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US4032515A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable resorcinol terminated urea-formaldehyde resins

Assignee: Beazer East Inc
•
Filing: 1975-07-24
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Granted: 1977-06-28
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Expires: 1995-07-24
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Abstract

Abstract A urea-formaldehyde resin based adhesive that is resistant to heat and hydrolysis and hence is useful for exterior use in plywood and laminated timbers consists of a resorcinol terminated urea-formaldehyde resin having the general formula: ##STR1## where η = 0 to 10, that is cured by conventional hardeners under neutral or alkaline conditions.

Inventors

  • 👤 Elizabeth A. Blommers
  • 👤 Roy H. Moult

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:12
CPC Classifications
C; C08; C08J; C08J3/00; C08G; C08G14/00; C08G14/02; C08G14/04; C08G14/06; C08G14/08; C08J2361/00; C08J2361/34

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 34 words
An adhesive comprising a resorcinol terminated urea-formaldehyde resin having the general formula: ##STR5## where η = 0 to 10, said resin being cured under neutral or alkaline conditions by reacting it with a formaldehyde.
Claim 2
Dependent Claim 34 words
An adhesive comprising a resorcinol terminated urea-formaldehyde resin having the general formula: ##STR5## where η = 0 to 10, said resin being cured under neutral or alkaline conditions by reacting it with a formaldehyde.
Claim 3
Dependent Claim 17 words
An adhesive as set forth in claim 1 wherein said resin is a sulfite-modified resorcinol terminated urea-formaldehyde.
Claim 4
Dependent Claim 13 words
An adhesive as set forth in claim 1 wherein said formaldehyde is paraformaldehyde.
Claim 5
Dependent Claim 95 words
In a method for forming an adhesive composition in which a compound of urea and formaldehyde is formed to a pH of about 8 and is polymerized to form a urea-formaldehyde resin under acid conditions of pH between about 3 and 4, the steps comprising: forming terminal methylol groups on the said resin under alkaline conditions, substituting terminal resorcinol groups for the hydroxyl radicals at a temperature of at most about 50° C. and at a pH no greater than 4, and cross-linking the so-formed resorcinol-terminated urea-formaldehyde resin at a pH of at least 7.
Claim 6
Dependent Claim 95 words
In a method for forming an adhesive composition in which a compound of urea and formaldehyde is formed to a pH of about 8 and is polymerized to form a urea-formaldehyde resin under acid conditions of pH between about 3 and 4, the steps comprising: forming terminal methylol groups on the said resin under alkaline conditions, substituting terminal resorcinol groups for the hydroxyl radicals at a temperature of at most about 50° C. and at a pH no greater than 4, and cross-linking the so-formed resorcinol-terminated urea-formaldehyde resin at a pH of at least 7.
Claim 7
Dependent Claim 27 words
The method of claim 4 in which the terminal resorcinol is added in a molar ratio to the originally employed urea of greater than 0.5 to 1.
Claim 8
Dependent Claim 29 words
The method of claim 4 in which the urea-formaldehyde resin is formed in a ratio of urea to formaldehyde of between about 1 to 2 and 1 to 1.

References Cited (Backward Citations)

US2437710A Cited
US2500543A Cited
DE1102394B Cited
US3076772A Cited
US3429770A Cited
US3336246A Cited
US3492263A Cited
US3547868A Cited
US3852374A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-27 1980-12-27 1981-06-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-27 1984-12-27 1985-06-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-27 1988-12-27 1989-06-28 $7700.00 Window Closed / Lapsed

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