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US4035291A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for separating aqueous formaldehyde mixtures

Assignee: Monsanto Co
•
Filing: 1976-01-05
•
Granted: 1977-07-12
•
Expires: 1996-01-05
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Abstract

Abstract Process for the separation of water from mixtures of water and formaldehyde by contacting the mixtures against an organic polymeric membrane, and withdrawing at the other side of the membrane a mixture having a higher concentration of water.

Inventors

  • 👤 Robert Chiang
  • 👤 Eli Perry

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 16:22
CPC Classifications
B; B01; B01D; B01D61/00; B01D61/36; B01D61/362; B01D71/00; B01D71/06; B01D71/76; B01D71/82; B01J; B01J47/00; B01J47/12; C; C07; C07C; C07C45/00; C07C45/78; C07C45/786; B01D2325/00; B01D2325/14

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 73 words
Process for the separation of water from feed mixtures comprising water and formaldehyde which comprises contacting the aforesaid mixture against one side of a membrane comprising a copolymer of non-nitrogen containing monomer and a copolymerizable sulfonate-substituted monomer and withdrawing, at second side, a vaporous mixture having a higher concentration of water than the aforesaid feed mixture, with the mixture at second side being maintained at a lower chemical potential than the feed side.
Claim 2
Dependent Claim 73 words
Process for the separation of water from feed mixtures comprising water and formaldehyde which comprises contacting the aforesaid mixture against one side of a membrane comprising a copolymer of non-nitrogen containing monomer and a copolymerizable sulfonate-substituted monomer and withdrawing, at second side, a vaporous mixture having a higher concentration of water than the aforesaid feed mixture, with the mixture at second side being maintained at a lower chemical potential than the feed side.
Claim 3
Dependent Claim 84 words
Process for the separation of water from feed mixtures comprising water and formaldehyde which comprises contacting the aforesaid mixture against one side of a membrane comprising a copolymer of a non-nitrogen-containing monomer and a copolymerizable sulfonate-substituted monomer and withdrawing, at the second side, a vaporous mixture having a higher concentration of water than the aforesaid feed mixture, with the mixture at the second side being maintained at a pressure less than atmospheric, but less than the pressure at the feed side of the membrane.
Claim 4
Dependent Claim 84 words
Process for the separation of water from feed mixtures comprising water and formaldehyde which comprises contacting the aforesaid mixture against one side of a membrane comprising a copolymer of a non-nitrogen-containing monomer and a copolymerizable sulfonate-substituted monomer and withdrawing, at the second side, a vaporous mixture having a higher concentration of water than the aforesaid feed mixture, with the mixture at the second side being maintained at a pressure less than atmospheric, but less than the pressure at the feed side of the membrane.
Claim 5
Dependent Claim 15 words
Process as in claim 1 in which the feed mixture comprises water, formaldehyde and methanol.
Claim 6
Dependent Claim 20 words
Process as in claim 1 in which the said membrane comprises a copolymer of a non-nitrogen-containing monomer and alkyl sulfonate.
Claim 7
Dependent Claim 20 words
Process as in claim 1 in which the said membrane comprises a copolymer of a non-nitrogen-containing monomer and vinyl sulfonate.
Claim 8
Dependent Claim 25 words
Process as in claim 1 in which the said membrane comprises a non-nitrogen-containing polymer which has as pendant groups along the polymer chain a sulfonate.
Claim 9
Dependent Claim 24 words
Process as in claim 1 in which the said membrane polymer contains groups whose model compounds have pK values of from 0.1 to 3.
Claim 10
Dependent Claim 20 words
Process as in claim 1 in which said membrane comprises a copolymer of a non-nitrogen-containing monomer and alkylene sulfonic acid.

References Cited (Backward Citations)

US2953502A Cited
US3723306A Cited
US3228877A Cited
US3257334A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-11 1981-01-10 1981-07-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-11 1985-01-10 1985-07-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-11 1989-01-10 1989-07-12 $7700.00 Window Closed / Lapsed

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