Patent US4026997A successfully refreshed from Google Patents.
US4026997A
Expired / Lapsed
US
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Process for the production of ammonium fluoride from fluosilicic acid
Assignee: Bayer AG
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Filing: 1976-04-13
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Granted: 1977-05-31
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Expires: 1996-04-13
Abstract
Abstract In the production of an ammonium fluoride solution by precipitating hexafluosilicic acid from its solution with ammonia and from the resulting suspension separating off the silicon dioxide precipitated, the improvement which comprises thoroughly mixing the hexafluosilicic acid solution and ammonia at a temperature of about 40° to 90° C, in such proportions that the suspension obtained contains at least 1% of free ammonia and at most 22% of ammonium fluoride, the average residence time of the reactants in the precipitation zone being at least 4 minutes. Advantageously, the silicon dioxide is separated off from the suspension obtained without previous cooling, the resulting ammonium fluoride filtrate is left standing for at least 30 minutes to permit flocculation of silicon dioxide contained therein and the flocculated silicon dioxide is separated off.
Inventors
- 👤 Siegfried Schneider
- 👤 Wolfgang Weis
- 👤 Volker Beyl
- 👤 Hans Niederprum
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 04:15
CPC Classifications
C; C01; C01B; C01B33/00; C01B33/113; C01B33/12; C01B33/18; C01B33/186; C01C; C01C1/00; C01C1/16; C01C1/162; C01P; C01P2006/00; C01P2006/80
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
148 words
In the production of an ammonium fluoride solution by precipitating hexafluosilicic acid from its solution with ammonia and from the resulting suspension separating off the silicon dioxide precipitated, the improvement which comprises continuously and simultaneously feeding aqueous solutions of hexafluosilicic acid and ammonia to a mixed precipitation zone maintained at a temperature of about 40° to 90° C. to form a suspension of silicon dioxide, the solutions being supplied in such proportions that the suspension obtained contains about 1.5 to 3.5% of free ammonia and at most 22% of ammonium fluoride, the average residence time of the reactants in the precipitation zone being about 8 to 15 minutes and filtering the solution to produce a filter cake comprising coarse SiO 2 having a solids content of about 55 to 75% by weight, the rate of filtration for a 250 ml aliquot portion being less than about 25 seconds.
Claim 2
Dependent Claim
148 words
In the production of an ammonium fluoride solution by precipitating hexafluosilicic acid from its solution with ammonia and from the resulting suspension separating off the silicon dioxide precipitated, the improvement which comprises continuously and simultaneously feeding aqueous solutions of hexafluosilicic acid and ammonia to a mixed precipitation zone maintained at a temperature of about 40° to 90° C. to form a suspension of silicon dioxide, the solutions being supplied in such proportions that the suspension obtained contains about 1.5 to 3.5% of free ammonia and at most 22% of ammonium fluoride, the average residence time of the reactants in the precipitation zone being about 8 to 15 minutes and filtering the solution to produce a filter cake comprising coarse SiO 2 having a solids content of about 55 to 75% by weight, the rate of filtration for a 250 ml aliquot portion being less than about 25 seconds.
Claim 3
Dependent Claim
18 words
The process of claim 1, wherein the suspension contains about 16 to 20% by weight of ammonium fluoride.
Claim 4
Dependent Claim
48 words
The process of claim 1, wherein the silicon dioxide is separated off from the suspension obtained without previous cooling, the resulting ammonium fluoride filtrate is left standing for at least 30 minutes to permit flocculation of silicon dioxide contained therein and the flocculated silicon dioxide is separated off.
Claim 5
Dependent Claim
28 words
The process of claim 3, wherein flocculation is carried out in the absence of cooling and the free ammonia content is kept at a value of about 1.5%.
Claim 6
Dependent Claim
28 words
The process of claim 4, wherein the reaction temperature is about 65° to 85° C., and the suspension contains about 16 to 20% by weight of ammonium fluoride.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-30 | 1980-11-29 | 1981-05-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-30 | 1984-11-29 | 1985-05-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-30 | 1988-11-29 | 1989-05-31 | $7700.00 | Window Closed / Lapsed |