Claim 6
Dependent Claim 25 words
A polyalkylene oxide adduct as claimed in claim 1 wherein R is the polyethylene oxide adduct of an oxoalcohol of 9 to 11 carbon atoms.
Claim 7
Dependent Claim 19 words
A polyalkylene oxide adduct as claimed in claim 1 wherein R is the polyethylene oxide adduct of stearyl alcohol.
Claim 8
Dependent Claim 28 words
A polyalkylene oxide adduct as claimed in claim 1 wherein the total amount of epoxide and tetrahydrofuran units in R--X is from 70 to 90 percent by weight.
Claim 9
Dependent Claim 36 words
A polyalkylene oxide adduct as claimed in claim 1 in which there are from 5 to 20 moles of expoxide and from 5 to 15 moles of tetrahydrofuran per mole of the alcohol or carboxylic acid.
Claim 10
Dependent Claim 15 words
A polyalkylene oxide adduct as claimed in claim 8 wherein the expoxide is ethylene oxide.
Claim 11
Dependent Claim 19 words
A polyalkylene oxide adduct as claimed in claim 2 wherein said weight ratio is 1:(1.6 to 1.8):(2.0 to 3).

References Cited (Backward Citations)

SU211429A1 Cited
US2533323A Cited
US2599803A Cited
DE1120139B Cited
US3425999A Cited
US3577559A Cited
US3539519A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-25 1981-01-24 1981-07-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-25 1985-01-24 1985-07-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-25 1989-01-24 1989-07-26 $7700.00 Window Closed / Lapsed

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