Patent US4036596A successfully refreshed from Google Patents.
US4036596A
Expired / Lapsed
US
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Apparatus for continuous sulfonation
Assignee: LION (LION CORPORATION) KK
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Filing: 1976-06-25
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Granted: 1977-07-19
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Expires: 1996-06-25
Abstract
Abstract A cylindrical apparatus for continuous sulfonation of an organic liquid is provided with an annular feeding device for permitting the organic liquid to flow in the form of a film down a reaction wall. The annular feeding device is provided with a number of slots in a horizontal and equidistant manner in a row.
Inventors
- 👤 Toshiaki Ogoshi
- 👤 Yozo Miyawaki
- 👤 Fusao Kondo
- 👤 Susumu Sakurai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 20:01
CPC Classifications
B; B01; B01J; B01J19/00; B01J19/24; B01J19/247; B01J10/00; B01J10/02; C; C07; C07B; C07B45/00; C07B45/02; C07C; C07C309/00
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
172 words
In an apparatus for continuous sulfonation comprising at least one vertically extending, cylindrical reaction wall having a reaction surface down which a liquid material to be sulfonated flows in the form of a thin film, and at least one annular nozzle for feeding a gaseous sulfonating agent to a corresponding reaction zone, wherein the improvement comprises an annular feeding device mounted on an upper end of said at least one cylindrical reaction wall for feeding said liquid material to be sulfonated to said reaction surface, and having a number of rectangular slots horizontally equidistantly arranged in a row; and in the percentage of slot area expressed by the formula: ##EQU4## where a represents the vertical clearance of the opening of each slot and is in the range of 0.2 mm to 1.0 mm; b the interval between two adjacent slots; and c the horizontal width of opening of each slot; said a, b and c are so chosen as to permit said percentage of slot area to range from 40 to 90%.
Claim 2
Dependent Claim
172 words
In an apparatus for continuous sulfonation comprising at least one vertically extending, cylindrical reaction wall having a reaction surface down which a liquid material to be sulfonated flows in the form of a thin film, and at least one annular nozzle for feeding a gaseous sulfonating agent to a corresponding reaction zone, wherein the improvement comprises an annular feeding device mounted on an upper end of said at least one cylindrical reaction wall for feeding said liquid material to be sulfonated to said reaction surface, and having a number of rectangular slots horizontally equidistantly arranged in a row; and in the percentage of slot area expressed by the formula: ##EQU4## where a represents the vertical clearance of the opening of each slot and is in the range of 0.2 mm to 1.0 mm; b the interval between two adjacent slots; and c the horizontal width of opening of each slot; said a, b and c are so chosen as to permit said percentage of slot area to range from 40 to 90%.
Claim 3
Dependent Claim
22 words
An apparatus according to claim 1, characterized in that said percentage of slot area is in the range of 50% to 90%.
Claim 4
Dependent Claim
21 words
An apparatus according to claim 1, characterized in that said b is in the range of 1 mm to 5 mm.
Claim 5
Dependent Claim
38 words
An apparatus according to claim 1 characterized in that said annular nozzle is opened slightly below said annular feeding device so as to feed a gaseous sulfonating agent in parallel-flow relation to thin film of said liquid material.
Claim 6
Dependent Claim
24 words
An apparatus according to claim 1, characterized in that said cylindrical reaction wall is provided with a cooling jacket for removing the reaction heat.
Claim 7
Dependent Claim
172 words
An apparatus according to claim 1, characterized in that two externally cooled cylindrical reaction walls are so longitudinally concentrically provided that their respective reaction surfaces are opposed to each other; an inner annular feeding device for permitting a liquid material fed to a circular chamber defined inside said device to flow through the slots in the form of a thin film down a reaction surface of a inner reaction wall is provided at an upper end of said inner reaction wall and an outer annular feeding device for permitting a liquid material fed to a circular chamber defined outside said device to flow through the slots in the form of a thin film down a reaction surface of an outer reaction wall is provided at an upper end of said outer reaction wall; and an annular nozzle for feeding a gaseous sulfonating agent to a reaction zone defined by said two reaction surfaces in parallel-flow relation to the thin film of said liquid material is opened slightly below said annular feeding devices.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-07-18 | 1981-01-17 | 1981-07-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-07-18 | 1985-01-17 | 1985-07-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-07-18 | 1989-01-17 | 1989-07-19 | $7700.00 | Window Closed / Lapsed |