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US4029670A Expired / Lapsed US ⏱️ 0.0 years remaining

Polychromophoric heterocyclic ultraviolet stabilizers

Assignee: Eastman Kodak Co
•
Filing: 1975-09-19
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Granted: 1977-06-14
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Expires: 1995-09-19
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Abstract

Abstract The invention relates to bichromophoric heterocyclic ester compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of these bichromophoric heterocyclic ester compositions to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.

Inventors

  • 👤 David M. Pond
  • 👤 William C. Dickason
  • 👤 Edward U. Elam

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 17:00
CPC Classifications
C; C07; C07D; C07D263/00; C07D263/52; C07D263/54; C07D263/56; C07D263/57; C07D249/00; C07D249/16; C07D249/18; C07D249/20; C07D263/62; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3472; C08K5/3475

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 289 words
A polychromophoric compound having the formula: (A).sub.x --C where A is a group having the structure ##STR15## wherein R 1 , R 2 , R 3 , R 4 and R 5 are hydrogen, chloro, bromo, fluoro, lower alkyl, cycloalkyl, phenyl, lower alkylphenyl, phenyl-substituted-phenyl, alkoxy, phenoxy, dilower alkyl substituted amino, cyano, carboalkoxy and the substituents R 1 and R 2 , R 2 and R 3 , and R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the heterocyclic ring and the carbon atom attached to the carbonyl group connecting the heterocyclic aromatic A group with the aromatic C group, at least one I substituent on one of the carbon atoms adjacent to said carbon atom attached to said carbonyl group is hydrogen and said remaining I substituents can all be the same or different; x is an integer of 1 to 4; and C is: a. an aromatic group having the formula ##STR16## where I is the same substituent as listed above and is present in all positions of the benzenoid ring except the carbon atom attached to the carbonyl group connecting the A and C moieties, and said I substituents can all be one of the substituents listed above or different listed substituents; or b. an aromatic group having the formula ##STR17##
Claim 2
Dependent Claim 289 words
A polychromophoric compound having the formula: (A).sub.x --C where A is a group having the structure ##STR15## wherein R 1 , R 2 , R 3 , R 4 and R 5 are hydrogen, chloro, bromo, fluoro, lower alkyl, cycloalkyl, phenyl, lower alkylphenyl, phenyl-substituted-phenyl, alkoxy, phenoxy, dilower alkyl substituted amino, cyano, carboalkoxy and the substituents R 1 and R 2 , R 2 and R 3 , and R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the heterocyclic ring and the carbon atom attached to the carbonyl group connecting the heterocyclic aromatic A group with the aromatic C group, at least one I substituent on one of the carbon atoms adjacent to said carbon atom attached to said carbonyl group is hydrogen and said remaining I substituents can all be the same or different; x is an integer of 1 to 4; and C is: a. an aromatic group having the formula ##STR16## where I is the same substituent as listed above and is present in all positions of the benzenoid ring except the carbon atom attached to the carbonyl group connecting the A and C moieties, and said I substituents can all be one of the substituents listed above or different listed substituents; or b. an aromatic group having the formula ##STR17##
Claim 3
Dependent Claim 187 words
A compound according to claim 1 having the formula ##STR18## wherein R 1 , R 2 , R.sub. 3, R 4 and R 5 are hydrogen, chloro, bromo, lower alkyl, cycloalkyl, phenyl, lower alkyl phenyl, alkoxy, phenyloxy, diloweralkyl substituted amino, and cyano, carboalkoxy, and the substituents R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the carbonyl linking substituent, at least one of said I substituents on the carbon atom adjacent to said carbon atom attached to said carbonyl group is hydrogen and the remaining I substituents can all be one of the substituents listed above or different listed substituents.
Claim 4
Dependent Claim 10 words
A compound according to claim 2 having the formula: ##STR19##
Claim 5
Dependent Claim 10 words
A compound according to claim 2 having the formula: ##STR20##
Claim 6
Dependent Claim 10 words
A compound according to claim 2 having the formula ##STR21##
Claim 7
Dependent Claim 10 words
A compound according to claim 2 having the formula: ##STR22##
Claim 8
Dependent Claim 10 words
A compound according to claim 2 having the formula: ##STR23##
Claim 9
Dependent Claim 10 words
A compound according to claim 2 having the formula: ##STR24##

References Cited (Backward Citations)

US3936418A Cited
US3954706A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-13 1980-12-13 1981-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-13 1984-12-13 1985-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-13 1988-12-13 1989-06-14 $7700.00 Window Closed / Lapsed

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