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Antistatic agents for melt-formed polymers

Assignee: BASF Corp
•
Filing: 1974-03-22
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Granted: 1977-06-14
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Expires: 1994-03-22
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Abstract

Abstract Permanent antistatic properties are imparted to melt-formed polymers by the incorporation therewith of a polymer composition prepared by reacting a hydrogen-reactive compound with an alkylene oxide adduct of a nitrogen-containing compound. Further, the polymer composition may be capped to minimize reaction with the melt-formed polymer.

Inventors

  • 👤 Eugene A. Weipert
  • 👤 Charles F. Deck

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 08:10
CPC Classifications
C; C08; C08L; C08L77/00; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/48; C08G18/50; C08G18/5021; C08G63/00; C08G63/68; C08G63/685; C08G63/6854; C08G65/00; C08G65/02; C08G65/26; C08G65/2618; C08G65/2621; C08L101/00; Y; Y10; Y10S; Y10S524/00; Y10S524/91; Y10S524/913

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 201 words
An antistatic agent prepard by the reaction in a mole ratio of (a) to (b) of from about 0.5:1.0 to 1.0:1.0 at a temperature from about 60° to 160° C. for a period of from about 1 to about 4 hours of: a. an alkyl ester of a dicarboxylic acid represented by the formula: R"OOC--R--COOR' wherein R is the organic portion of the dicarboxylic acid selected from the group consisting of oxalic, malonic, succinic, glutaric, adipic, pimelic, suberic, azelaic, sebasic, phthalic, isophthalic, terephthalic, and hydrogenated terephthalic, and R' and R" are, each, individually, alkyl having from one to four carbon atoms, or hydroxyalkyl having from two to four carbon atoms with b. an alkylene oxide adduct of a nitrogen-containing compound selected from the group consisting of alkanolamine, alkanolpolyamine, alkylene polyamine, polyalkylenepolyamine, aromatic polyamine and α -olefin oxide adducts thereof, said alkylene oxide selected from the group consisting of ethylene oxide or a mixture of ethylene oxide and a lower alkylene oxide having from three to four carbon atoms, said mixture comprising at least 25% by weight of ethylene oxide, said adduct having a molecular weight of from 1,000 to 40,000 and comprising from 60% to 99% by weight of alkylene oxide.
Claim 2
Dependent Claim 201 words
An antistatic agent prepard by the reaction in a mole ratio of (a) to (b) of from about 0.5:1.0 to 1.0:1.0 at a temperature from about 60° to 160° C. for a period of from about 1 to about 4 hours of: a. an alkyl ester of a dicarboxylic acid represented by the formula: R"OOC--R--COOR' wherein R is the organic portion of the dicarboxylic acid selected from the group consisting of oxalic, malonic, succinic, glutaric, adipic, pimelic, suberic, azelaic, sebasic, phthalic, isophthalic, terephthalic, and hydrogenated terephthalic, and R' and R" are, each, individually, alkyl having from one to four carbon atoms, or hydroxyalkyl having from two to four carbon atoms with b. an alkylene oxide adduct of a nitrogen-containing compound selected from the group consisting of alkanolamine, alkanolpolyamine, alkylene polyamine, polyalkylenepolyamine, aromatic polyamine and α -olefin oxide adducts thereof, said alkylene oxide selected from the group consisting of ethylene oxide or a mixture of ethylene oxide and a lower alkylene oxide having from three to four carbon atoms, said mixture comprising at least 25% by weight of ethylene oxide, said adduct having a molecular weight of from 1,000 to 40,000 and comprising from 60% to 99% by weight of alkylene oxide.
Claim 3
Dependent Claim 10 words
The antistatic agent of claim 2 wherein (a) is dimethylterephthalate.
Claim 4
Dependent Claim 20 words
The antistatic agent of claim 1 wherein (b) is an ethylene oxide adduct of a propylene oxide adduct of ethylenediamine.
Claim 5
Dependent Claim 24 words
The antistatic agent of claim 1 wherein (a) is dimethylterephthalate and (b) is an ethylene oxide adduct of a propylene oxide adduct of ethylenediamine.
Claim 6
Dependent Claim 21 words
The antistatic agent of claim 1 wherein (b) is an ethylene oxide adduct of an α -olefin oxide adduct of ethanolamine.
Claim 7
Dependent Claim 25 words
The antistatic agent of claim 1 wherein (a) is dimethylterephthalate and (b) is an ethylene oxide adduct of an α -olefin oxide adduct of ethanolamine.
Claim 8
Dependent Claim 69 words
A compound obtained by the reaction, at a temperature from about 80° to about 180° C. for about 1 to 6 hours, of the antistatic agent of claim 1 with an aromatic carboxylic acid or ester in an amount ranging from about 0.5 to 4.0 moles of said acid or ester per hydroxyl equivalent of said antistatic agent whereby esterification of the hydroxyl groups of the antistatic agent occurs.

References Cited (Backward Citations)

US2626919A Cited
US3121750A Cited
US2901451A Cited
US3200155A Cited
US3381022A Cited
US3464925A Cited
US3585185A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-13 1980-12-13 1981-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-13 1984-12-13 1985-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-13 1988-12-13 1989-06-14 $7700.00 Window Closed / Lapsed

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