Patent US4742679A successfully refreshed from Google Patents.
Patent US4032609A successfully refreshed from Google Patents.
US4032609A
Expired / Lapsed
US
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Method for pre-expanding and molding expandable thermoplastic polymer particles
Assignee: Huntsman Chemical Corp
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Filing: 1975-07-22
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Granted: 1977-06-28
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Expires: 1995-07-22
Abstract
Abstract An energy saving and material conserving method and apparatus are provided for expanding and molding expandable thermoplastic polymer particles. Especially significant is the ability to produce molded objects of generally uniform density in the higher density range in the order of 4-15 pounds per square inch, or greater, as well as lower density molded objects due to improved control of the particle expansion. The particles are partially expanded in a vessel in a heated substantially dry atmosphere and agitated in a manner to provide uniform heating thereof. After an initial heating period to soften and partially expand the particles they are subjected to superatmospheric pressure to substantially prevent further expansion and are discharged and conveyed to a mold for further expansion therein. In certain instances, the particles are subjected to superatmospheric pressure within the vessel during a portion of the initial heating period to prevent premature particle expansion and loss of blowing agent within the particles. The temperature of the particles are continuously maintained above the boiling point of the blowing agent within said particles at all times subsequent to the partial expansion of the particles up to the final expansion and fusion of the particles in a mold.
Inventors
- 👤 Stuart B. Smith
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 20:19
CPC Classifications
B; B29; B29C; B29C44/00; B29C44/34; B29C44/3461; Y; Y10; Y10S; Y10S264/00; Y10S264/09; Y10S264/10; Y10S264/13; Y10S425/00; Y10S425/039
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
282 words
A method of mold expandable thermoplastic polymer particles containing a blowing agent comprising: (a) inserting a measured amount of the particles into a vessel; (b) heating the particles in a substantially dry atmosphere within said vessel to a temperature high enough to soften the polymer particles and volatize the blowing agent, the heat applied by conduction through the walls of the vessel and radiation therefrom and causing partial expansion of the particles; (c) agitating the particles within said vessel at all times during the heating thereof in a manner so that the particles are repeatedly wiped by an agitator within said vessel against the walls thereof and then returned toward the center of said vessel; (d) subjecting the particles while in their heat softened state to a super atmospheric pressure with a substantially dry gaseous medium after a predetermined period of heating in said vessel the pressure being adequate to substantially prevent further expansion of the particles to obtain the desired generally uniform density thereof; (e) removing the particles from said vessel with the aid of the gaseous medium under pressure which carries said particles out of the closed vessel when an exit opening is provided for the particles. (f) conveying the heated partially expanded particles to a mold and filling the mold therewith and; (g) heating the particles in the mold to effect the further expansion and fusion of the particles into the desired molded article; The temperature of the particles being continuously maintained above the boiling-point of the blowing agent within said particles at all time subsequent to the partial expansion of the particles in said vessel up to the final expansion and fusion of the particles within the mold.
Claim 2
Independent Claim
282 words
A method of mold expandable thermoplastic polymer particles containing a blowing agent comprising: (a) inserting a measured amount of the particles into a vessel; (b) heating the particles in a substantially dry atmosphere within said vessel to a temperature high enough to soften the polymer particles and volatize the blowing agent, the heat applied by conduction through the walls of the vessel and radiation therefrom and causing partial expansion of the particles; (c) agitating the particles within said vessel at all times during the heating thereof in a manner so that the particles are repeatedly wiped by an agitator within said vessel against the walls thereof and then returned toward the center of said vessel; (d) subjecting the particles while in their heat softened state to a super atmospheric pressure with a substantially dry gaseous medium after a predetermined period of heating in said vessel the pressure being adequate to substantially prevent further expansion of the particles to obtain the desired generally uniform density thereof; (e) removing the particles from said vessel with the aid of the gaseous medium under pressure which carries said particles out of the closed vessel when an exit opening is provided for the particles. (f) conveying the heated partially expanded particles to a mold and filling the mold therewith and; (g) heating the particles in the mold to effect the further expansion and fusion of the particles into the desired molded article; The temperature of the particles being continuously maintained above the boiling-point of the blowing agent within said particles at all time subsequent to the partial expansion of the particles in said vessel up to the final expansion and fusion of the particles within the mold.
Claim 3
Dependent Claim
41 words
The method of claim 1 wherein the particles are exposed to substantially dry air at generally atmospheric pressure during the heating period within the vessel except when the particles are exposed to superatmospheric pressure before the discharge thereof from said vessel.
