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US4036944A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrogen sorbent composition and its use

Assignee: Shell USA Inc
•
Filing: 1976-05-17
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Granted: 1977-07-19
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Expires: 1996-05-17
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Abstract

Abstract A hydrogen sorbent composition comprising a lanthanum pentanickel sorbent and a thermoplastic elastomer binder is disclosed. Also disclosed is the use of the composition in storing hydrogen and in the purification of hydrogen-containing streams.

Inventors

  • 👤 George C. Blytas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 06:08
CPC Classifications
C; C01; C01B; C01B3/00; C01B3/50; C01B3/508; C01B3/0005; C01B3/001; C01B3/0018; C01B3/0031; C01B3/0047; C01B3/0057; C01B3/0078; F; F17; F17C; F17C11/00; F17C11/005; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/32

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 77 words
A solid hydrogen sorbent composition comprising a sorbent having greater that 50% lanthanum pentanickel alloy and a binder matrix selected from the group consisting of (i) non-hydrogenated block copolymers having at least two monoalkenyl arene polymer end blocks A and at least one elastomeric conjugated diene mid block B, and (ii) selectively hydrogenated block copolymers having at least two monoalkenyl arene polymer end blocks C and at least one substantially completely hydrogenated diene polymer mid block D.
Claim 2
Dependent Claim 77 words
A solid hydrogen sorbent composition comprising a sorbent having greater that 50% lanthanum pentanickel alloy and a binder matrix selected from the group consisting of (i) non-hydrogenated block copolymers having at least two monoalkenyl arene polymer end blocks A and at least one elastomeric conjugated diene mid block B, and (ii) selectively hydrogenated block copolymers having at least two monoalkenyl arene polymer end blocks C and at least one substantially completely hydrogenated diene polymer mid block D.
Claim 3
Dependent Claim 29 words
A composition according to claim 1 wherein the hydrogen sorbent composition comprises about 99% to about 70% by weight sorbent and about 1% to about 30% by weight binder.
Claim 4
Dependent Claim 38 words
A composition according to claim 1 wherein said binder is a selectively hydrogenated block copolymer wherein at least 80% of the aliphatic double bonds are hydrogenated while no more than about 25% of the aromatic bonds are hydrogenated.
Claim 5
Dependent Claim 31 words
A composition according to claim 1 wherein said sorbent comprises at least about 80% lanthanum pentanickel with the remainder being selected from the group consisting of copper, nickel and iron metals.
Claim 6
Dependent Claim 14 words
A composition according to claim 1 wherein said sorbent comprises lanthanum pentanickel and Mischmetal.
Claim 7
Dependent Claim 31 words
A composition according to claim 1 wherein said hydrogen sorbent composition comprises about 45% by weight lanthanum pentanickel alloy, about 45% by weight copper metal, and about 10% by weight binder.
Claim 8
Dependent Claim 75 words
A process for absorbing and subsequently desorbing hydrogen gas in and from the solid hydrogen sorbent composition of claim 1 which process comprises: a. subjecting said solid hydrogen sorbent composition to an external hydrogen gas pressure which exceeds the plateau pressure at the absorption temperature; and b. reducing the hydrogen gas pressure to which said solid hydrogen sorbent composition is subjected to a value which is lower than the plateau pressure at the desorption temperature.
Claim 9
Dependent Claim 21 words
A process according to claim 7 wherein the absorption temperature and desorption temperature varies between about 0° C. and 150° C.
Claim 10
Dependent Claim 26 words
A process according to claim 8 wherein the external hydrogen gas pressure and the hydrogen gas pressure varies from about 10 psia to about 2,000 psia.
Claim 11
Dependent Claim 29 words
A process according to claim 7 wherein said hydrogen sorbent composition comprises about 99% to about 70% by weight sorbent and about 1% to about 30% by weight binder.

References Cited (Backward Citations)

US2929792A Cited
US3345319A Cited
GB1291976A Cited
US3700633A Cited
US3793435A Cited
US3910831A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-18 1981-01-17 1981-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-18 1985-01-17 1985-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-18 1989-01-17 1989-07-19 $7700.00 Window Closed / Lapsed

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