Patent US251121A successfully refreshed from Google Patents.
Patent US4034061A successfully refreshed from Google Patents.
US4034061A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Aluminum borate catalyst compositions and use thereof in chemical conversions
Assignee: Union Oil Company of California
•
Filing: 1975-06-30
•
Granted: 1977-07-05
•
Expires: 1995-06-30
Abstract
Abstract Certain crystalline aluminum borate catalyst supports containing about 8-25 weight-percent of B 2 O 3 are found to provide unusually stable and active catalysts for high-temperature chemical conversions, particularly exhaust gas conversion, when prepared by precalcining shaped composites of alumina and boria at temperatures between about 1250° and 2600° F, prior to the addition thereto of active metal or metals. Calcination at below 1250° F is found to yield amorphous catalysts of inferior activity, while at temperatures above 2600° F drastic reductions in surface area may occur.
Inventors
- 👤 Dennis P. McArthur
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 12:27
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9445; B01D53/945; B01J; B01J21/00; B01J21/02; B01J23/00; B01J23/70; B01J23/74; B01J23/755; C; C07; C07C; C07C1/00; C07C1/02; C07C2521/00; C07C2521/02; C07C2521/04; C07C2523/00; C07C2523/70; C07C2523/74; C07C2523/755; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/12
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
219 words
In a process wherein a desired chemical conversion is carried out by contacting at least one fluid reactant with a solid catalyst at temperatures in the range of about 600°- 3000° F., said catalyst comprising at least one catalytically active component selected from the group consisting of the metals of Groups IB, IIB, VB, VIB, VIIB and VIII, and catalytically active compounds thereof dispersed and supported on a shaped porous support, the improvement which comprises using as said catalyst a composite prepared by the steps of: (1) intimately admixing finely divided alumina in a dry or hydrous state with sufficient boria or boria precursor to provide in the finished catalyst a B 2 O 3 /Al 2 O 3 weight ratio between about 8/92 and 25/75; (2) forming the resulting mixture into an aggregate of desired shape for catalytic contacting; (3) calcining the shaped aggregate for a time and at temperatures sufficient to form a cohesive crystalline aluminum borate aggregate having a surface area between about 1 and 150 m 2 /g and a porosity of at least about 0.1 ml/g; (4) impregnating the calcined aggregate from step (3) with one or more soluble compounds of said catalytically active components; and (5) calcining the impregnated aggregate to convert said one or more soluble compounds to a catalytically active form.
Claim 2
Dependent Claim
219 words
In a process wherein a desired chemical conversion is carried out by contacting at least one fluid reactant with a solid catalyst at temperatures in the range of about 600°- 3000° F., said catalyst comprising at least one catalytically active component selected from the group consisting of the metals of Groups IB, IIB, VB, VIB, VIIB and VIII, and catalytically active compounds thereof dispersed and supported on a shaped porous support, the improvement which comprises using as said catalyst a composite prepared by the steps of: (1) intimately admixing finely divided alumina in a dry or hydrous state with sufficient boria or boria precursor to provide in the finished catalyst a B 2 O 3 /Al 2 O 3 weight ratio between about 8/92 and 25/75; (2) forming the resulting mixture into an aggregate of desired shape for catalytic contacting; (3) calcining the shaped aggregate for a time and at temperatures sufficient to form a cohesive crystalline aluminum borate aggregate having a surface area between about 1 and 150 m 2 /g and a porosity of at least about 0.1 ml/g; (4) impregnating the calcined aggregate from step (3) with one or more soluble compounds of said catalytically active components; and (5) calcining the impregnated aggregate to convert said one or more soluble compounds to a catalytically active form.
Claim 3
Dependent Claim
20 words
A process as defined in claim 1 wherein said catalytically active component comprises nickel, or an oxide or sulfide thereof.
Claim 4
Dependent Claim
60 words
A process as defined in claim 1 wherein said chemical conversion comprises the reduction of nitrogen oxides and/or the oxidation of unburned hydrocarbons and carbon monoxide in engine exhaust gases, and wherein said catalytically active component comprises at least one member selected from the class consisting of copper, nickel, cobalt, iron, platinum and palladium, and the oxides and sulfides thereof.
Claim 5
Dependent Claim
20 words
A process as defined in claim 3 wherein said shaped aggregate is in the form of 1/32- 1/2 inch granules.
Claim 6
Dependent Claim
29 words
A process as defined in claim 3 wherein said shaped aggregate is in the form of a monolithic structure traversed by channels of about 1/32- 1/4 inch in diameter.
Claim 7
Dependent Claim
35 words
A process as defined in claim 3 wherein said shaped aggregate is in the form of a membranous coating supported on an inert monolithic structure traversed by channels of about 1/32- 1/4 inch in diameter.
Claim 8
Dependent Claim
44 words
A process as defined in claim 3 wherein said catalytically active component comprises a mixture of copper or an oxide or sulfide thereof with at least one member selected from the class consisting of iron, cobalt and nickel and the oxides and sulfides thereof.
Claim 9
Dependent Claim
51 words
A process as defined in claim 1 wherein, following step (3) and prior to step (4), said shaped aggregate is leached with a reagent selected from the class consisting of hot water and aqueous ammonia to remove free B 2 O 3 therefrom without essentially altering the shape of said aggregate.
Claim 10
Dependent Claim
20 words
A process as defined in claim 1 wherein said shaped aggregate is in the form of 1/32- 1/2 inch granules.
Claim 11
Dependent Claim
29 words
A process as defined in claim 1 wherein said shaped aggregate is in the form of a monolithic structure traversed by channels of about 1/32- 1/4 inch in diameter.
Claim 12
Dependent Claim
35 words
A process as defined in claim 1 wherein said shaped aggregate is in the form of a membranous coating supported on an inert monolithic structure traversed by channels of about 1/32- 1/4 inch in diameter.
References Cited (Backward Citations)
US2118143A
Cited
GB923430A
Cited
US3071449A
Cited
US3164442A
Cited
US3331787A
Cited
US3755534A
Cited
US3883442A
Cited
US3856705A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-07-04 | 1981-01-03 | 1981-07-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-07-04 | 1985-01-03 | 1985-07-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-07-04 | 1989-01-03 | 1989-07-05 | $7700.00 | Window Closed / Lapsed |