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Aqueous acrylate-epoxy silane crosslinker adhesive dispersion composition

Assignee: Hexion Inc
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Filing: 1976-04-12
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Granted: 1977-06-28
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Expires: 1996-04-12
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Abstract

Abstract An adhesive composition which comprises, for each 100 parts by weight thereof, an aqueous dispersion having pH of about 8 to 12 of the following components dispersed in 25 to 75 parts of water: A. from 25 to 75 parts by weight of water insoluble linear polymer containing the following interpolymerized unsaturated monomers in parts by weight based on the weight of the polymer: 1. at least 50 parts and up to 99 parts of an acrylate monomer containing from about 4 to 27 carbon atoms selected from alkyl acrylates, alkyl methacrylates, and mixtures thereof: 2. from about 0.1 to 10 parts of a nitrogen monomer selected from vinyl amines and salts thereof; vinyl ureido monomers; vinyl compounds having heterocyclic nitrogen containing groups and halogen, hydroxyalkyl or aminoalkyl substituted derivatives thereof; amino and loweralkyl amino loweralkyl acrylates and methacrylates; and mixtures thereof; 3. from about 0.1 to 25 parts of an acid selected from acrylic acid, methacrylic acid and mixtures thereof; B. from a small but effective amount to effect cross-linking of the polymer to 5 parts of a silane containing both alkoxy and epoxy functionalities.

Inventors

  • 👤 Peter Spiros Columbus

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 13:53
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54; C08K5/541; C08K5/5435; C09; C09J; C09J133/00; C09J133/04; C09J133/06; C09J133/062; C09J133/064; C08L; C08L2666/00; C08L2666/28; C08L2666/44; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31645; Y10T428/31649; Y10T428/31826; Y10T428/31833

