Radiation-curable coating compositions and inks

Claim 1

A polymerizable agent selected from the group consisting of the monomer and mixtures of such monomers wherein said monomer has the formula: ##STR9## wherein Z is a divalent aromatic, aliphatic or cycloaliphatic radical and R is, an alkoxy group substituted by a plurality of α, β -unsaturated low molecular weight acylate groups.

Claim 5

A method of making a polymerizable monomer which comprises reacting substantially equimolar proportions of polyacrylate and diisocyanate at a temperature of between about 56° to about 75° C. for about three hours, while under agitation, the polyacrylate containing substantially one equivalent of hydroxyl group and the diisocyanate containing substantially two equivalents of isocyanate, leaving about one equivalent of isocyanate unreacted, then reacting the resultant mixture with an amount of castor oil containing sufficient hydroxyl groups to react with substantially all of the remaining isocyanate, the latter reaction being effected at a temperature of between about 70° to 80° C. for about four and one-half hours, while under agitation, and thereafter removing any unreacted isocyanate remaining in the mixture by reacting it with a long-chain alcohol, the polyacrylate being selected from the group consisting of pentaerythritol triacrylate, pentaerythritol diacrylate, pentaerythritol trimethacrylate, dipentaerythritol pentaacrylate, and mixtures thereof, and the diisocyanate being selected from the group consisting of 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 2,4-methylcyclohexyl diisocyanate, 2,6-methylcyclohexyl diisocyanate, 4,4'-methylene-bis-phenyl isocyanate, 4,4'-methylene-bis-cyclohexyl isocyanate, isophorene diisocyanate, hexamethylene diisocyanate, phorone diisocyanate, and mixtures thereof.

Claim 6

A method of making a polymerizable monomer which comprises reacting substantially equimolar proportions of polyacrylate and diisocyanate at a temperature of between about 56° to about 75° C. for about three hours, while under agitation, the polyacrylate containing substantially one equivalent of hydroxyl group and the diisocyanate containing substantially two equivalents of isocyanate, leaving about one equivalent of isocyanate unreacted, then reacting the resultant mixture with an amount of castor oil containing sufficient hydroxyl groups to react with substantially all of the remaining isocyanate, the latter reaction being effected at a temperature of between about 70° to 80° C. for about four and one-half hours, while under agitation, and thereafter removing any unreacted isocyanate remaining in the mixture by reacting it with a long-chain alcohol, the polyacrylate being selected from the group consisting of pentaerythritol triacrylate, pentaerythritol diacrylate, pentaerythritol trimethacrylate, dipentaerythritol pentaacrylate, and mixtures thereof, and the diisocyanate being selected from the group consisting of 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 2,4-methylcyclohexyl diisocyanate, 2,6-methylcyclohexyl diisocyanate, 4,4'-methylene-bis-phenyl isocyanate, 4,4'-methylene-bis-cyclohexyl isocyanate, isophorene diisocyanate, hexamethylene diisocyanate, phorone diisocyanate, and mixtures thereof.