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US4029606A Expired / Lapsed US ⏱️ 0.0 years remaining

Non-liquid detergent composition

Assignee: Lion Corp
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Filing: 1975-05-09
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Granted: 1977-06-14
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Expires: 1995-05-09
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Abstract

Abstract A non-liquid detergent composition prepared by shaping a detergent composition comprising an acyl-poly-hydroxy carboxylate having the formula <IMAGE> (wherein R represents a saturated or unsaturated straight-chain or branched-chain hydrocarbon group having 5 to 19 carbon atoms, R' represents H, CH3 or C2H5, n is an integer of 1 or more, m is an integer ranging from 1 to 2, and M represents monovalent or divalent cation).

Inventors

  • 👤 Hiroshi Isa
  • 👤 Noboru Suzuki
  • 👤 Masatoshi Takahashi
  • 👤 Eriko Hirayama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 10:12
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/02; C11D1/04

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 231 words
A solid detergent composition in the form of a powder, granules or tablets, consisting essentially of a mixture obtained by blending a. from 5 to 80 weight percent of organic surfactant substance having the formula ##STR6## wherein R is saturated or unsaturated straight-chain or branched-chain hydrocarbon having 5 to 19 carbon atoms, with the proviso that more than 70 weight percent of R has from 10 to 14 carbon atoms, R' is hydrogen, CH 3 or C 2 H 5 , n is a number in the range of 1.7 to 6.5 on the average, M is a monovalent or divalent cation, and m is one or 2 depending on the valency of M, and b. from 5 to 95 weight percent of water-soluble organic or inorganic salt selected from the group consisting of sodium sulfate, sodium carbonate, sodium bicarbonate, sodium chloride, sodium phosphate, sodium tripolyphosphate, sodium borate, potassium carbonate, magnesium sulfate, sodium citrate, sodium tartrate, sodium malate, sodium succinate, sodium sulfosuccinate, sodium lactate, sodium glycolate, potassium citrate, potassium lactate, calcium citrate and calcium lactate, or mixtures thereof, with the proviso that one percent aqueous solutions of said salts have a pH of from 6 to 11, said composition additionally containing from 5 to 30 weight percent of anhydrous calcium chloride, said composition containing less than 0.8 mole of free water per mole of ester linkages in said organic surfactant substance.
Claim 2
Dependent Claim 231 words
A solid detergent composition in the form of a powder, granules or tablets, consisting essentially of a mixture obtained by blending a. from 5 to 80 weight percent of organic surfactant substance having the formula ##STR6## wherein R is saturated or unsaturated straight-chain or branched-chain hydrocarbon having 5 to 19 carbon atoms, with the proviso that more than 70 weight percent of R has from 10 to 14 carbon atoms, R' is hydrogen, CH 3 or C 2 H 5 , n is a number in the range of 1.7 to 6.5 on the average, M is a monovalent or divalent cation, and m is one or 2 depending on the valency of M, and b. from 5 to 95 weight percent of water-soluble organic or inorganic salt selected from the group consisting of sodium sulfate, sodium carbonate, sodium bicarbonate, sodium chloride, sodium phosphate, sodium tripolyphosphate, sodium borate, potassium carbonate, magnesium sulfate, sodium citrate, sodium tartrate, sodium malate, sodium succinate, sodium sulfosuccinate, sodium lactate, sodium glycolate, potassium citrate, potassium lactate, calcium citrate and calcium lactate, or mixtures thereof, with the proviso that one percent aqueous solutions of said salts have a pH of from 6 to 11, said composition additionally containing from 5 to 30 weight percent of anhydrous calcium chloride, said composition containing less than 0.8 mole of free water per mole of ester linkages in said organic surfactant substance.
Claim 3
Dependent Claim 27 words
A composition according to claim 1, containing from 10 to 60 weight of said organic surfactant substance and from 30 to 80 weight percent of said salts.
Claim 4
Dependent Claim 17 words
A composition according to claim 1 in which n is from 1.7 to 4.5 on the average.
Claim 5
Dependent Claim 14 words
A composition according to claim 1, in which n is from 2 to 4.
Claim 6
Dependent Claim 17 words
A composition according to claim 1 in which R is lauryl and R' is CH 3 .
Claim 7
Dependent Claim 15 words
A composition according to claim 1 in which R is lauryl and R' is hydrogen.
Claim 8
Dependent Claim 23 words
A composition according to claim 1 in which more than 70 percent of said organic surfactant substance is present as the calcium salt.
Claim 9
Dependent Claim 24 words
A composition according to claim 1 in which M is selected from the group consisting of calcium, magnesium, barium, cobalt, sodium, potassium and triethanolamine.
Claim 10
Dependent Claim 24 words
A composition according to claim 1 containing less than 0.5 mole of free water per mole of ester linkages in said organic surfactant substance.
Claim 11
Dependent Claim 16 words
A composition according to claim 1 in which said salt is comprised predominantly of sodium sulfate.
Claim 12
Dependent Claim 11 words
A composition according to claim 1, also containing an alkali silicate.
Claim 13
Dependent Claim 227 words
