Abstract A hot melt composition is used to form a closure liner, e.g. the circular, integral, gasket-like member adhered to the periphery of a circular top or closure for a food jar or the like. The hot melt composition is selected to have, in the solid state, sufficient deformabilty, resiliency, hardness, lubricity, and other requirements of closure liners. It has been found that silicone oil, used in a concentration of about 1-8% by weight of the total hot melt composition can provide a high degree of lubricity, similar to the type of lubricity in self-lubricated plastic bearings. The remainder of the hot melt system or composition generally comprises a rubbery block co-polymer (serving as a film former), a hydrocarbon wax, a hydrocarbon oil, and, if desired, a thermoplastic vinyl arene polymer such as poly(methylstyrene). To apply the hot melt composition to the closure, the hot melt is poured on in a molten or flowable state, and this flowable state is maintained, so that the resulting deposit of hot melt composition seeks its own level under the influence of gravity.
A hot melt composition comprising an intimate admixture of the following components: (a) 15-45% by weight of a hydrocarbon wax; (b) 5-35% by weight of a rubbery block co-polymer said block co-polymer comprising at least one A-B-A unit, the A blocks of said A-B-A unit comprising repeating vinyl arene units and the B block comprising a rubbery ethylene-butylene or butadiene polymer; (c) 20-45% by weight of an essentially hydrocarbon oil; (d) 1-8% by weight of a liquid silicone which is essentially non-toxic; and (e) up to 30% by weight of a resinous thermoplastic polymer containing vinyl arene units; said hot melt composition being substantially homogeneous in the molten phase and being deformable thermoplastic solid which is lubricitous and generally tack-free at the surfaces at temperatures below 65° C.; said hot melt composition being flowable at temperatures below 320° C.
Claim 2
Dependent Claim
139 words
A hot melt composition comprising an intimate admixture of the following components: (a) 15-45% by weight of a hydrocarbon wax; (b) 5-35% by weight of a rubbery block co-polymer said block co-polymer comprising at least one A-B-A unit, the A blocks of said A-B-A unit comprising repeating vinyl arene units and the B block comprising a rubbery ethylene-butylene or butadiene polymer; (c) 20-45% by weight of an essentially hydrocarbon oil; (d) 1-8% by weight of a liquid silicone which is essentially non-toxic; and (e) up to 30% by weight of a resinous thermoplastic polymer containing vinyl arene units; said hot melt composition being substantially homogeneous in the molten phase and being deformable thermoplastic solid which is lubricitous and generally tack-free at the surfaces at temperatures below 65° C.; said hot melt composition being flowable at temperatures below 320° C.
Claim 3
Dependent Claim
23 words
A hot melt composition according to claim 1 wherein said rubbery block co-polymer is a three block A-B-A co-polymer with the structure: polystyrene-poly(ethylene-butylene)-polystyrene.
Claim 4
Dependent Claim
33 words
A hot melt composition according to claim 2 wherein said wax is a paraffin wax, said liquid silicone is dimethylpolysiloxane, and said vinyl arene units of said resinous thermoplastic polymer are methylstyrene units.
Claim 5
Dependent Claim
21 words
A hot melt composition according to claim 3 wherein said composition contains about 5- 30% by weight of said component (e).
Claim 6
Dependent Claim
108 words
A hot melt composition according to claim 1 consisting essentially of: about 20% by weight of a paraffin wax with a melting point above 150° F.; about 10% by weight of a rubbery three block co-polymer with terminal polystyrene blocks and a central, rubbery poly(ethylene-butylene) block; about 40% by weight of a hydrocarbon oil consisting essentially of a blend of naphthenic and paraffinic hydrocarbons and an aromatic content not exceeding about 5% by weight; about 5% by weight of a liquid dimethylpolysiloxane; and about 25% by weight of a vinyltoluene-alphamethylstyrene co-polymer having a ring and ball softening point within the range of about 70° to about 120° C.