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US4028434A Expired / Lapsed US ⏱️ 0.0 years remaining

Graft polymers of vinyl phosphonic acid esters

Assignee: Bayer AG
•
Filing: 1975-08-14
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Granted: 1977-06-07
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Expires: 1995-08-14
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Abstract

Abstract The instant invention relates to graft polymers of vinyl phosphonic acid esters, optionally together with nitrogen-containing polymerizable vinyl compounds, on polyalkylene glycols and to a process for their production. The polymers so produced necessarily contain phosphorus and, optionally, nitrogen in the molecule. The polymers are rendered flameproof by the phosphorus and, in addition, self-extinguishing by the nitrogen.

Inventors

  • 👤 Wolfgang Konter
  • 👤 Josef Witte
  • 👤 Peter Vehlewald
  • 👤 Hans-Dieter Block

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 21:26
CPC Classifications
C; C08; C08F; C08F283/00; C08F283/06

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 66 words
A graft polymer of a. from 5 to 50 parts by weight of halogen-free vinyl phosphonic acid alkyl ester b. from 0 to 30 parts by weight of nitrogen-containing polymerizable vinyl compound and c. a polyalkylene oxide free from unsaturation having a molecular weight of from 1500 to 10,000 the amounts of components (a) and (b) being based on 100 parts by weight of component (c).
Claim 2
Dependent Claim 66 words
A graft polymer of a. from 5 to 50 parts by weight of halogen-free vinyl phosphonic acid alkyl ester b. from 0 to 30 parts by weight of nitrogen-containing polymerizable vinyl compound and c. a polyalkylene oxide free from unsaturation having a molecular weight of from 1500 to 10,000 the amounts of components (a) and (b) being based on 100 parts by weight of component (c).
Claim 3
Dependent Claim 46 words
A graft polymer according to claim 1, wherein component (a) is vinyl phosphonic acid methyl ester, component (b) comprising from 2 to 20 parts by weight and is selected from the group consisting of acrylamide, methacrylamide, acrylonitrile and methacrylonitrile, and component (c) is a polyethylene oxide.
Claim 4
Dependent Claim 45 words
A process for the production of graft polymers, wherein vinyl phosphonic acid esters and, optionally, copolymerizable nitrogen-containing vinyl compounds are polymerized at temperatures in the range from 5° to 150° C, in the presence of a polyalkylene glycol and radical catalysts or under high-energy radiation.
Claim 5
Dependent Claim 45 words
A process for the production of graft polymers, wherein vinyl phosphonic acid esters and, optionally, copolymerizable nitrogen-containing vinyl compounds are polymerized at temperatures in the range from 5° to 150° C, in the presence of a polyalkylene glycol and radical catalysts or under high-energy radiation.
Claim 6
Dependent Claim 18 words
A process as claimed in claim 3, wherein the polymerization reaction is conducted in an inert organic solvent.
Claim 7
Dependent Claim 42 words
A process as claimed in claim 3, wherein from 5 to 50 parts by weight of vinyl phosphonic acid esters from 0 to 30 parts by weight of the nitrogen-containing vinyl compound are grafted onto 100 parts by weight of polyalkylene glycol.
Claim 8
Dependent Claim 27 words
A process as claimed in claim 5, wherein vinyl phosphonic acid methyl ester and acrylamide, methacrylamide, acrylonitrile or methacrylonitrile are grafted onto polyethylene oxide or polypropylene oxide.

References Cited (Backward Citations)

US3188228A Cited
US3418354A Cited
US3626027A Cited
US3627839A Cited
US3676529A Cited
US3763277A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-06 1980-12-06 1981-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-06 1984-12-06 1985-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-06 1988-12-06 1989-06-07 $7700.00 Window Closed / Lapsed

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