Process for the preparation of aminated polymers useful as additives for fuels and lubricants

Claim 1

A method for preparing an oil-soluble, sludge dispersing, aminated copolymer, said aminated copolymer having a molecular weight in the range of about 1000 to 500,000 Mn, and containing about 0.02 to about 2.0 wt. % nitrogen, based on the weight of said aminated copolymer, comprising the steps of solution brominating a terpolymer having an olefinic double bond in a hydrocarbon moiety which is pendant to the backbone chain of carbon atoms with a brominating agent to incorporate from about 0.1 to 10 wt. % viscinally substituted bromine in said pendant hydrocarbon moiety, said terpolymer comprising ethylene, a C 3 to C 18 straight or branched chain α-olefin and a C 5 to C 14 acyclic or alicyclic non-conjugated diolefin, said solution brominating step being carried out at a temperature of from 0° to 100° C.; and thereafter aminating said brominated terpolymer with a C 1 to C 60 amine containing 1 to 12 amine groups by reacting said amine with said brominated terpolymer until from about 10 to 100 mole percent of the bromine content of said terpolymer is replaced by amination groups, said reacting being carried out at a temperature in the range of about 20° C. to about 150° C. and for a period of from 0.1 to 10 hours.

Claim 2

A method for preparing an oil-soluble, sludge dispersing, aminated copolymer, said aminated copolymer having a molecular weight in the range of about 1000 to 500,000 Mn, and containing about 0.02 to about 2.0 wt. % nitrogen, based on the weight of said aminated copolymer, comprising the steps of solution brominating a terpolymer having an olefinic double bond in a hydrocarbon moiety which is pendant to the backbone chain of carbon atoms with a brominating agent to incorporate from about 0.1 to 10 wt. % viscinally substituted bromine in said pendant hydrocarbon moiety, said terpolymer comprising ethylene, a C 3 to C 18 straight or branched chain α-olefin and a C 5 to C 14 acyclic or alicyclic non-conjugated diolefin, said solution brominating step being carried out at a temperature of from 0° to 100° C.; and thereafter aminating said brominated terpolymer with a C 1 to C 60 amine containing 1 to 12 amine groups by reacting said amine with said brominated terpolymer until from about 10 to 100 mole percent of the bromine content of said terpolymer is replaced by amination groups, said reacting being carried out at a temperature in the range of about 20° C. to about 150° C. and for a period of from 0.1 to 10 hours.

Claim 9

A method for preparing an oil-soluble, sludge dispersing, aminated copolymer, said aminated copolymer having a molecular weight in the range of about 1000 to 500,000 Mn, and containing about 0.02 to about 2.0 wt. % nitrogen, based on the weight of said aminated copolymer, comprising the steps of solution chlorinating a terpolymer having an olefinic double bond in a hydrocarbon moiety which is pendant to the backbone chain of carbon atoms with a chlorinating agent to incorporate from about 0.1 to 10 wt. % allylically substituted chlorine in said pendant hydrocarbon moiety, said terpolymer comprising ethylene, a C 3 to C 18 staight or branched chain α-olefin and a C 5 to C 14 acyclic or alicyclic non-conjugated diolefin, said solution chlorinating step being carried out at a temperature of from 0° to 100° C.; and thereafter aminating said chlorinated terpolymer with a C 1 to C 60 amine containing 1 to 12 amine groups by reacting said amine with said chlorinated terpolymer until from about 10 to 100 mole percent of the chlorine content of said terpolymer is replaced by amination groups, said reacting being carried out at a temperature in the range of about 80° C. to about 200° C. and for a period of from 3 to 100 hours.

Claim 10

A method for preparing an oil-soluble, sludge dispersing, aminated copolymer, said aminated copolymer having a molecular weight in the range of about 1000 to 500,000 Mn, and containing about 0.02 to about 2.0 wt. % nitrogen, based on the weight of said aminated copolymer, comprising the steps of solution chlorinating a terpolymer having an olefinic double bond in a hydrocarbon moiety which is pendant to the backbone chain of carbon atoms with a chlorinating agent to incorporate from about 0.1 to 10 wt. % allylically substituted chlorine in said pendant hydrocarbon moiety, said terpolymer comprising ethylene, a C 3 to C 18 staight or branched chain α-olefin and a C 5 to C 14 acyclic or alicyclic non-conjugated diolefin, said solution chlorinating step being carried out at a temperature of from 0° to 100° C.; and thereafter aminating said chlorinated terpolymer with a C 1 to C 60 amine containing 1 to 12 amine groups by reacting said amine with said chlorinated terpolymer until from about 10 to 100 mole percent of the chlorine content of said terpolymer is replaced by amination groups, said reacting being carried out at a temperature in the range of about 80° C. to about 200° C. and for a period of from 3 to 100 hours.