Patent US4028309A successfully refreshed from Google Patents.
US4028309A
Expired / Lapsed
US
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Coating compositions containing esters of dibasic acids, glycols and glycidyl esters, and polyisocyanates
Assignee: EIDP Inc
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Filing: 1975-07-31
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Granted: 1977-06-07
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Expires: 1995-07-31
Abstract
Abstract Diesters and triesters of dibasic acids, glycols, triols, and glycidyl esters, when formulated with polyfunctional isocyanates, form coating compositions which require little or no organic liquid carrier. These compositions air-dry or cure at low temperatures, and give off little or no organic liquid on drying or curing, thereby conforming to most anti-pollution legislation and saving fuel.
Inventors
- 👤 James C. Fang
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 13:05
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/42; C08G18/4291; C08G18/30; C08G18/32; C08G18/3203; C08G18/3221; C08G18/67; C08G18/68
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
176 words
A composition comprising the reaction product of A. a compound selected from the group consisting of: ##STR17## where, in either structure, X is hydrogen, an alkyl radical of 1-4 carbon atoms or phenyl; Y 1 and Y 2 can be the same or different and are hydrogen, --CH 2 OH or an alkyl radical of 1-4 carbon atoms; ##STR18## where A is hydrogen or --COOH for the diester and a valence bond for the triester; D 1 is hydrogen or --CH 2 OH; D 2 is hydrogen or --OH provided that one and only one of D 1 or D 2 must be --OH or --CH 2 OH; ##STR19## R is an alkyl radical of 4-18 carbon atoms, or a singly, doubly or triply unsaturated hydrocarbon radical of 17 carbon atoms; a and b and 1 or 2, provided that a + b is 2 or 3; c is 2 or 3; n is 0 or 1; m is 1-5; p is 0 or 1; and t is 0 or 1; and B. a polyfunctional isocyanate.
Claim 2
Dependent Claim
176 words
A composition comprising the reaction product of A. a compound selected from the group consisting of: ##STR17## where, in either structure, X is hydrogen, an alkyl radical of 1-4 carbon atoms or phenyl; Y 1 and Y 2 can be the same or different and are hydrogen, --CH 2 OH or an alkyl radical of 1-4 carbon atoms; ##STR18## where A is hydrogen or --COOH for the diester and a valence bond for the triester; D 1 is hydrogen or --CH 2 OH; D 2 is hydrogen or --OH provided that one and only one of D 1 or D 2 must be --OH or --CH 2 OH; ##STR19## R is an alkyl radical of 4-18 carbon atoms, or a singly, doubly or triply unsaturated hydrocarbon radical of 17 carbon atoms; a and b and 1 or 2, provided that a + b is 2 or 3; c is 2 or 3; n is 0 or 1; m is 1-5; p is 0 or 1; and t is 0 or 1; and B. a polyfunctional isocyanate.
