Metal-containing oxazoline additives and lubricating oils containing said additives

Claim 2

In a process for preparing oxazoline compounds wherein one molar equivalent of an alkenyl substituted succinic acid or alkenyl substituted succinic acid anhydride is reacted with one to two molar equivalents of a 2,2-di-substituted -2-amino-1-alkanol having 2 to 3 hydroxy groups and containing a total of 4 to 8 carbon atoms and represented by the formula: ##STR3## wherein X is an alkyl or hydroxy alkyl group and one of the X substituents being a hydroxyalkyl group of the structure --(CH 2 ) n OH wherein n is 1 to 3 at a temperature of from 140° to 240° C., the improvement which comprises conducting said reaction in the presence of from 0.01 to 10 wt. % based on the combined total weight of said reactants of a metal salt promotor of the class of a metal salt of a C 1-8 hydrocarbyl carboxylic acid or metal oxide whereby said reaction time is shortened, said metal being of the class consisting of zinc, manganese, iron, cobalt and nickel.

Claim 3

The process according to claim 1 wherein said metal carboxylate salt consists of metal salts of C 1 to C 8 fatty acids and said amino-alkanol is present in about two molar equivalents.

Claim 4

The process according to claim 2 wherein said salt is zinc acetate or zinc oxide, said amino alkanol is trishydroxy-aminomethane and said temperature is from 170-210° C.

Claim 5

An oil soluble reaction product having a weight average molecular weight of from about 200 to 5000 obtained from the reaction of one molar equivalent of an alkenyl substituted succinic acid or alkenyl substituted succinic acid anhydride with from one to two molar equivalents of a 2,2-disubstituted-2-amino-1-alkanol having 2 to 3 hydroxy groups and containing a total of 4 to 8 carbon atoms and represented by the formula: ##STR4## wherein X is an alkyl or hydroxy alkyl group and one of the X substituents being a hydroxyalkyl group of the structure --(CH 2 ) n OH wherein n is 1 to 3 at a temperature of from 140° to 240° C., said reaction product containing from about 0.01 to 6 wt. % metal of the class consisting of zinc, manganese, iron, cobalt and nickel, said metal present as a metal salt of a C 1-8 hydrocarbyl carboxylic acid.

Claim 6

An oil soluble reaction product having a weight average molecular weight of from about 200 to 5000 obtained from the reaction of one molar equivalent of an alkenyl substituted succinic acid or alkenyl substituted succinic acid anhydride with from one to two molar equivalents of a 2,2-disubstituted-2-amino-1-alkanol having 2 to 3 hydroxy groups and containing a total of 4 to 8 carbon atoms and represented by the formula: ##STR4## wherein X is an alkyl or hydroxy alkyl group and one of the X substituents being a hydroxyalkyl group of the structure --(CH 2 ) n OH wherein n is 1 to 3 at a temperature of from 140° to 240° C., said reaction product containing from about 0.01 to 6 wt. % metal of the class consisting of zinc, manganese, iron, cobalt and nickel, said metal present as a metal salt of a C 1-8 hydrocarbyl carboxylic acid.

Claim 7

The reaction product of claim 4 wherein said metal is zinc and is present in the amounts of from about 0.1 to 2 wt. %.

Claim 8

An oil soluble reaction product according to claim 4 wherein one molar proportion of said acid material is reacted with about two molar proportions of tris-hydroxy-aminomethane whereby a bis-oxazoline reaction product complexed with a metal salt is obtained.

Claim 9

A reaction product according to claim 4 wherein said product is substantially imide free and at least 70% of its carboxyl groups have been converted to oxazoline groups.

Claim 10

A mono-oxazoline reaction product having a weight average molecular weight of from about 500 to about 3000 obtained from the reaction of one molar proportion of an alkenyl substituted succinic acid or alkenyl substituted succinic acid anhydride and one molar proportion of a 2,2-disubstituted-2-amino-1-alkanol having 2 to 3 hydroxy groups and containing a total of 4 to 8 carbon atoms and represented by the formula: ##STR5## wherein X is an alkyl or hydroxy alkyl group and one of the X substituents being a hydroxy alkyl group of the structure --(CH 2 ) n OH wherein n is 1 to 3 at a temperature of from 140° to 240° C. and containing from about 0.1 to 2 wt. % of metal of the class consisting of zinc, iron, cobalt and nickel, said metal present as a salt of a C 1-8 hydrocarbyl carboxylic acid.

Claim 11

A mono-oxazoline reaction product having a weight average molecular weight of from about 500 to about 3000 obtained from the reaction of one molar proportion of an alkenyl substituted succinic acid or alkenyl substituted succinic acid anhydride and one molar proportion of a 2,2-disubstituted-2-amino-1-alkanol having 2 to 3 hydroxy groups and containing a total of 4 to 8 carbon atoms and represented by the formula: ##STR5## wherein X is an alkyl or hydroxy alkyl group and one of the X substituents being a hydroxy alkyl group of the structure --(CH 2 ) n OH wherein n is 1 to 3 at a temperature of from 140° to 240° C. and containing from about 0.1 to 2 wt. % of metal of the class consisting of zinc, iron, cobalt and nickel, said metal present as a salt of a C 1-8 hydrocarbyl carboxylic acid.

Claim 12

An oleaginous composition comprising a major amount of an oil of lubricating viscosity and at least a dispersant amount of an oil soluble oxazoline reaction product having a weight average molecular weight of from about 200 to 5000 obtained from the reaction of about one molar equivalent of an alkenyl substituted succinic acid or alkenyl substituted succinic anhydride reacted with from about one to two molar equivalents of a 2,2-disubstituted-2-amino-1 -alkanol having 2 to 3 hydroxy groups and containing a total of 4 to 8 carbon atoms and represented by the formula: ##STR6## wherein X is an alkyl or hydroxy alkyl group and one of the X substituents being a hydroxyalkyl group of the structure --(CH 2 ) n OH wherein n is 1 to 3 at a temperature of from 140° C. to 240° C., said reaction product containing from about 0.01 to 6 wt. % metal of the class consisting of zinc, manganese, iron, cobalt and nickel, said metal present as a metal salt of a C 1-8 hydrocarbyl carboxylic acid.

Claim 13

An oleaginous composition comprising a major amount of an oil of lubricating viscosity and at least a dispersant amount of an oil soluble oxazoline reaction product having a weight average molecular weight of from about 200 to 5000 obtained from the reaction of about one molar equivalent of an alkenyl substituted succinic acid or alkenyl substituted succinic anhydride reacted with from about one to two molar equivalents of a 2,2-disubstituted-2-amino-1 -alkanol having 2 to 3 hydroxy groups and containing a total of 4 to 8 carbon atoms and represented by the formula: ##STR6## wherein X is an alkyl or hydroxy alkyl group and one of the X substituents being a hydroxyalkyl group of the structure --(CH 2 ) n OH wherein n is 1 to 3 at a temperature of from 140° C. to 240° C., said reaction product containing from about 0.01 to 6 wt. % metal of the class consisting of zinc, manganese, iron, cobalt and nickel, said metal present as a metal salt of a C 1-8 hydrocarbyl carboxylic acid.

Claim 14

A composition according to claim 9 wherein said product is a bis-oxazoline reaction product and said metal is zinc and is complexed with said product.