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US3954706A Expired / Lapsed US ⏱️ 0.0 years remaining

Polychromophoric benzotriazole ultraviolet stabilizers for organic compositions

Assignee: Eastman Kodak Co
•
Filing: 1974-10-02
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Granted: 1976-05-04
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Expires: 1994-10-02
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Abstract

Abstract The invention relates to polychromophoric compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the polychromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.

Inventors

  • 👤 Richard Hsu-Shien Wang
  • 👤 Gether Irick, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 19:50
CPC Classifications
C; C07; C07D; C07D249/00; C07D249/16; C07D249/18; C07D249/20; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3472; C08K5/3475; C09; C09K; C09K15/00; C09K15/04; C09K15/30

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 312 words
An organic composition susceptible to ultraviolet light degradation stabilized against such degradation with a stabilizing amount of at least one compound having the formula: (A).sub.a --C wherein A is a group having the structure ##SPC9## wherein the oxy group is in the meta or para position to the benzotriazole group; R 1 , r 2 , r 3 and R 4 are hydrogen, chloro, bromo, fluoro, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, aryl-substituted-aryl, alkoxy, substituted amino, cyano, carboalkoxy and the substituents R 1 and R 2 , R 2 and R 3 , and R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the heterocyclic ring and the carbon atom attached to the carbonyl group connecting the heterocyclic aromatic A group with the aromatic C group, at least one I substituent on one of the carbon atoms adjacent to said carbon atoms attached to said carbonyl group is hydrogen and said remaining I substituents can all be the same or different; a is an integer of 1 to 4; and C is an aromatic group having the formula: ##SPC10## where I is the same substituent as listed above and is present in all positions of the benzenoid ring except the carbon atom attached to the carbonyl group connecting the A and C moieties, and said I substituents can all be one of the substituents listed above or different listed substituents.
Claim 2
Dependent Claim 312 words
An organic composition susceptible to ultraviolet light degradation stabilized against such degradation with a stabilizing amount of at least one compound having the formula: (A).sub.a --C wherein A is a group having the structure ##SPC9## wherein the oxy group is in the meta or para position to the benzotriazole group; R 1 , r 2 , r 3 and R 4 are hydrogen, chloro, bromo, fluoro, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, aryl-substituted-aryl, alkoxy, substituted amino, cyano, carboalkoxy and the substituents R 1 and R 2 , R 2 and R 3 , and R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the heterocyclic ring and the carbon atom attached to the carbonyl group connecting the heterocyclic aromatic A group with the aromatic C group, at least one I substituent on one of the carbon atoms adjacent to said carbon atoms attached to said carbonyl group is hydrogen and said remaining I substituents can all be the same or different; a is an integer of 1 to 4; and C is an aromatic group having the formula: ##SPC10## where I is the same substituent as listed above and is present in all positions of the benzenoid ring except the carbon atom attached to the carbonyl group connecting the A and C moieties, and said I substituents can all be one of the substituents listed above or different listed substituents.
Claim 3
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC11##
Claim 4
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC12##
Claim 5
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC13##
Claim 6
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC14##
Claim 7
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC15##
Claim 8
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC16##
Claim 9
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC17##
Claim 10
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC18##
Claim 11
Dependent Claim 20 words
An organic composition according to claim 1 containing a stabilizing amount of a composition of matter having the formula: ##SPC19##
Claim 12
Dependent Claim 232 words
An organic composition susceptible to ultraviolet degradation stabilized against such degradation with a stabilizing amount of at least one compound according to claim 1 having the formula: ##SPC20## wherein the ester linking group is in the meta or para position to the benzotriazole group; a is an integer of 2 to 4; R 1 , r 2 , r 3 and R 4 are hydrogen, chloro, bromo, lower alkyl, substituted lower alkyl, cycloalkyl, substituted cycloalkyl, aryl, substituted aryl, lower alkylaryl, alkoxy, aryloxy, substituted amino, cyano, carboalkoxy and the substituents R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the carbonyl linking substituent, at least one of said I substituents on one of the carbon atoms adjacent to said carbon atom attached to said carbonyl group is hydrogen and the remaining I substituents can all be one of the substituents listed above or different listed substituents.
Claim 13
Dependent Claim 11 words
An organic composition according to claim 11 having the formula: ##SPC21##
Claim 14
Dependent Claim 20 words
An organic composition according to claim 11 containing a stabilizing amount of a composition of matter having the formula: ##SPC22##
Claim 15
Dependent Claim 20 words
An organic composition according to claim 11 containing a stabilizing amount of a composition of matter having the formula: ##SPC23##
Claim 16
Dependent Claim 20 words
An organic composition according to claim 11 containing a stabilizing amount of a composition of matter having the formula: ##SPC24##
Claim 17
Dependent Claim 20 words
An organic composition according to claim 11 containing a stabilizing amount of a composition of matter having the formula: ##SPC25##
Claim 18
Dependent Claim 20 words
An organic composition according to claim 11 containing a stabilizing amount of a composition of matter having the formula: ##SPC26##
Claim 19
Dependent Claim 20 words
An organic composition according to claim 11 containing a stabilizing amount of a composition of matter having the formula: ##SPC27##
Claim 20
Dependent Claim 20 words
An organic composition according to claim 11 containing a stabilizing amount of a composition of matter having the formula: ##SPC28##
Claim 21
Dependent Claim 20 words
An organic composition according to claim 11 containing a stabilizing amount of a composition of matter having the formula: ##SPC29##

References Cited (Backward Citations)

US3004896A Cited
US3385910A Cited
US3366668A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-04 1979-11-03 1980-05-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-04 1983-11-03 1984-05-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-04 1987-11-03 1988-05-04 $7700.00 Window Closed / Lapsed

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