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US4036740A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrocarbon catalytic cracking process

Assignee: Chevron USA Inc
•
Filing: 1975-10-28
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Granted: 1977-07-19
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Expires: 1995-10-28
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Abstract

Abstract An improved hydrocarbon catalytic cracking process which comprises determining the concentrations of carbon dioxide and carbon monoxide in the gaseous effluent from the catalyst regeneration zone and adjusting the rate of addition of a selective treating agent to the hydrocarbon feed to the cracking zone so as to maintain a volume ratio of carbon dioxide to carbon monoxide of at least 2.2 in said effluent.

Inventors

  • 👤 Thomas C. Readal
  • 👤 Joel D. McKinney
  • 👤 Robert A. Titmus

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 13:56
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/14; C10G11/18; Y; Y02; Y02P; Y02P30/00; Y02P30/40; Y10; Y10S; Y10S502/00; Y10S502/521

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 167 words
In a process which comprises contacting a hydrocarbon feed with a cracking catalyst in a cracking zone under cracking conditions to produce a lower boiling gasoline fraction and thereafter heating the deactivated catalyst in the presence of oxygen in a regeneration zone to a temperature in the range of 800° to 1600° F. until the concentration of carbon on the catalyst is less than 0.3 weight percent; the improvement which comprises conducting the cracking process until the concentration of metal contaminants on the catalyst is at least 1500 ppm nickel equivalents, determining the carbon dioxide and carbon monoxide concentrations in the gaseous effluent withdrawn from said regeneration zone, and adjusting the rate of flow in said hydrocarbon feed to said cracking zone of a treating agent selected from the group consisting of antimony, bismuth, manganese and compounds of such treating agents convertible to the oxide form so as to maintain a volume ratio of carbon dioxide to carbon monoxide in said gaseous effluent of at least 2.2.
Claim 2
Dependent Claim 167 words
In a process which comprises contacting a hydrocarbon feed with a cracking catalyst in a cracking zone under cracking conditions to produce a lower boiling gasoline fraction and thereafter heating the deactivated catalyst in the presence of oxygen in a regeneration zone to a temperature in the range of 800° to 1600° F. until the concentration of carbon on the catalyst is less than 0.3 weight percent; the improvement which comprises conducting the cracking process until the concentration of metal contaminants on the catalyst is at least 1500 ppm nickel equivalents, determining the carbon dioxide and carbon monoxide concentrations in the gaseous effluent withdrawn from said regeneration zone, and adjusting the rate of flow in said hydrocarbon feed to said cracking zone of a treating agent selected from the group consisting of antimony, bismuth, manganese and compounds of such treating agents convertible to the oxide form so as to maintain a volume ratio of carbon dioxide to carbon monoxide in said gaseous effluent of at least 2.2.
Claim 3
Dependent Claim 28 words
The process of claim 1 wherein the cracking process is conducted until the concentration of metal contaminants as nickel equivalents is at least 2500 ppm on said catalyst.
Claim 4
Dependent Claim 29 words
The process of claim 1 wherein the volume ratio of carbon dioxide to carbon monoxide maintained in said regeneration zone effluent is in the range of 2.2 to 5.0.
Claim 5
Dependent Claim 33 words
The process of claim 1 wherein the concentration of said treating agent applied to said catalyst in said cracking zone is less than 2 mol per mol of metal contaminants on said catalyst.
Claim 6
Dependent Claim 38 words
The process of claim 1 wherein the amount of treating agent added to the hydrocarbon feed to said cracking zone will range from about 3 ppm to 3000 ppm, based upon the hydrocarbon feed to said cracking zone.
Claim 7
Dependent Claim 19 words
The process of claim 1 wherein said treating agent is antimony or an antimony compound convertible to antimony oxide.
Claim 8
Dependent Claim 19 words
The process of claim 1 wherein said treating agent is bismuth or a bismuth compound convertible to bismuth oxide.

References Cited (Backward Citations)

US2129693A Cited
US2436927A Cited
US3711422A Cited
US3909392A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-18 1981-01-17 1981-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-18 1985-01-17 1985-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-18 1989-01-17 1989-07-19 $7700.00 Window Closed / Lapsed

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