Claim 4
Dependent Claim
87 words
The method of claim 1 wherein the particles are exposed to substantially dry air at generally atmospheric pressure during the heating period within the vessel except when the particles are exposed to superatmospheric pressure both during a time period soon after insertion into the vessel in order to prevent premature bead expansion and undesirable loss of blowing agent and in a time period just before discharge of the beads from the vessel in order to control bead expansion to achieve the desired generally uniform bead density desired.
Claim 5
Dependent Claim
53 words
The method of claim 1 for molding expandable thermoplastic polymer particles wherein during the molding cycle subsequent to the partial expansion of said particles in said vessel the temperature of the particles is maintained only slightly lower than that required to affect said further expansion and fusion of the particles within the mold.
Claim 6
Dependent Claim
26 words
The method of molding of claim 1 wherein the expandable thermoplastic particles are of polystyrene containing about 6% by weight of pentane as the blowing agent.
Claim 7
Independent Claim
209 words
A method of partially expanding expandable thermoplastic polymer particles containing a blowing agent, said particles being capable of further expansion, comprising: (a) inserting a measured amount of the particles into a vessel; (b) heating the particles in a substantially dry atmosphere within said vessel to a temperature high enough to soften the polymer particles and to volatize the blowing agent, the heat applied by conduction through the walls of the vessel and radiation therefrom and causing partial expansion of the particles; (c) agitating the particles within said vessel at all times during the heating thereof in a manner so that the particles are repeatedly wiped by an agitator within said vessel against the walls thereof and then returned toward the center of said vessel; (d) subjecting the particles while in their heat softened state to a super atmospheric pressure with a substantially dry gaseous medium after a predetermined period of heating in said vessel the pressure being adequate to substantially prevent further expansion of the particles to obtain the desired generally uniform density thereof; and (e) removing the particles from said vessel with the aid of the gaseous medium under pressure which carries said particles out of the closed vessel when an exit opening is provided for the particles.
Claim 8
Independent Claim
209 words
A method of partially expanding expandable thermoplastic polymer particles containing a blowing agent, said particles being capable of further expansion, comprising: (a) inserting a measured amount of the particles into a vessel; (b) heating the particles in a substantially dry atmosphere within said vessel to a temperature high enough to soften the polymer particles and to volatize the blowing agent, the heat applied by conduction through the walls of the vessel and radiation therefrom and causing partial expansion of the particles; (c) agitating the particles within said vessel at all times during the heating thereof in a manner so that the particles are repeatedly wiped by an agitator within said vessel against the walls thereof and then returned toward the center of said vessel; (d) subjecting the particles while in their heat softened state to a super atmospheric pressure with a substantially dry gaseous medium after a predetermined period of heating in said vessel the pressure being adequate to substantially prevent further expansion of the particles to obtain the desired generally uniform density thereof; and (e) removing the particles from said vessel with the aid of the gaseous medium under pressure which carries said particles out of the closed vessel when an exit opening is provided for the particles.
Claim 9
Dependent Claim
33 words
The temperature of the particles being continuously maintained above the boiling point of the blowing agent within said particles at all time subsequent to the partial expansion of the particles in said vessel.
Claim 10
Dependent Claim
33 words
The temperature of the particles being continuously maintained above the boiling point of the blowing agent within said particles at all time subsequent to the partial expansion of the particles in said vessel.
Claim 11
Dependent Claim
41 words
The method of claim 6 wherein the particles are exposed to substantially dry air at generally atmospheric pressure during the heating period within the vessel except when the particles are exposed to superatmospheric pressure before the discharge thereof from said vessel.
Claim 12
Dependent Claim
87 words
The method of claim 6 wherein the particles are exposed to substantially dry air at generally atmospheric pressure during the heating period within the vessel except when the particles are exposed to superatmospheric pressure both during a time period soon after insertion into the vessel in order to prevent premature bead expansion and undesirable loss of blowing agent and in a time period just before discharge of the beads from the vessel in order to control bead expansion to achieve the desired generally uniform bead density desired.
Claim 13
Dependent Claim
26 words
The method of molding of claim 6 wherein the expandable thermoplastic particles are of polystyrene containing about 6% by weight of pentane as the blowing agent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-06-27 | 1980-12-27 | 1981-06-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-06-27 | 1984-12-27 | 1985-06-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-06-27 | 1988-12-27 | 1989-06-28 | $7700.00 | Window Closed / Lapsed |