Claim 3
Dependent Claim
76 words
The composition of claim 1 where, in formula (1), X is hydrogen; a and b are 1; n is 0, m is 1, Y 1 and Y 2 are hydrogen; D 1 is hydrogen; D 2 is --OH; p is 1; ##STR20## where R 1 is --CH 3 and R 2 and R 3 are lower alkyl, the total number of carbon atoms in R 1 , R 2 and R 3 being 7-11; and ##STR21##
Claim 4
Dependent Claim
79 words
The composition of claim 1 wherein, in formula (1), X is hydrogen; a and b are 1; n is 0; m is 1; Y 1 is --CH 3 ; Y 2 is hydrogen; D 1 is hydrogen; D 2 is --OH; p is 1; ##STR22## where R 1 is --CH 3 and R 2 and R 3 are lower alkyl, the total number of carbon atoms in R 1 , R 2 and R 3 being 7-11; and ##STR23##
Claim 5
Dependent Claim
88 words
The composition of claim 1 where, in formula (1), X is hydrogen; n is 0; m is 2; Y 1 and Y 2 are (1) hydrogen and --OH and (2) hydrogen and hydrogen; D 1 is hydrogen; D 2 is --OH; p is 1; ##STR24## t is 1; a and b are 1; ##STR25## where R 1 is --CH 3 and R 2 and R 3 are lower alkyl, the total number of carbon atoms in R 1 , R 2 and R 3 being 7-11; and ##STR26##
Claim 6
Dependent Claim
25 words
The composition of claim 1 wherein a and b are 1 or 2, provided that a + b is 3, c is 3, and ##STR27##
Claim 7
Dependent Claim
11 words
The composition of claim 1 wherein the polyfunctional isocyanate is ##STR28##
Claim 8
Dependent Claim
11 words
The composition of claim 2 wherein the polyfunctional isocyanate is ##STR29##
Claim 9
Dependent Claim
11 words
The composition of claim 3 wherein the polyfunctional isocyanate is ##STR30##
Claim 10
Dependent Claim
11 words
The composition of claim 4 wherein the polyfunctional isocyanate is ##STR31##
Claim 11
Dependent Claim
11 words
The composition of claim 5 wherein the polyfunctional isocyanate is ##STR32##
Claim 12
Dependent Claim
13 words
An article coated with a cured film of the composition of claim 1.
Claim 13
Dependent Claim
13 words
An article coated with a cured film of the composition of claim 2.
Claim 14
Dependent Claim
13 words
An article coated with a cured film of the composition of claim 3.
Claim 15
Dependent Claim
13 words
An article coated with a cured film of the composition of claim 4.
Claim 16
Dependent Claim
13 words
An article coated with a cured film of the composition of claim 5.
Claim 17
Dependent Claim
13 words
The composition of claim 1 wherein the polyfunctional isocyanate is a blocked isocyanate.
Claim 18
Dependent Claim
183 words
A curable composition comprising A. a compound selected from the group consisting of: ##STR33## where, in either structure, X is hydrogen, an alkyl radical of 1-4 carbon atoms or phenyl; Y 1 and Y 2 can be the same or different and are hydrogen, --CH 2 OH or an alkyl radical of 1-4 carbon atoms; ##STR34## where A is hydrogen or --COOH for the diester and a valence bond for the triester; D 1 is hydrogen or --CH 2 OH; D 2 is hydrogen or --OH provided that one and only one of D 1 or D 2 must be --OH or --CH 2 OH; ##STR35## R is an alkyl radical of 4-18 carbon atoms, or a singly, doubly or triply unsaturated hydrocarbon radical of 17 carbon atoms; a and b are 1 or 2, provided that a + b is 2 or 3; c is 2 or 3; n is 0 or 1; m is 1-5; p is 0 or 1; and t is 0 or 1; and B. a polyfunctional isocyanate, brought into form for use by mixing (A) with (B).
Claim 19
Dependent Claim
183 words
A curable composition comprising A. a compound selected from the group consisting of: ##STR33## where, in either structure, X is hydrogen, an alkyl radical of 1-4 carbon atoms or phenyl; Y 1 and Y 2 can be the same or different and are hydrogen, --CH 2 OH or an alkyl radical of 1-4 carbon atoms; ##STR34## where A is hydrogen or --COOH for the diester and a valence bond for the triester; D 1 is hydrogen or --CH 2 OH; D 2 is hydrogen or --OH provided that one and only one of D 1 or D 2 must be --OH or --CH 2 OH; ##STR35## R is an alkyl radical of 4-18 carbon atoms, or a singly, doubly or triply unsaturated hydrocarbon radical of 17 carbon atoms; a and b are 1 or 2, provided that a + b is 2 or 3; c is 2 or 3; n is 0 or 1; m is 1-5; p is 0 or 1; and t is 0 or 1; and B. a polyfunctional isocyanate, brought into form for use by mixing (A) with (B).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-06-06 | 1980-12-06 | 1981-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-06-06 | 1984-12-06 | 1985-06-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-06-06 | 1988-12-06 | 1989-06-07 | $7700.00 | Window Closed / Lapsed |