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 274 words
An aqueous adhesive dispersion composition of pH of 8 to 12 containing 25 to 75% by weight of water having dispersed therein reaction product of A and B, as defined below: A. a water insoluble binder polymer having the following structural formula: ##STR7## vinyl unit I nitrogen unit II acrylate unit III where R 1 and R 2 , which can be same or different are selected from H, lower-alkyl groups of 1 to 4 carbon atoms, halogens, --CH 2 COOR, --COOR, and --CH 2 COOH groups where R is a lower alkyl group of 1 to 8 carbon atoms; R 3 is selected from H and lower alkyl groups of 1 to 8 carbon atoms, at least or portion of R 3 radical being H to give free carboxyl groups; R 4 and R 5 , which can be same or different, are selected from H, --COOH and --COOR groups, where R is as defined above; X is derived from copolymerizable vinyl monomers and is different from the acrylate unit III; Y is a nitrogen-containing radical of unit II which is derived from a nitrogen-containing monomer; radical Y is selected from the following radicals: ##STR8## where R 6 is selected from H, --R 7 NR 8 and --R 7 OH; R 7 and R 8 being same or different lower alkyl radicals of 1 to 5 carbon atoms; R 9 is a heterocyclic nitrogen-containing group selected from substituted ethylene urea groups; R 10 is a heterocyclic nitrogen-containing group selected from pyridyl groups; and B. an effective amount, to effect crosslinking of the binder polymer, of a silane containing both alkoxy and epoxy functionalites.
Claim 2
Dependent Claim 274 words
An aqueous adhesive dispersion composition of pH of 8 to 12 containing 25 to 75% by weight of water having dispersed therein reaction product of A and B, as defined below: A. a water insoluble binder polymer having the following structural formula: ##STR7## vinyl unit I nitrogen unit II acrylate unit III where R 1 and R 2 , which can be same or different are selected from H, lower-alkyl groups of 1 to 4 carbon atoms, halogens, --CH 2 COOR, --COOR, and --CH 2 COOH groups where R is a lower alkyl group of 1 to 8 carbon atoms; R 3 is selected from H and lower alkyl groups of 1 to 8 carbon atoms, at least or portion of R 3 radical being H to give free carboxyl groups; R 4 and R 5 , which can be same or different, are selected from H, --COOH and --COOR groups, where R is as defined above; X is derived from copolymerizable vinyl monomers and is different from the acrylate unit III; Y is a nitrogen-containing radical of unit II which is derived from a nitrogen-containing monomer; radical Y is selected from the following radicals: ##STR8## where R 6 is selected from H, --R 7 NR 8 and --R 7 OH; R 7 and R 8 being same or different lower alkyl radicals of 1 to 5 carbon atoms; R 9 is a heterocyclic nitrogen-containing group selected from substituted ethylene urea groups; R 10 is a heterocyclic nitrogen-containing group selected from pyridyl groups; and B. an effective amount, to effect crosslinking of the binder polymer, of a silane containing both alkoxy and epoxy functionalites.
Claim 3
Dependent Claim 89 words
Composition of claim 1 wherein the vinyl unit A is derived from acrylate monomer A represented by ##STR9## where R 11 is H or an alkyl group having from 1 to 4 carbon atoms and R 12 is an alkyl radical having from about 1 to 14 carbon atoms; acrylate monomer B represented by ##STR10## where R 11 is H or an alkyl group having from 1 to 4 carbon atoms and R 22 is an alkyl radical having from about 13 to 20 carbon atoms; and mixtures thereof.
Claim 4
Dependent Claim 26 words
Composition of claim 2 wherein Tg of the binder polymer is selected from the values of below 0° C. and between 10° C. and 25° C.
Claim 5
Dependent Claim 72 words
Composition of claim 3 wherein the R 12 radical of the acrylate monomer A has 3 to 12 carbon atoms when R 11 is H or methyl, and when R 11 is alkyl R 12 has 6 to 14 carbon atoms; R 22 has 13 to 20 carbon atoms when R 11 is H and R 22 has 1 to 5 or 15 to 20 carbon atoms when R 11 is methyl.
Claim 6
Dependent Claim 35 words
Composition of claim 4 wherein R 11 is H or methyl and wherein the nitrogen monomer is selected from amino and loweralkyl amino loweralkyl acrylates and methaacrylates, pyridyl loweralkyl acrylates and methacrylates, and mixtures thereof.
Claim 7
Dependent Claim 85 words
Composition of claim 1 wherein the vinyl unit is derived from acrylate monomers selected from C 1 to C 4 alkyl acrylates, methacrylates and mixtures thereof; the nitrogen unit is derived from monomers selected from amino and C 1 to C 5 alkyl amino and C 1 to C 5 alkyl acrylates and methacrylates, pyridyl C 1 to C 5 alkyl acrylates and methacrylates, and mixtures thereof; and the acrylate unit III is derived from monomers selected from acrylic acid, methacrylic acid and mixtures thereof.
Claim 8
Dependent Claim 21 words
Composition of claim 6 wherein the composition includes an effective amount of hydroxyethyl cellulose and propylene glycol to provide freeze-thaw stability.
Claim 9
Dependent Claim 21 words
Composition of claim 7 wherein the silane is selected from beta- (3, 4 epoxycyclohexyl) ethyltrimethoxy silane, gamma-glycidoxypropyltrimethoxy silane and epoxytrimethoxy silane.
Claim 10
Dependent Claim 26 words
Composition of claim 8 wherein the vinyl unit I is derived from monomers selected from a mixture of methyl methacrylate and ethyl acrylate or butyl acrylate.
Claim 11
Dependent Claim 25 words
Composition of claim 9 wherein the unit II is derived from nitrogen monomers selected from pyridyl ethyl methacrylate, dimethylaminoethyl methacrylate, dimethylaminomethyl methacrylate and mixtures thereof.
Claim 12
Dependent Claim 42 words
Composition of claim 6 wherein the vinyl monomer is used in amount of at least 50% by weight and up to 99%, whereas amount of the nitrogen monomer can vary from 0.1 to 10% and the acrylate monomer from 0.1 to 5%.
Claim 13
Dependent Claim 16 words
Composition of claim 11 wherein the acrylate monomer is used in amount of 1 to 5%.

References Cited (Backward Citations)

US3759915A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-27 1980-12-27 1981-06-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-27 1984-12-27 1985-06-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-27 1988-12-27 1989-06-28 $7700.00 Window Closed / Lapsed

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