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US4032468A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrolytically stable urethane foam precursors

Assignee: Air Products and Chemicals Inc
•
Filing: 1976-09-13
•
Granted: 1977-06-28
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Expires: 1996-09-13
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Abstract

Abstract The hydrolytic stability of catalyst-containing precursors for both flexible and rigid polyurethane foams wherein the catalyst is a tin compound is considerably increased when the catalyst is a triorganotin compound wherein the hydrocarbon groups bonded to the tin atom are methyl or methoxymethyl.

Inventors

  • 👤 Kenneth Treadwell
  • 👤 Melvin H. Gitlitz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:56
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/16; C08G18/22; C08G18/24; C08G18/242; C08G2110/00; C08G2110/0008; C08G2110/0025; C08G2110/0083

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 136 words
A hydrolytically stable precursor for preparing flexible or rigid cellular polyurethanes, said precursor consisting essentially of 100 parts by weight of a polyalkylene polyol, between 0.5 and 5 parts of water, between 0.05 and 0.5 parts of a foaming catalyst, between 0.05 and 2 parts of a silicone surfactant and between 0.05 and 0.5 parts of a gel catalyst, said gel catalyst being selected from the group consisting of organotin compounds of the formulae R a SnX 4 -- a , R 2 SnO and (R 3 Sn) 2 O wherein R is CH 3 -- or CH 3 OCH 2 --, X is selected from the group consisting of the chlorine, bromine and iodine atoms and radicals of the formula --OOCCH 3 or --OOCCH 2 CH 3 and a is the integer 2 or 3.
Claim 2
Dependent Claim 136 words
A hydrolytically stable precursor for preparing flexible or rigid cellular polyurethanes, said precursor consisting essentially of 100 parts by weight of a polyalkylene polyol, between 0.5 and 5 parts of water, between 0.05 and 0.5 parts of a foaming catalyst, between 0.05 and 2 parts of a silicone surfactant and between 0.05 and 0.5 parts of a gel catalyst, said gel catalyst being selected from the group consisting of organotin compounds of the formulae R a SnX 4 -- a , R 2 SnO and (R 3 Sn) 2 O wherein R is CH 3 -- or CH 3 OCH 2 --, X is selected from the group consisting of the chlorine, bromine and iodine atoms and radicals of the formula --OOCCH 3 or --OOCCH 2 CH 3 and a is the integer 2 or 3.
Claim 3
Dependent Claim 17 words
A hydrolytically stable precursor as described in claim 1 wherein X is chlorine or --OOCCH 3 .
Claim 4
Dependent Claim 13 words
A hydrolytically stable precursor as described in claim 2 wherein R is methyl.

References Cited (Backward Citations)

US3194773A Cited
US3392153A Cited
US3044971A Cited
US3507815A Cited
US3378497A Cited
US3822223A Cited
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US3876567A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-27 1980-12-27 1981-06-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-27 1984-12-27 1985-06-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-27 1988-12-27 1989-06-28 $7700.00 Window Closed / Lapsed

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