A solid detergent composition in the form of a powder, granules or tablets, consisting essentially of: a. from 5 to 80 weight percent of organic surfactant substance having the formula ##STR7## wherein R is saturated or unsaturated straight-chain or branched-chain hydrocarbon having 5 to 19 carbon atoms, with the proviso that more than 70 weight percent of R has from 10 to 14 carbon atoms, R' is hydrogen, CH 3 or C 2 H 5 , n is a number in the range of 1.7 to 6.5 on the average, M is a monovalent or divalent cation, and m is one or 2 depending on the valency of M, b. from 5 to 95 weight percent of water-soluble organic or inorganic salt selected from the group consisting of sodium sulfate, sodium carbonate, sodium bicarbonate, sodium chloride, sodium phosphate, sodium tripolyphosphate, sodium borate, potassium carbonate, magnesium sulfate, calcium chloride, sodium citrate, sodium tartrate, sodium malate, sodium succinate, sodium sulfosuccinate, sodium lactate, sodium glycolate, potassium citrate, potassium lactate, calcium citrate and calcium lactate, or mixtures thereof, with the proviso that one percent aqueous solutions of said salts have a pH of from 6 to 11 and with the further proviso that component (b) is comprised predominantly of sodium sulfate said composition containing less than 0.8 mole of free water per mole of ester linkages in said organic surfactant substance.
Claim 14
Dependent Claim 227 words
A solid detergent composition in the form of a powder, granules or tablets, consisting essentially of: a. from 5 to 80 weight percent of organic surfactant substance having the formula ##STR7## wherein R is saturated or unsaturated straight-chain or branched-chain hydrocarbon having 5 to 19 carbon atoms, with the proviso that more than 70 weight percent of R has from 10 to 14 carbon atoms, R' is hydrogen, CH 3 or C 2 H 5 , n is a number in the range of 1.7 to 6.5 on the average, M is a monovalent or divalent cation, and m is one or 2 depending on the valency of M, b. from 5 to 95 weight percent of water-soluble organic or inorganic salt selected from the group consisting of sodium sulfate, sodium carbonate, sodium bicarbonate, sodium chloride, sodium phosphate, sodium tripolyphosphate, sodium borate, potassium carbonate, magnesium sulfate, calcium chloride, sodium citrate, sodium tartrate, sodium malate, sodium succinate, sodium sulfosuccinate, sodium lactate, sodium glycolate, potassium citrate, potassium lactate, calcium citrate and calcium lactate, or mixtures thereof, with the proviso that one percent aqueous solutions of said salts have a pH of from 6 to 11 and with the further proviso that component (b) is comprised predominantly of sodium sulfate said composition containing less than 0.8 mole of free water per mole of ester linkages in said organic surfactant substance.
Claim 15
Dependent Claim 218 words
A solid detergent composition in the form of a powder, granules or tablets, consisting essentially of: a. from 5 to 80 weight percent of organic surfactant substance having the formula ##STR8## wherein R is saturated or unsaturated straight-chain or branched-chain hydrocarbon having 5 to 19 carbon atoms. with the proviso that more than 70 weight percent of R has from 10 to 14 carbon atoms, R' is hydrogen, CH 3 or C 2 H 5 , n is a number in the range of 1.7 to 6.5 on the average, M is a monovalent or divalent cation, and m is one or 2 depending on the valency of M, b. from 5 to 95 weight percent of water-soluble organic or inorganic salt selected from the group consisting of sodium sulfate, sodium carbonate, sodium bicarbonate, sodium chloride, sodium phosphate, sodium tripolyphosphate, sodium borate, potassium carbonate, magnesium sulfate, calcium chloride, sodium citrate, sodium tartrate, sodium malate, sodium succinate, sodium sulfosuccinate, sodium lactate, sodiium glycolate, potassium citrate, potassium lactate, calcium citrate and calcium lactate, or mixtures thereof, with the proviso that one percent aqueous solutions of said salts have a pH of from 6 to 11, and c. an alkali silicate, said composition containing less than 0.8 mole of free water per mole of ester linkages in said organic surfactant substance.
Claim 16
Dependent Claim 218 words
A solid detergent composition in the form of a powder, granules or tablets, consisting essentially of: a. from 5 to 80 weight percent of organic surfactant substance having the formula ##STR8## wherein R is saturated or unsaturated straight-chain or branched-chain hydrocarbon having 5 to 19 carbon atoms. with the proviso that more than 70 weight percent of R has from 10 to 14 carbon atoms, R' is hydrogen, CH 3 or C 2 H 5 , n is a number in the range of 1.7 to 6.5 on the average, M is a monovalent or divalent cation, and m is one or 2 depending on the valency of M, b. from 5 to 95 weight percent of water-soluble organic or inorganic salt selected from the group consisting of sodium sulfate, sodium carbonate, sodium bicarbonate, sodium chloride, sodium phosphate, sodium tripolyphosphate, sodium borate, potassium carbonate, magnesium sulfate, calcium chloride, sodium citrate, sodium tartrate, sodium malate, sodium succinate, sodium sulfosuccinate, sodium lactate, sodiium glycolate, potassium citrate, potassium lactate, calcium citrate and calcium lactate, or mixtures thereof, with the proviso that one percent aqueous solutions of said salts have a pH of from 6 to 11, and c. an alkali silicate, said composition containing less than 0.8 mole of free water per mole of ester linkages in said organic surfactant substance.

References Cited (Backward Citations)

US2733252A Cited
US2183853A Cited
US2789992A Cited
US3332880A Cited
US3728447A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-13 1980-12-13 1981-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-13 1984-12-13 1985-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-13 1988-12-13 1989-06-14 $7700.00 Window Closed / Lapsed

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