Manufacture of isomer-free 3-methylbutylamine

Claim 2

A process for manufacture of pure 3-methylbutylamine-1 which comprises reacting 2-methylbuten-1-ol-4 with hydrogen and a molar excess of ammonia simultaneously at about 140° to 240° C. at superatmospheric pressure in the presence of a hydrogenation catalyst containing one or more metals selected from the group consisting of iron, cobalt, nickel, ruthenium, rhodium, platinum and copper, distilling off the excess ammonia from the reaction mixture, and recovering pure 3-methylbutylamine-1.

Claim 3

A process as claimed in claim 1 wherein said catalyst is sintered, unsupported cobalt.

Claim 4

A process as claimed in claim 1 wherein said catalyst contains a mixture of metals selected from the group consisting of cobalt, nickel and copper; cobalt, nickel, copper, manganese and phosphoric acid; cobalt, manganese and phosphoric acid; and nickel, copper and chromium.

Claim 5

A process for the production of pure 3-methylbutylamine-1 which comprises reacting hydrogen and ammonia simultaneously with a hydroformylation reaction mixture derived by the thermal condensation of isobutene and aqueous formaldehyde, said reaction mixture consisting mainly of 2-methylbuten-1-ol-4 and containing minor amounts of isomeric alcohols derived from cis- and trans-butene-2 and n-butene-1 impurities in the isobutene reactant or from hydroformylation of the isobutene at the β-position, said simultaneous reaction of ammonia, hydrogen and said reaction mixture being carried out at about 140° to 240° C. in the presence of a catalyst containing a catalytically active amount of one or more metals from the group consisting of iron, nickel, cobalt, ruthenium, rhodium, platinum and copper.

Claim 6

A process for the production of pure 3-methylbutylamine-1 which comprises reacting hydrogen and ammonia simultaneously with a hydroformylation reaction mixture derived by the thermal condensation of isobutene and aqueous formaldehyde, said reaction mixture consisting mainly of 2-methylbuten-1-ol-4 and containing minor amounts of isomeric alcohols derived from cis- and trans-butene-2 and n-butene-1 impurities in the isobutene reactant or from hydroformylation of the isobutene at the β-position, said simultaneous reaction of ammonia, hydrogen and said reaction mixture being carried out at about 140° to 240° C. in the presence of a catalyst containing a catalytically active amount of one or more metals from the group consisting of iron, nickel, cobalt, ruthenium, rhodium, platinum and copper.